Conductive nanostructure purification
A method of purifying a metal nanostructure composition containing desired nanostructures and undesired nanostructures. The method includes providing a solution within which metal nanostructures have been synthesized including desired and undesired nanostructures. The solution includes polyol and has a viscosity. The method includes diluting the solution with a dilutant to lower the viscosity of the solution and provide a diluted solution. The method includes sedimenting the undesired nanostructures from the diluted solution. The method includes collecting the supernatant with the desired nanostructures and retaining the undesired nanostructures inside the sedimentation device. In an example, such is via a sedimentation device, which is a special tray system designed with grooved bottoms to retain the undesired nanostructures.
1. A method of purifying a metal nanostructure composition, the method comprising:
providing a solution within which metal nanostructures have been synthesized including first aspect ratio nanostructures and second aspect ratio nanostructures having an aspect ratio lower than the first aspect ratio nanostructures, the solution including a polyol and having a viscosity;
diluting the solution with a dilutant to lower the viscosity of the solution and provide a diluted solution; and
sedimenting the second aspect ratio nanostructures from the diluted solution, wherein the method includes introducing the diluted solution into a device that aids in retention of the first aspect ratio nanostructures in the diluted solution and removal of the second aspect ratio nanostructures that are sedimented from the diluted solution and the device includes a tray having a grooved bottom orientated traverse to an outflow direction associated with an outlet of the device.
2. The method of claim 1 , wherein the first aspect ratio nanostructures remain in the diluted solution.
3. The method of claim 1 , wherein the second aspect ratio nanostructures have all dimensions of at least 50 nm.
4. The method of claim 1 , wherein the device has a depth that is no more than 1 inch.
5. The method of claim 4 , wherein a depth of the tray is no more than 0.5 inch.
6. The method of claim 5 , wherein a depth of the tray is no more than 0.25 inch.
7. The method of claim 1 , wherein the grooved bottom has elongated troughs.
8. The method of claim 7 , wherein the elongated troughs have a V shape and have a width less than 0.1 inch and a height less than 0.05 inches.
9. The method of claim 1 , including introducing the diluted solution into multiple devices that aid in retention of the first aspect ratio nanostructures in the diluted solution and removal of the second aspect ratio nanostructures that are sedimented from the diluted solution, and subsequently simultaneously operating upon the multiple devices.
10. The method of claim 1 , wherein the dilutant includes at least one of water or alcohol.
11. The method of claim 1 , wherein the dilutant is an alcohol.
12. The method of claim 1 , wherein the polyol includes ethylene glycol.
13. The method of claim 1 , wherein the polyol includes propylene glycol.
14. The method of claim 1 , wherein the polyol includes glycerol.
15. The method of claim 1 , wherein the step of sedimenting the second aspect ratio nanostructures from the diluted solution occurs for a time period of 5 days or less.
16. The method of claim 1 , wherein the step of sedimenting the second aspect ratio nanostructures from the diluted solution occurs for a time period of 3 days or less.