IP Library Granted Patent US 12,104,049
Granted Patent B2
US 12,104,049 · App. 17/598,494 · Granted Oct 1, 2024

Compatibilization of recycled polyethylene-polypropylene blends

Inventors: Susanne Kahlen (Linz, AT); Hermann Braun (Linz, AT); Yi Liu (Linz, AT); Markus Gahleitner (Linz, AT); Gerhard Hubner (Linz, AT)
Assignee: BOREALIS AG
C08L23/16C08J3/005C08L23/06C08L23/12C08L2205/03C08L2207/20
View Patent ↗
Loading inventors, assignments & file history…
Monitor This Case
Get email alerts when status or documents change.
Order Certified Copies
Most orders are placed with the USPTO same day — all within 24 business hours.
Order via The Patent Place →
Pre-filled with this patent's details
Quick Facts
Patent No.
US 12,104,049
App. No.
17/598,494
Granted
Oct 1, 2024
Kind
B2
Abstract

The present invention is directed to a polyethylene-polypropylene composition comprising a blend (A) being a recycled material, said blend comprising polypropylene and polyethylene, and a compatibilizer (B) being a C 2 C 3 C 4 terpolymer. Further, the present invention is directed to an article comprising said polyethylene-polypropylene composition and a process for preparing said polyethylene-polypropylene composition. The present invention is also directed to the use of a compatibilizer (B) being a C 2 C 3 C 4 terpolymer for improving the impact-stiffness balance and the morphology of the blend (A).

Claims (34)

1. A polyethylene-polypropylene composition, obtained by blending:

a) 85.0 to 99.0 wt. %, based on an overall weight of the polyethylene-polypropylene composition, of a blend (A) comprising:

i) polypropylene, and

ii) polyethylene,

wherein a weight ratio of polypropylene to polyethylene is in a range of 3:7 to 7:3, and

wherein blend (A) is a recycled material, which is recovered from a waste plastic material derived from post-consumer and/or industrial waste;

and

b) 1.0 to 15.0 wt. %, based on the overall weight of the polyethylene-polypropylene composition, of a compatibilizer (B) which is a C 2 C 3 C 4 terpolymer having a density determined according to ISO 1183 equal or below 880 kg/m 3 .

2. The polyethylene-polypropylene composition according to claim 1 , wherein the C 2 C 3 C 4 terpolymer has a melt flow rate MFR 2 (230° C., 2.16 kg) determined according to ISO 1133 in a range of 2.0 to 40.0 g/10 min.

3. The polyethylene-polypropylene composition according to claim 1 , wherein a weight ratio between the blend (A) and the compatibilizer (B) is in a range of 99:1 to 5:1.

4. The polyethylene-polypropylene composition according to claim 1 , wherein the C 2 C 3 C 4 terpolymer has:

i) an ethylene content in a range of 2.0 to 15.0 wt. %, and/or

ii) a 1-butene content in a range of 5.0 to 30.0 wt. %, based on an overall weight of the C 2 C 3 C 4 terpolymer.

5. The polyethylene-polypropylene composition according to claim 1 , wherein the C 2 C 3 C 4 terpolymer has a melting temperature Tm determined according to ISO 11357-below 180° C. a range of 150 to 165° C.

6. The polyethylene-polypropylene composition according to claim 1 , wherein the C 2 C 3 C 4 terpolymer has a glass transition temperature Tg-below −5° C. in a range of −25 to −12° C.

7. The polyethylene-polypropylene composition according to claim 1 , wherein blend (A) has a content of limonene as determined by using solid phase microextraction (HS-SPME-GC-MS) of

(i) from 1 ppm-to 100 ppm or

(ii) from 0.10 ppm to less than 1 ppm.

8. The polyethylene-polypropylene composition according to claim 1 , wherein blend (A) has a relative amount of units derived from ethylene of greater than 20 wt. %, based on an overall weight of blend (A).

9. The polyethylene-polypropylene composition according to claim 1 , wherein blend (A) contains:

i) up to 6.0 wt. % polystyrene, and/or

ii) up to 3 wt. % talc, and/or

iii) up to 5.0 wt. %, polyamide, and/or

iv) up to 3 wt. % chalk,

based on an overall weight of blend (A).

10. The polyethylene-polypropylene composition according to claim 1 , having a melt flow rate MFR 2 (230° C., 2.16 kg) determined according to ISO 1133 in a range of 0.1 to 50.0 g/10 min.

11. The polyethylene-polypropylene composition according to claim 1 , having a Charpy notched impact strength determined according to ISO 179/1eA at 23° C. of at least 6.0 KJ/m 2 .

12. The polyethylene-polypropylene composition according to claim 1 , having a tensile modulus determined according to ISO 527-2 of at least 600 MPa.

13. An article, comprising the polyethylene-*polypropylene composition according to claim 1 .

14. A process for preparing the polyethylene-polypropylene composition according to claim 1 , comprising the steps of:

a) providing the blend (A) in an amount of 85.0 to 99.0 wt. %, based on the overall weight of the polyethylene-polypropylene composition,

b) providing the compatibilizer (B) in an amount of 1.0 to 15.0 wt. %, based on the overall weight of the polyethylene-polypropylene composition,

c) melting and mixing a blend of blend (A) and the compatibilizer (B), optionally in the presence of 0 to 1.0 wt. % of a stabilizer or a mixture of stabilizers, and

d) optionally pelletizing.

Assignments (2)
CHANGE OF ADDRESS Recorded Feb 23, 2022
From: BOREALIS AG
To: BOREALIS AG
Reel/Frame 059219/0949 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Nov 11, 2021
From: KAHLEN, SUSANNE; BRAUN, HERMANN; LIU, YI; GAHLEITNER, MARKUS; HUBNER, GERHARD
To: BOREALIS AG
Reel/Frame 058086/0394 →