THERMOPLASTIC MEMBRANES INCLUDING POLYMER WITH ISOCYANATE-REACTIVE FUNCTIONALITY

1 . An adhered roofing system comprising

i. a roof substrate;

ii. a thermoplastic membrane including a first layer, which forms a top surface of the membrane, laminated to a second layer, which forms the bottom surface of the membrane, where the second layer includes from about 3 to about 25 wt. % of a polymer having at least one isocyanate-reactive substituent, and where the first layer is substantially devoid of a polymer having an isocyanate-reactive substituent; and

iii. an adhesive securing the membrane to the substrate such that the second layer of the thermoplastic membrane is in direct contact with said adhesive.

2 . The roofing system of claim 1 , where the adhered roofing system is a fully-adhered roofing system.

3 . The roofing system of claim 1 , where the second layer is a coextruded layer that includes at least two sublayers with one sublayer being the lowermost sublayer of the thermoplastic membrane thereby forming the bottom surface of the thermoplastic membrane, where the lowermost sublayer includes the polymer having at least one isocyanate-reactive substituent.

4 . The roofing system of claim 1 , where the thermoplastic membrane further includes a scrim reinforcement disposed between the first and second layers.

5 . The roofing system of claim 1 , where the polymer having at least one isocyanate-reactive substituent is a block copolymer including at least one hard segment and at least one soft segment.

6 . The roofing system of claim 1 , where the length of the polymer having at least one isocyanate-reactive substituent is at least one times the entanglement length of the polymer.

7 . The roofing system of claim 1 , where the adhesive is a polyurethane adhesive.

8 . The roofing system of claim 1 , where the isocyanate-reactive substituent is a hydroxyl group.

9 . The roofing system of claim 8 , where the polymer having at least one isocyanate-reactive group includes at least 1 wt. % hydroxyl functionality based upon the entire weight of the polymer.

10 . A method of forming an adhered membrane roof system, the method comprising:

i. applying a polyurethane adhesive to a substrate on a roof to form an adhesive layer; and

ii. applying a thermoplastic membrane directly to the adhesive layer, where the thermoplastic membrane includes a first layer, which forms a top surface of the membrane, laminated to a second layer, which forms the bottom surface of the membrane, where the second layer includes from about 3 to about 25 wt. % of a polymer having at least one isocyanate-reactive substituent, where the first layer is substantially devoid of a polymer having an isocyanate-reactive substituent, and wherein the second layer of the thermoplastic membrane is in direct contact with said adhesive layer.

11 . The method of claim 10 , where the substrate is completely covered with the adhesive.

12 . The method of claim 10 , where the substrate is partially covered with the adhesive.

13 . The method of claim 10 , where the second layer is a coextruded layer that includes at least two sublayers with one sublayer being the lowermost sublayer of the thermoplastic membrane thereby forming the bottom surface of the membrane, where the lowermost sublayer includes the polymer having at least one isocyanate-reactive substituent.

14 . The method of claim 10 , where the thermoplastic membrane further includes a scrim reinforcement disposed between the first and second layers.

15 . The method of claim 10 , where polymer having at least one isocyanate-reactive substituent is a block copolymer including at least one hard segment and at least one soft segment.

16 . The method of claim 10 , where the length of the polymer having at least one isocyanate-reactive substituent is at least one times the entanglement length of the polymer.

17 . The method of claim 10 , where the adhesive is a polyurethane adhesive.

18 . The roofing system of claim 3 , wherein the at least two sublayers also include an uppermost sublayer and wherein the lowermost sublayer is thinner than the uppermost sublayer.

19 . The method of claim 13 , wherein the at least two sublayers also include an uppermost sublayer and wherein the lowermost sublayer is thinner than the uppermost sublayer.

20 . A method of forming an adhered membrane roof system, the method comprising:

i. applying a polyurethane adhesive to a substrate on a roof to form an adhesive layer; and

ii. applying a thermoplastic membrane directly to the adhesive layer, where the thermoplastic membrane includes a top layer laminated to a bottom layer, said bottom layer including from about 3 to about 25 wt. % of a polymer having at least one isocyanate-reactive substituent, said top layer being devoid of a polymer having an isocyanate-reactive substituent, and where said step of applying contacts the bottom layer with the polyurethane adhesive.