Negative electrode plate, lithium secondary battery, and apparatus containing such lithium secondary battery
This application provides a lithium secondary battery and a negative electrode plate for the lithium secondary battery. The negative electrode plate includes a negative electrode current collector and a negative electrode active material layer disposed on at least one surface of the negative electrode current collector, where a surface of the negative electrode active material layer closer to the current collector is provided with an elastic coating. And the elastic coating includes an elastic polymer and a conductive agent. At a pressure of 1 MPa to 20 MPa, the elastic coating has a compression deformation of 20% to 80% and an elastic modulus of 1 MPa to 800 MPa. And optionally, at the pressure of 1 MPa to 20 MPa, the elastic coating has a compression deformation of 30% to 60% and an elastic modulus of 5 MPa to 100 MPa.
1 . A negative electrode plate for a lithium secondary battery, comprising:
a negative electrode current collector:
an elastic coating disposed on at least one surface of the negative electrode current collector; and
a negative electrode active material layer disposed on the elastic coating, wherein,
the elastic coating comprises an elastic polymer and a conductive agent;
the conductive agent is a uniform mixture of conductive carbon with a fibrous structure and conductive carbon with a spherical structure, the conductive carbon with a fibrous structure is carbon nanotube, and a mass ratio of the conductive carbon with a fibrous structure to the conductive carbon with a spherical structure is 1:1;
at a pressure of 1 MPa to 20 MPa, the elastic coating has a compression deformation of 30% to 60% and an elastic modulus of 5 MPa to 100 MPa;
a mass of the elastic polymer is 50% to 80% of a total mass of the elastic coating, and a mass of the conductive agent is 20% to 50% of the total mass of the elastic coating; and
the elastic polymer comprises one or more of polyethylene, polyethylene oxide, polyvinylidene fluoride, or polystyrene butadiene.
2 . The negative electrode plate according to claim 1 , wherein a surface coarseness of the elastic coating is 0.2 μm to 20 μm.
3 . The negative electrode plate according to claim 2 , wherein a thickness of the elastic coating is 1 μm to 100 μm.
4 . The negative electrode plate according to claim 1 , wherein
the conductive carbon with a spherical structure comprises one or more of conductive carbon black, conductive graphite, or acetylene black.
5 . The negative electrode plate according to claim 1 , wherein a surface coarseness of the current collector is 0.05 μm to 5 μm.
6 . The negative electrode plate according to claim 1 , wherein values of a thickness T of the elastic coating (in μm), a surface coarseness Ra 1 of the current collector (in μm), a surface coarseness Ra 2 of the elastic coating (in μm), and an elastic modulus E of the elastic coating (in mPa) satisfy the following equation:
2.50≤ E·Ra 1 ·Ra 2 /[T ( Ra 1 +Ra 2 )]≤2.60.
7 . The negative electrode plate according to claim 1 , wherein the negative electrode active material layer comprises metallic lithium and/or a lithium alloy.
8 . A lithium secondary battery, comprising:
a solid electrolyte; and
the negative electrode plate according to claim 1 ;
wherein the solid electrolyte is a sulfide solid electrolyte and/or a polymer solid electrolyte.
9 . The lithium secondary battery according to claim 8 , wherein the lithium secondary battery further comprises a positive electrode, the positive electrode comprises a positive electrode active material, and the positive electrode active material is an NCM ternary material.
10 . The lithium secondary battery according to claim 8 , wherein the sulfide solid electrolyte is selected from one or more of Li 3 PS 4 , Li 6 PS 5 Cl, Li 10 GeP 2 S 12 , or Li 7 P 3 S 11 .
11 . An apparatus, comprising the lithium secondary battery according to claim 8 .