IP Library Granted Patent US 11,512,189
Granted Patent B2
US 11,512,189 · App. 17/598,572 · Granted Nov 29, 2022

Recycled polyethylene-polypropylene blends comprising a compatibilizer

Inventors: Susanne Kahlen (Linz, AT); Hermann Braun (Linz, AT); Yi Liu (Linz, AT); Markus Gahleitner (Linz, AT); Gerhard Hubner (Linz, AT)
Assignee: BOREALIS AG
C08L23/06C08J11/04C08L23/12C08L2207/20
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Quick Facts
Patent No.
US 11,512,189
App. No.
17/598,572
Granted
Nov 29, 2022
Kind
B2
Abstract

The present invention is directed to a polyethylene-polypropylene composition comprising a blend (A) being a recycled material, said blend comprising polypropylene and polyethylene, and a compatibilizer (B) being a copolymer of 1-butene and ethylene. Further, the present invention is directed to an article comprising said polyethylene-polypropylene composition and a process for preparing said polyethylene-polypropylene composition. The present invention is also directed to the use of a compatibilizer (B) being a copolymer of 1-butene and ethylene for improving the impact-stiffness balance and the morphology of the blend (A).

Claims (28)

1. A polyethylene-polypropylene composition, obtainable by blending:

a) 75.0 to 94.0 wt. %, based on the overall weight of the polyethylene-polypropylene composition, of a blend (A) comprising:

i) polypropylene, and

ii) polyethylene,

wherein the weight ratio of polypropylene to polyethylene is in the range of 3:7 to 7:3, and

wherein blend (A) is a recycled material, which is recovered from a waste plastic material derived from post-consumer and/or industrial waste;

and

b) 6.0 to 25.0 wt. %, based on the overall weight of the polyethylene-polypropylene composition, of a compatibilizer (B) being a copolymer of 1-butene and ethylene, wherein the copolymer of 1-butene and ethylene has 1-butene content of at least 70 wt. %, based on the overall weight of the copolymer of 1-butene and ethylene.

2. The polyethylene-polypropylene composition according to claim 1 , wherein the copolymer of 1-butene and ethylene has a density determined according to ISO 1183 equal or below 930 kg/m 3 .

3. The polyethylene-polypropylene composition according to claim 1 , wherein the copolymer of 1-butene and ethylene has a melt flow rate MFR 2 (190° C., 2.16 kg) determined according to ISO 1133 in the range of 1.0 to 20.0 g/10 min.

4. The polyethylene-polypropylene composition according to claim 1 , wherein the copolymer of 1-butene and ethylene has a melting temperature Tm determined according to ISO 11357 below 130° C.

5. The polyethylene-polypropylene composition according to claim 1 , wherein blend (A) has a content of limonene as determined by using solid phase microextraction (HS-SPME-GC-MS) of 0.10 to 100 ppm.

6. The polyethylene-polypropylene composition according to claim 1 , wherein blend (A) has a relative amount of units derived from ethylene of greater than 40 wt. %, based on the overall weight of blend (A).

7. The polyethylene-polypropylene composition according to claim 1 , wherein blend (A) contains:

i) up to 6.0 wt. % polystyrene, and/or

ii) up to 3 wt. % talc, and/or

iii) up to 5.0 wt. % polyamide, and/or

iv) up to 3 wt. % chalk,

based on the overall weight of blend (A).

8. The polyethylene-polypropylene composition according to claim 1 , having a melt flow rate MFR 2 (2.16 kg, 230° C.) determined according to ISO 1133 in the range of 4.0 to 10.0 g/10 min.

9. The polyethylene-polypropylene composition according to claim 1 , having a Charpy notched impact strength determined according to ISO 179/1 eA at 23° C. of at least 6.0 kJ/m 2 .

10. The polyethylene-polypropylene composition according to claim 1 , having a tensile modulus determined according to ISO 527-2 in the range of 640 to 770 MPa.

11. An article, comprising the polyethylene-polypropylene composition according to claim 1 .

12. A process for preparing the polyethylene-polypropylene composition according to claim 1 , comprising the steps of:

a) providing the blend (A) in an amount of 75.0 to 94.0 wt. %, based on the overall weight of the polyethylene-polypropylene composition,

b) providing the compatibilizer (B) being a copolymer of 1-butene and ethylene in an amount of 6.0 to 25.0 wt. %, based on the overall weight of the polyethylene-polypropylene composition, wherein the copolymer of 1-butene and ethylene has a 1-butene content of at least 70.0 wt. %, based on the overall weight of the copolymer of 1-butene and ethylene,

c) melting and mixing the blend of blend (A) and the compatibilizer (B), optionally in the presence of 0 to 1.0 wt. % of a stabilizer or a mixture of stabilizers, and

d) optionally pelletizing.

Assignments (2)
CHANGE OF ADDRESS Recorded Feb 23, 2022
From: BOREALIS AG
To: BOREALIS AG
Reel/Frame 059219/0949 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Nov 11, 2021
From: KAHLEN, SUSANNE; BRAUN, HERMANN; LIU, YI; GAHLEITNER, MARKUS; HUBNER, GERHARD
To: BOREALIS AG
Reel/Frame 058087/0012 →
Priority Claims (2)
EP 19166181 · Mar 29, 2019 · regional
WO PCT/EP2020/058578 · Mar 26, 2020 · international
Continuity (1)
Related Publication 20220177679A1 · Jun 9, 2022