Negative electrode plate, lithium-ion battery and apparatus
A negative electrode plate, a lithium-ion battery and an apparatus are disclosed. The negative electrode plate includes a negative electrode current collector, a negative electrode active material layer including a negative electrode active material and disposed on at least one surface of the negative electrode current collector, and a lithium-replenishing layer disposed on a surface of the negative electrode active material layer away from the negative current collector. The negative electrode plate can effectively ameliorate the problem of plate heating, and channels formed by the lithium-replenishing region and the gap region can enable the lithium-ion battery to be effectively impregnated with the electrolyte after electrolyte injection is performed to the lithium-ion battery, thereby improving the energy density of the battery while also improving the service life and kinetic performance of the battery.
1. A negative electrode plate, comprising:
a negative electrode current collector;
a negative electrode active material layer comprising a negative electrode active material and disposed on at least one surface of the negative electrode current collector; and
a lithium-replenishing layer disposed on a surface of the negative electrode active material layer away from the negative current collector;
wherein the lithium-replenishing layer comprises a lithium-replenishing region and a gap region, and the lithium-replenishing region and the gap region being interconnected in order,
the lithium-replenishing region has a width A of 50 μm≤A≤2000 μm,
the gap region has a width B of 50 μm≤B≤1500 μm,
A, B are measurement values measured along an extension direction of connection between the lithium-replenishing region and the gap region,
the lithium-replenishing region and the gap region further satisfy 3.0×10 −2 ≤A/(A+B)<0.976,
a middle line of the lithium-replenishing region and a direction of a width of the negative electrode plate have an angle θ, and the angle θ satisfies condition of 0°≤θ≤75°,
a ratio of a distance difference L of an edge of the lithium-replenishing region to the width A of the lithium-replenishing region satisfies condition of 0<L/A≤0.5,
a ratio of a thickness of the lithium-replenishing region to a weight of the negative electrode active material satisfies condition of 0.02≤C/M≤0.18;
wherein C is the thickness of the lithium-replenishing region, and M is the weight of the negative electrode active material, and the C/M has a unit of 1540.25 μm/mg/mm 2 .
2. The negative electrode plate according to claim 1 , wherein the lithium-replenishing region and the gap region satisfy condition of 3.0×10 −2 ≤A/(A+B)<0.938.
3. The negative electrode plate according to claim 1 , wherein the lithium-replenishing region and the gap region satisfy condition of 0.667≤A/(A+B)≤0.976.
4. The negative electrode plate according to claim 1 , wherein the width A is of 50 μm≤A≤1500 μm.
5. The negative electrode plate according to claim 1 , wherein the width B is of 50 μm≤B≤500 μm.
6. The negative electrode plate according to claim 1 , wherein 1000 μm≤A≤2000 μm, and 100 μm≤B≤500 μm.
7. The negative electrode plate according to claim 1 , wherein 0°≤θ≤60°.
8. The negative electrode plate according to claim 7 , wherein 0°≤θ≤45°.
9. The negative electrode plate according to claim 1 , wherein a ratio of a distance difference L of an edge of the lithium-replenishing region to the width A of the lithium-replenishing region satisfies condition of 0<L/A≤0.2.
10. The negative electrode plate according to claim 9 , wherein 0.05≤L/A≤0.20.
11. The negative electrode plate according to claim 1 , wherein a ratio of a thickness of the lithium-replenishing region to a weight of the negative electrode active material satisfies condition of 0.02≤C/M≤0.18;
wherein C is the thickness of the lithium-replenishing region, and M is the weight of the negative electrode active material.
12. The negative electrode plate according to claim 11 , wherein 0.06≤C/M≤0.13.
13. The negative electrode plate according to claim 1 , wherein a component of the lithium-replenishing region is selected from one or more of elemental lithium, lithium oxide, lithium nitride, lithium fluoride, lithium hydroxide and lithium silicon alloy.
14. The negative electrode plate according to claim 1 , wherein the negative electrode active material comprises one or more of a Si-based material, a Sn-based material, Si/C, Sn/C, Si halide, Sn halide, Si alloy and Sn alloy.
15. A lithium-ion battery, comprising a positive electrode, a negative electrode, an electrolyte and a separator, wherein the negative electrode comprises the negative electrode plate according to claim 1 .
16. The lithium-ion battery according to claim 15 , wherein the lithium-replenishing region has a thickness C1 of 0.05 μm≤C1≤10 μm after formation.
17. A battery module, comprising the lithium-ion battery according to claim 15 .
18. A battery pack, comprising the battery module according to claim 17 .
19. An apparatus, comprising the lithium-ion battery according to claim 15 .
20. The apparatus according to claim 19 , wherein the apparatus is selected from one or more of an electric vehicle, an electric ship, an electric tool, an electronic device and an energy storage system.