Impact resistant hydrophobic high heat optical acrylic copolymers
The invention relates to impact resistant acrylic copolymers and terpolymers incorporating high Tg, hydrophobic (meth)acrylates and derivatives that have high thermal stability and excellent impact resistance. These copolymers have a Tg of 114-130° C., along with high molecular weight and high impact resistance. The copolymer is found to exhibit high heat resistance, high light transmission, low haze, low moisture uptake, excellent environmental stability, excellent high temperature thermal stability, and excellent mechanical properties, along with excellent UV resistance. The copolymer, or terpolymer may be used in many applications, including, but not limited to automotive parts, lighting pipes, thin wall parts, optical lenses, extruded optical films, (co-)extruded sheets/profiles, thermo-formable sheets, injection molded parts, and composites.
1 . A composition comprising:
a) an acrylic copolymer comprising:
1) From 0.1 to 20 weight percent monomer units chosen from tert-butyl cyclohexyl methacrylate, 3,3,5-trimethylcyclohexyl (meth) acrylate, and a mixture thereof, wherein said tert-butyl cyclohexyl methacrylate and/or 3,3,5-trimethylcyclohexyl (meth) acrylate monomer units have a trans/cis ratio of from 30/70 to 85/15;
2) from 80 to 99.1 weight percent methylmethacrylate monomer units;
3) Optionally from 0 to 25 weight percent of other monomer units copolymerizable with methylmethacrylate;
the weight percents being based on the total monomer units in the acrylic copolymer, wherein said acrylic copolymer has a Tg of from 114° C. to 140° C.; and
b) from 5 to 60 weight percent of impact modifiers, based on total composition weight, wherein said impact modifiers comprise a core-shell polymer having a hard core with a Tg of greater than 20° C., one or more elastomeric intermediate layers, and at least one hard shell having a Tg of greater than 20° C.,
wherein the composition has a Total Light Transmission (TLT) of at least 89%,
wherein the composition has an optical haze of less than 4.0%, as measured on a 3.22 mm thick plaque, using ASTM D1003, and
wherein the composition has a refractive index of 1.47-1.50 at the wavelength of 589 nm.
2 . The composition of claim 1 , wherein said other monomer units comprise from 0.01 to 25 weight percent of a high Tg comonomer, comprising at least one of methacrylic acid, acrylic acid, itaconic acid, alpha methyl styrene, maleic anhydride, maleimide, isobornyl methacrylate, norbornyl methacrylate, t-butyl methacrylate, cyclohexyl methacrylate, acrylamide and methacrylamide, and mixtures thereof.
3 . The composition of claim 1 , wherein said other monomer units comprise from 0.01 to 6 weight percent of methacrylic acid.
4 . The composition of claim 1 , wherein said acrylic copolymer has a weight average molecular weight of from 55,000 g/mole to 250,000 g/mole.
5 . The composition of claim 1 , wherein said impact modifiers comprise a self-assembling, nanostructured acrylic block copolymer.
6 . The composition of claim 1 , wherein said impact modifiers comprise a blend of 1-20 weight percent of a self-assembling, nanostructured acrylic block copolymer, and 5 to 40 weight percent of one or more core-shell impact modifiers, based on the total weight of the composition.
7 . The composition of claim 1 , further comprising from 5 to 95 weight percent of one or more compatible polymers, based on the weight of the total polymer solids.
8 . The composition of claim 1 , further comprising 50 to 3500 ppm of one or more antioxidants, based on the weight of the polymer solids.
9 . An article comprising the composition of claim 1 , wherein said article is at least one of automotive front lenses, thin wall pats, lighting pipes, solar back sheets, optical lenses, optical films for electronics, thermo-formable sheets, injection molded parts, extruded surface layers, (co-) extruded sheets and profiles, and composites.
10 . A composition comprising:
a) an acrylic copolymer comprising:
1) From 0.1 to 20 weight percent monomer units chosen from tert-butyl cyclohexyl methacrylate, 3,3,5-trimethylcyclohexyl (meth) acrylate, and a mixture thereof, wherein said tert-butyl cyclohexyl methacrylate and/or 3,3,5-trimethylcyclohexyl (meth) acrylate monomer units have a trans/cis ratio of from 30/70 to 85/15;
2) from 80 to 99.1 weight percent methylmethacrylate monomer units;
3) Optionally from 0 to 25 weight percent of other monomer units copolymerizable with methylmethacrylate;
the weight percents being based on the total monomer units in the acrylic copolymer, wherein said acrylic copolymer has a Tg of from 114° C. to 140° C.; and
b) from 5 to 60 weight percent of impact modifiers, based on total composition weight, wherein said impact modifiers comprise acrylic based core-shell structured copolymers,
wherein the composition has a Total Light Transmission (TLT) of at least 89%,
wherein the composition has an optical haze of less than 4.0%, as measured on a 3.22 mm thick plaque, using ASTM D1003, and
wherein the composition has a refractive index of 1.47-1.50 at the wavelength of 589 nm.