Binder composition for enhanced catalyst washcoat adhesion
The present disclosure provides binder compositions formed with a plurality of binder materials having differing mean particles, the binder compositions being useful to improve washcoat adhesion on a substrate. Adhesion can be improved related to an increase in the binder concentration without a significant or substantial increase in associated viscosity. Such binder compositions can comprise a first binder material formed of a plurality of particles having a first mean particle size and a second binder material formed of a plurality of particles having a second mean particle size, wherein a ratio of the first mean particle size to the second mean particle size about 2 or greater. The present disclosure further provides catalyst compositions, catalyst articles, and emission systems incorporating the binder compositions.
1. A binder composition comprising:
a first binder material formed of a plurality of particles having a first mean particle size;
a second binder material formed of a plurality of particles having a second mean particle size; and
a third binder material formed of a plurality of particles having a third mean particle size;
wherein a ratio of the first mean particle size to the second mean particle size is about 2 or greater; and
wherein a ratio of the first mean particle size to the third mean particle size is about 2 or greater.
2. The binder composition of claim 1 , wherein the first binder material and the second binder material are each independently chosen from alumina-containing materials, silica-containing materials, zirconia-containing materials, ceria-containing materials, lanthana-containing materials, yttria-containing materials, and combinations thereof.
3. The binder composition of claim 1 , wherein the first binder material is an alumina-containing material, and the second binder material is a zirconia-containing material.
4. The binder composition of claim 1 , wherein the first mean particle size ranges from about 50 nm to about 1000 nm.
5. The binder composition of claim 1 , wherein the second mean particle size ranges from about 10 nm to about 500 nm.
6. The binder composition of claim 1 , wherein the first binder material and the second binder material are present in a concentration ratio of about 0.01 to about 0.5.
7. The binder composition of claim 1 , wherein one or both of the first binder material and the second binder material is catalytic.
8. A washcoat slurry comprising:
a liquid medium;
a binder composition according to claim 1 .
9. The washcoat slurry of claim 8 , wherein the binder composition is present in an amount ranging from about 0.01 g/in 3 to about 1.0 g/in 3 , and wherein the washcoat slurry has a viscosity ranging from about 300 s −1 of about 100 cP or less.
10. The washcoat slurry of claim 9 , wherein the washcoat slurry has a viscosity at about 300 s −1 of about 50 cP or less.
11. The washcoat slurry of claim 8 , further comprising a catalyst material.
12. A catalyst article comprising a catalyst substrate having a plurality of channels adapted for gas flow, wherein each channel has a wall surface in adherence to a catalytic coating comprising a binder composition according claim 1 .
13. The catalyst article of claim 12 , wherein the catalytic coating comprises a catalyst material in combination with the binder composition.
14. The catalyst article of claim 12 , wherein the catalyst substrate is a honeycomb comprising a wall flow filter substrate or a flow through substrate.
15. The catalyst article of claim 12 , wherein the catalytic coating is present on the substrate with a loading of at least about 1.0 g/in 3 .
16. The catalyst article of claim 12 , wherein the catalyst substrate includes a first coating layer of the catalytic coating and includes a second coating layer of a different overall composition overlying at least a portion of the first coating layer of the catalytic coating.
17. The catalyst article of claim 16 , wherein one or both of the following conditions is met:
the first binder material is present in an amount ranging from about 0.1 wt % to about 5 wt % of a total dry gain of the first coating layer of the catalytic coating;
the second binder material is present in an amount ranging from about 7 wt % to about 20 wt % of the total dry gain of the first coating layer of the catalytic coating.
18. An emission treatment system for treatment of an exhaust gas stream, the emission treatment system comprising:
i. an engine producing an exhaust gas stream; and
ii. a catalyst article according to claim 12 positioned downstream from the engine and in fluid communication with the exhaust stream.