IP Library Granted Patent US 11,993,536
Granted Patent B2
US 11,993,536 · App. 17/581,184 · Granted May 28, 2024

Solar control coating with discontinuous metal layer

Inventors: Adam D. Polcyn (Pittsburgh, PA); Jeffrey A. Benigni (McGrann, PA); Abhinav Bhandari (Solon, OH); Harry Buhay (Allison Park, PA); James J. Finley (Pittsburgh, PA); Paul A. Medwick (Wexford, PA); Dennis J. O'Shaughnessy (Allison Park, PA); Paul R. Ohodnicki, Jr. (Allison Park, PA); James P. Thiel (Lihue, HI); Andrew V. Wagner (Pittsburgh, PA)
Assignee: Vitro Flat Glass LLC
C03C17/36C03C17/3618C03C17/3639C03C17/366C03C2217/42Y10T428/12542Y10T428/12549Y10T428/24851Y10T428/24917
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Quick Facts
Patent No.
US 11,993,536
App. No.
17/581,184
Granted
May 28, 2024
Kind
B2
Abstract

An architectural transparency includes a substrate; a first dielectric layer over at least a portion of the substrate, a first metallic layer over the first dielectric layer, a first primer layer over the first metallic layer, a second dielectric layer over the first primer layer, a second metallic layer over the second dielectric layer, a second primer layer over the second metallic layer, a third dielectric layer over the second primer layer, a third metallic layer over the third dielectric layer, a third primer layer over the third dielectric layer, and a fourth dielectric layer over the third primer layer. At least one of the metallic layers is a subcritical metallic layer.

Claims (62)

1. A coated transparency, comprising:

a glass substrate; and

a solar control coating over at least a portion of the glass substrate, the coating comprising:

a first dielectric layer formed over at least a portion of the glass substrate;

a first metallic layer over the first dielectric layer;

a second dielectric layer over the first metallic layer;

a second metallic layer over the second dielectric layer;

a third dielectric layer over the second metallic layer;

a third metallic layer over the third dielectric layer; and

a fourth dielectric layer over the third metallic layer,

wherein at least one of the metallic layers is a discontinuous metallic layer,

wherein the coated transparency has a solar heat gain coefficient (SHGC) of less than 0.3,

wherein the coated transparency can be tempered or heat treated without adversely impacting the performance characteristics of the coated transparency and/or producing haze therein, and

wherein the coated transparency is an automotive transparency or an architectural transparency.

2. The transparency of claim 1 , wherein the at least one discontinuous metallic layer has an effective thickness of less than 50 Å.

3. The transparency of claim 1 , wherein the first dielectric layer, the second dielectric layer, the third dielectric layer, or the fourth dielectric layer comprise a first film and a second film deposited over the first film.

4. The transparency of claim 1 , wherein at least one of the second dielectric layer and third dielectric layer comprise a first film, a second film over the first film, and a third film over the second film.

5. The transparency of claim 1 , wherein the first dielectric layer comprises a metal oxide, an oxide of a metal alloy, a nitride, an oxynitride, or a mixture thereof.

6. The transparency of claim 1 , wherein the first dielectric layer comprises silicon nitride, silicon aluminum nitride, aluminum nitride, zinc oxide, or zinc stannate.

7. The transparency of claim 1 , wherein the at least one discontinuous metallic layer is selected from the group consisting of silver, gold, copper, palladium, and a mixture thereof.

8. The transparency of claim 1 , wherein the second dielectric layer is selected from the group consisting of silicon nitride, silicon aluminum nitride, aluminum nitride, zinc oxide, or zinc stannate.

9. The transparency of claim 1 , further comprising a protective coating over the fourth dielectric layer.

10. The transparency of claim 9 , wherein the protective coating comprises titania.

11. A coated transparency, comprising:

a glass substrate; and

a solar control coating over at least a portion of the glass substrate, the coating comprising:

a first dielectric layer formed over at least a portion of the glass substrate;

a first continuous metallic layer over the first dielectric layer;

a first primer layer over the first continuous metallic layer;

a second dielectric layer over the first primer layer;

a second discontinuous metallic layer over the second dielectric layer;

a third dielectric layer over the second discontinuous metallic layer;

a third continuous metallic layer over the third dielectric layer;

a third primer layer over the third continuous metallic layer;

a fourth dielectric layer over the third primer layer; and

a protective coating over the fourth dielectric layer,

wherein the coated transparency has a solar heat gain coefficient (SHGC) of less than 0.3,

wherein the coated transparency can be tempered or heat treated without adversely impacting the performance characteristics of the coated transparency and/or producing haze therein, and

wherein the coated transparency is an automotive transparency or an architectural transparency.

