System and method of producing carbon nanotubes
A system and method of producing carbon nanotubes from flare gas and other gaseous carbon-containing sources.
1. A method of producing carbon nanotubes, comprising:
(i) obtaining a flare gas comprising carbonaceous gases;
(ii) treating the flare gas by subjecting the flare gas to one or more processes to remove at least a portion of any excess hydrogen sulfide from the flare gas;
(iii) introducing a mixture of the flare gas, catalyst, and hydrogen into a reactor;
(iv) permitting the carbon atoms of the carbonaceous gases to interact with the catalyst to produce carbon nanotubes; and
(v) collecting the carbon nanotubes.
2. The method of claim 1 , wherein the flare gas is obtained from an oil or gas production site, refinery, chemical plant, coal plant, or landfill.
3. The method of claim 1 , wherein the step of treating the flare gas comprises further subjecting the flare gas to one or more processes to remove at least a portion of any excess carbon dioxide and/or carbon monoxide from the flare gas.
4. The method of claim 1 , wherein the step of treating the flare gas comprises at least one of (i) electrochemically reducing at least a portion of any excess hydrogen sulfide in the flare gas to sulfur and thereafter removing such and (ii) oxidizing at least a portion of any excess hydrogen disulfide in the flare gas to sulfuric acid and removing such.
5. The method of claim 3 , wherein at least a portion of any excess carbon monoxide and/or carbon dioxide in the flare gas are scrubbed from the flare gas.
6. The method of claim 1 , wherein the catalyst is ferrocene, which becomes iron particles at the temperature in the reactor.
7. The method of claim 1 , wherein a portion of the mixture containing carbonaceous gases that did not interact with the catalyst to form carbon nanotubes is sent to a second reactor, optionally, with an additional amount of natural gas or treated or untreated flare gas.
8. The method of claim 7 , wherein an amount of the catalyst is collected from the mixture and then reconditioned and introduced into the second reactor, optionally, with an amount of fresh catalyst, or stored for later use.
9. The method of claim 8 , wherein the catalyst is reconditioned by at least one of (i) oxidizing the catalyst in air and/or exfoliating the catalyst by electrochemical treatment, dissolving the catalyst in muriatic acid to form a chloride salt, and then reacting the chloride salt with sodium cyclopentadienide; and (ii) heating the catalyst to at least 2000° C. to vaporize the catalyst and then plate out the vaporized catalyst.
10. The method of claim 1 , wherein the hydrogen formed from the decomposition of the carbonaceous gas is separated and either collected for storage or resale, used as a fuel to heat the reactor, and/or introduced into another reactor.
11. The method of claim 1 , wherein the carbon nanotubes formed in the reactor are subjected to (i) one or more high velocity jets of gas, (ii) one or more spinning impellers, (iii) a gas flow across a textured surface, and/or (iv) impact with an array of blunt objects before exiting the reactor such that the carbon nanotubes collected in step (v) are in the form of short carbon nanotube fibers having lengths in a range of from 1 mm to about 50 mm, or more preferably about 25 mm.