Polypropylene polymer composition having high stiffness properties
View Patent ↗Polypropylene polymer compositions are disclosed that have excellent stiffness properties. The polypropylene polymer compositions are made by combining a first polypropylene polymer with a second polypropylene polymer. The combination of polymers has been found to produce a composition having high stiffness properties in addition to excellent toughness properties. In addition, the polymer composition has good flow properties for being molded into various products and articles. Of particular advantage, the different polypropylene polymers can be produced at relatively high catalyst activity, especially in comparison to high crystalline polymers made in the past.
1. A polypropylene polymer composition comprising:
a first polypropylene polymer combined with a second polypropylene polymer, the first polypropylene polymer has a melt flow rate of from about 0.1 g/10 min to about 3 g/10 min and a xylene soluble content of from about 2.5% by weight to about 7% by weight,
the second polypropylene polymer has a melt flow rate of from about 5 g/10 min to about 100 g/10 min and a xylene soluble content of from about 2.5% by weight to about 7% by weight; and
wherein the polypropylene polymer composition has a flexural modulus according to the following formula:
FX≥ 2072* XS − 0.18
wherein FX is flexural modulus and XS is xylene soluble content of the polypropylene polymer composition, the xylene soluble content of the polypropylene polymer composition is from about 2.5% to about 7% by weight.
2. The polypropylene polymer composition of claim 1 , where one of the polypropylene polymers has a xylene soluble content of greater than 5% by weight and the other polypropylene polymer has a xylene soluble content of less than about 4% by weight.
3. The polypropylene polymer composition of claim 1 , wherein the first polypropylene polymer is present in the polymer composition in an amount less than about 66% by weight, and in an amount greater than about 30%.
4. The polypropylene polymer composition of claim 1 , wherein the polypropylene polymer composition contains a nucleating agent.
5. The polypropylene polymer composition of claim 1 , wherein the polypropylene polymer composition does not contain a nucleating agent.
6. The polypropylene polymer composition of claim 1 , wherein the polypropylene polymer composition has a melt flow rate of from about 0.5 g/10 min to about 30 g/10 min and has a xylene soluble content of from about 3% to about 7% by weight.
7. The polypropylene polymer composition of claim 1 , wherein the polypropylene polymer composition has a polydispersity index of from about 5 to about 10.
8. The polypropylene polymer composition of claim 1 , wherein the first polypropylene polymer has a polydispersity index of from about 4 to about 5.5 and the second polypropylene polymer has a polydispersity index of from about 4 to about 5.5.
9. The polypropylene polymer composition of claim 1 , wherein a weight ratio between the first polypropylene polymer and the second polypropylene polymer is from about 5:95 to about 80:20.
10. The polypropylene polymer composition of claim 1 , wherein the first polypropylene polymer and the second polypropylene polymer both comprise non-phthalate Ziegler-Natta catalyzed polypropylene polymers.
11. The polypropylene polymer composition of claim 1 , wherein the polypropylene polymer composition has a flexural modulus of from about 1,500 MPa to about 2,500 MPa.
12. The polypropylene polymer composition of claim 1 , wherein the polypropylene polymer composition has a melt flow rate of from about 0.5 g/10 min to about 3 g/10 min.
13. The polypropylene polymer composition of claim 12 , wherein the polypropylene polymer composition has a xylene soluble content of from 3.5% by weight to 7% by weight.
14. The polypropylene polymer composition of claim 1 , wherein the polypropylene polymer composition has a melt flow rate of from about 5 g/10 min to about 30 g/10 min.
15. The polypropylene polymer composition of claim 1 , wherein the polypropylene polymer composition has an IZOD impact resistance of greater than about 40 J/m and less than about 90 J/m.
16. A polymer article formed from the polypropylene polymer composition of claim 1 .
17. The polymer article of claim 16 , wherein the polymer article comprises a storage or packaging container.