12. The transparency of claim 11 , wherein the second discontinuous metallic layer has an effective thickness of less than 50 Å.

13. The transparency of claim 11 , wherein the first dielectric layer, the second dielectric layer, the third dielectric layer, or the fourth dielectric layer comprise a first film and a second film deposited over the first film.

14. The transparency of claim 11 , wherein at least one of the second dielectric layer and the third dielectric layer comprise a first film, a second film deposited over the first film, and a third film deposited over the second film.

15. The transparency of claim 11 , wherein the first dielectric layer comprises a metal oxide, an oxide of a metal alloy, a nitride, an oxynitride, or mixtures thereof.

16. The transparency of claim 11 , wherein the protective coating comprises titania, silica, alumina, or a mixture thereof.

17. A coated transparency, comprising:

a glass substrate; and

a solar control coating over at least a portion of the glass substrate, the coating comprising:

a first dielectric layer formed over at least a portion of the glass substrate, wherein the first dielectric layer comprises a metal that is an oxide, an oxynitride, or a nitride, wherein the metal is selected from the group consisting of silicon, silicon-aluminum alloy or mixture, zinc, and zinc-tin alloy or mixture;

a first metallic layer over the first dielectric layer, wherein the first metallic layer comprises silver, gold, copper, palladium or a mixture thereof;

a first primer layer over the first metallic layer;

a second dielectric layer over the first primer layer, wherein the second dielectric layer comprises a metal that is an oxide, an oxynitride, or a nitride, wherein the metal is selected from the group consisting of silicon, silicon-aluminum alloy or mixture, zinc, and zinc-tin alloy or mixture;

a second metallic layer over the second dielectric layer, wherein the second metallic layer comprises silver, gold, copper, palladium or a mixture thereof, and wherein the second metallic layer is a discontinuous metallic layer having an effective thickness of less than 50 Å;

a third dielectric layer over the second primer layer, wherein the third dielectric layer comprises a metal that is an oxide, an oxynitride, or a nitride, wherein the metal is selected from the group consisting of silicon, silicon-aluminum alloy or mixture, zinc, and zinc-tin alloy or mixture;

a third metallic layer over the third dielectric layer, wherein the third metallic layer comprises silver, gold, copper, palladium or a mixture thereof;

a third primer layer over the third metallic layer; and

a fourth dielectric layer over the third primer layer, wherein the fourth dielectric layer comprises a metal that is an oxide, an oxynitride, or a nitride, wherein the metal is selected from the group consisting of silicon, silicon-aluminum alloy or mixture, zinc, and zinc-tin alloy or mixture,

wherein the coated transparency has a solar heat gain coefficient (SHGC) of less than 0.3,

wherein the coated transparency can be tempered or heat treated without adversely impacting the performance characteristics of the coated transparency and/or producing haze therein, and

wherein the coated transparency is an automotive transparency or an architectural transparency.

18. The transparency of claim 17 , wherein the first dielectric layer comprises zinc oxide.

19. The transparency of claim 17 , further comprising a protective coating over the fourth dielectric layer.

20. The transparency of claim 19 , wherein the protective coating comprises titania, silica, alumina, or a mixture thereof.

Assignments (2)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jan 21, 2022
From: POLCYN, ADAM D.; BENIGNI, JEFFREY A.; BHANDARI, ABHINAV; BUHAY, HARRY; FINLEY, JAMES J.; MEDWICK, PAUL A.; O'SHAUGHNESSY, DENNIS J.; OHODNICKI, PAUL R., JR.; THIEL, JAMES P.; WAGNER, ANDREW V.
To: VITRO, S.A.B. DE C.V.
Reel/Frame 058726/0251 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jan 21, 2022
From: VITRO, S.A.B. DE C.V.
To: VITRO FLAT GLASS LLC
Reel/Frame 058726/0544 →
Continuity (6)
Continuation 16820878 · Mar 17, 2020
Continuation 16423489 · May 28, 2019
Continuation 15842118 · Dec 14, 2017
Continuation 13072866 · Mar 28, 2011
Provisional Application 61318471 · Mar 29, 2010
Related Publication 20220144697A1 · May 12, 2022