Catalytic article and method of manufacturing the catalytic article
The presently claimed invention provides a catalytic article and an exhaust gas treatment system. The catalytic article comprises platinum supported on a first support comprising ceria containing metal oxide component; rhodium supported on a second support selected from a refractory alumina component, an oxygen storage component or a combination thereof; and a substrate, wherein said catalytic article is essentially free of palladium. The presently claimed invention also provides a process for preparing the catalytic article and use of the catalytic article and the exhaust gas treatment system for purifying a gaseous exhaust stream comprising hydrocarbons, carbon monoxide, and nitrogen oxide.
1 . A catalytic article comprising:
a bi-layered article comprising:
platinum supported on a first support comprising a ceria containing metal oxide component selected from ceria-alumina, ceria-yttrium-alumina, ceria-silica-alumina, ceria-tin-alumina, ceria-manganese alumina, ceria-iron-alumina, ceria-nickel-alumina, ceria-iridium-alumina, ceria-ruthenium-alumina, ceria-indium-alumina, ceria-titania-alumina ceria-titania, or any combination thereof, wherein the ceria content of the ceria-containing metal oxide component ranges from 1.0 wt. % to 80.0wt. %, based on the total weight of the ceria-containing metal oxide component;
rhodium supported on a second support chosen from a refractory alumina component, an oxygen storage component, and a combination thereof; and
a substrate,
wherein the catalytic article is essentially free of palladium; and
wherein the catalytic article exhibits hydrothermal stability at an aging temperature of greater than 950° C.
2 . The catalytic article according to claim 1 , wherein the first support further comprises a refractory alumina component.
3 . The catalytic article according to claim 1 , wherein the second support comprises a combination of a refractory alumina component and an oxygen storage component.
4 . The catalytic article according to claim 1 , wherein the catalytic article is a bi-layered article comprising a first layer, a second layer, and a substrate, wherein the first layer comprises platinum supported on a ceria containing metal oxide component and a refractory alumina component, deposited on the substrate, and the second layer comprises rhodium supported on a support chosen from a refractory alumina component, an oxygen storage component, and a combination thereof, deposited on the first layer.
5 . The catalytic article according to claim 1 , wherein the catalytic article is a bi-layered article comprising a first layer, a second layer, and a substrate, wherein the first layer comprises rhodium supported on a support chosen from a refractory alumina component, an oxygen storage component, and a combination thereof, deposited on the substrate, and the second layer comprises platinum supported on a ceria containing metal oxide component and refractory alumina component deposited on the first layer.
6 . The catalytic article according to claim 1 , wherein the amount of platinum ranges from 0.1 wt. % to 10.0 wt. %, based on the total weight of the first support and the amount of rhodium ranges from 0.1 wt. % to 10.0 wt. %, based on the total weight of the second support.
7 . The catalytic article according to claim 1 , wherein the ceria content of the ceria-containing metal oxide component ranges from 5.0 wt. % to 50.0 wt. %, based on the total weight of the ceria-containing component.
8 . The catalytic article according to claim 1 , wherein the ceria content of the ceria-containing metal oxide component ranges from 5.0 wt. % to 30 wt. %, based on the total weight of the ceria-containing component.
9 . The catalytic article according to claim 1 , wherein the refractory alumina component comprises alumina, lanthana-alumina, ceria-alumina, titania-alumina, ceria-zirconia-alumina, zirconia-alumina, lanthana-zirconia-alumina, baria-alumina, baria-lanthana-alumina, baria-lanthana-neodymia-alumina, or any combination thereof.
10 . The catalytic article according to claim 1 , wherein the oxygen storage component comprises ceria-zirconia, ceria-zirconia-lanthana, ceria-zirconia-yttria, ceria-zirconia-lanthana-yttria, ceria-zirconia-neodymia, ceria-zirconia-praseodymia, ceria-zirconia-lanthana-neodymia, ceria-zirconia-lanthana-praseodymia, ceria-zirconia-lanthana-neodymia-praseodymia, or any combination thereof.
11 . The catalytic article according to claim 1 , wherein the oxygen storage component comprises ceria in an amount ranging from 5.0 wt. % to 100 wt. %, based on the total weight of the oxygen storage component.
12 . The catalytic article according to claim 1 , wherein the catalytic article is loaded with an amount ranging from 1.0 g/ft 3 to 300 g/ft 3 of platinum supported on the ceria containing metal oxide component and an amount ranging from 1.0 g/ft 3 to 100 g/ft 3 of rhodium supported on a support chosen from a refractory alumina component, an oxygen storage component or any combination thereof.
13 . The catalytic article according to claim 1 , wherein platinum is thermally or chemically fixed.
14 . The catalytic article according to claim 1 , wherein the amount of palladium is less than 0.001 wt. %, based on the total weight of the support in the catalytic article.
15 . The catalytic article according to claim 1 , wherein the substrate is chosen from a ceramic substrate, a metal substrate, a ceramic foam substrate, a polymer foam substrate, and a woven fibre substrate.
16 . The catalytic article according to claim 1 , wherein the catalytic article is essentially free of barium oxide.
17 . A process for the preparation of a catalytic article according to claim 1 , wherein process comprises preparing a slurry comprising platinum supported on a first support comprising a ceria containing metal oxide component and optionally a refractory alumina component, and rhodium supported on a second support chosen from a refractory alumina component, an oxygen storage component, and a combination thereof, depositing the slurry on a substrate to obtain a catalytic article followed by calcination at a temperature ranging from 400° C. to 700° C., wherein the step of preparing the slurry comprises a technique chosen from incipient wetness impregnation, incipient wetness co-impregnation, and post-addition.
18 . A process for the preparation of a catalytic article according to claim 1 , wherein the process comprises preparing a first layer slurry comprising platinum supported on a first support comprising a ceria containing metal oxide component and optionally a refractory alumina component, and a second layer slurry comprising rhodium supported on a second support chosen from a refractory alumina component, an oxygen storage component, and a combination thereof; depositing the first layer slurry on a substrate to obtain a first layer and depositing the second layer slurry on the first layer to obtain a second layer, followed by calcining at a temperature ranging from 400° C. to 700° C., wherein the step of preparing the slurry comprises a technique chosen from incipient wetness impregnation, incipient wetness co-impregnation, and post-addition.
19 . An exhaust gas treatment system for internal combustion engines, the system comprising the catalytic article according to claim 1 .
20 . The exhaust gas treatment system according to claim 19 , wherein the system comprises a platinum group metal based three-way conversion (TWC) catalytic article and the catalytic article, wherein the platinum group metal based three-way conversion (TWC) catalytic article is positioned downstream from an internal combustion engine and the catalytic article is positioned downstream in fluid communication with the platinum group metal based three-way conversion (TWC) catalytic article.
21 . The exhaust gas treatment system according to claim 19 , wherein the system comprises a platinum group metal based three-way conversion (TWC) catalytic article and the catalytic article, wherein the catalytic article is positioned downstream from an internal combustion engine and the platinum group metal based three-way conversion (TWC) catalytic article is positioned downstream in fluid communication with the three-way conversion (TWC) catalytic article.
22 . A method of treating a gaseous exhaust stream comprising hydrocarbons, carbon monoxide, and nitrogen oxide, wherein the method comprises contacting the exhaust stream with the catalytic article according to claim 1 .
23 . A method of reducing hydrocarbons, carbon monoxide, and nitrogen oxide levels in a gaseous exhaust stream, the method comprising contacting the gaseous exhaust stream with the catalytic article according to claim 1 to reduce the levels of hydrocarbons, carbon monoxide, and nitrogen oxide in the exhaust gas.