Polymer dispersion for coating wood for blocking migratable compounds
The invention relates to an aqueous polymer dispersion, with said polymer comprising, in its structure, monomer units incorporated from a composition of monomers comprising: a) at least one (meth)acrylic monomer which is a C 1 -C 18 (meth)acrylic ester, without any ionic group, b) at least one ethylenically unsaturated monomer carrying at least one carboxylic acid group, c) at least one ethylenically unsaturated monomer carrying a tertiary amine, and with said polymer additionally carrying grafted blocked silane groups in the —Si(OR 1 ) 3 or —Si—R 2 (OR 1 ) 2 or —Si—(R 2 ) 2 (OR 1 ), with R 1 , R 2 being an identical or different C 1 to C 4 alkyl, and with said grafted blocked silane groups being incorporated by at least one or two routes or their combination. The invention also relates to a coating composition comprising said dispersion of the invention and to its use for aqueous protective coating compositions for wood.
1 . A wood substrate coated with at least one coating layer, wherein the coating layer comprises a coating composition, wherein the coating composition comprises at least one polymer dispersion, wherein the polymer dispersion is an aqueous polymer dispersion of a polymer comprising, in its structure, monomer units incorporated from a composition of monomers comprising:
a) at least one (meth)acrylic monomer which is a C 1 -C 18 alkyl or C 6 -C 18 cycloalkyl (meth)acrylic ester, without any ionic group,
b) at least one ethylenically unsaturated monomer carrying at least one carboxylic acid group, and
c) at least one ethylenically unsaturated monomer carrying a tertiary amine, wherein said polymer additionally comprises grafted silane groups in a form of —Si(OR 1 ) 3 or —Si—R 2 (OR 1 ) 2 or —Si—(R 2 ) 2 (OR 1 ), with R 1 , R 2 being an identical or different C 1 to C 4 alkyl, wherein the composition of monomers comprises less than 25% by weight of vinylaromatic monomers, and
wherein said grafted silane groups are incorporated by
(i-a) preparing an aqueous dispersion comprising monomers (a), (b), (c) and silane graft compound (e) and simultaneously
polymerizing monomers (a), (b), and (c) and grafting to their polymerization product silane compound (e) or
(i-b) post-treating an aqueous dispersion comprising the polymerization product of monomers (a), (b), and (c) with graft silane compound (e);
wherein the silane compound (e) comprises at least one silane group and at least one functional group capable of reacting, at least in part, with the carboxylic groups of monomer (b) selected from the group consisting of epoxy-, amino-, thiol-, hydroxyl-, and isocyanate groups.
2 . The wood substrate as claimed in claim 1 , wherein said monomer b) is selected from (meth)acrylic acid, itaconic acid, fumaric acid, maleic acid and crotonic acid.
3 . The wood substrate as claimed in claim 1 , wherein said monomer c) is selected from: 2-dimethylaminoethyl (meth)acrylate, 2-diethylaminoethyl (meth)acrylate, N-(3-(N,N-dimethylamino) propyl) (meth) acrylamide, 3-dimethylaminopropyl (meth)acrylate, 3-diethylaminopropyl (meth)acrylate, 4-(N,N-dimethylamino) styrene, 4-(N,N-diethylamino) styrene, 4-vinylpyridine, 2-dimethylaminoethyl vinyl ether, 2-diethylaminoethyl vinyl ether, 3-dimethylaminopropyl vinyl ether, 3-diethylaminopropyl vinyl ether, 4-dimethylaminobutyl vinyl ether and 6-dimethylaminohexyl vinyl ether.
4 . The wood substrate as claimed in claim 1 , wherein said monomer a) is a C 1 -C 18 alkyl (meth)acrylate chosen from methyl (meth)acrylate, ethyl (meth)acrylate, propyl (meth)acrylate, butyl (meth)acrylate, 2-ethylhexyl (meth)acrylate, isooctyl and n-octyl (meth)acrylate, nonyl (meth)acrylate, decyl (meth)acrylate, lauryl (meth)acrylate and stearyl (meth)acrylate, or a C 6 -C 18 cycloalkyl (meth)acrylate chosen from: cyclohexyl (meth)acrylate with cyclohexyl substituted or unsubstituted by a C 1 -C 4 or C 1 -C 2 alkyl, isobornyl (meth)acrylate, norbornyl (meth)acrylate and dicyclopentadienyl (meth)acrylate.
5 . The wood substrate as claimed in claim 1 , wherein the composition of monomers comprises:
from 50% to 98% of said monomer a),
from 0.5% to 10% of said monomer b),
from 0.5% to 20% of said monomer c),
the % values being % values by weight, with respect to the weight of the composition of monomers.
6 . The wood substrate as claimed in claim 1 , wherein said monomer a) is a mixture of a monomer a1), which is at least one C 1 -C 2 alkyl (meth)acrylate, and a2), which is at least one C 4 -C 18 alkyl (meth)acrylate.
7 . The wood substrate as claimed in claim 6 , wherein said mixture a) comprises, as monomer a1), methyl or ethyl (meth)acrylate and, as monomer a2), butyl or 2-ethylhexyl or lauryl (meth)acrylate.
8 . The wood substrate as claimed in claim 1 , wherein said polymer has a Tg, determined by DSC, with a heating rate of 10° C./min, in two passes, ranging from −20 to 60° C.
9 . The wood substrate as claimed in claim 1 , wherein the aqueous polymer dispersion has a minimum film formation temperature (MFFT) according to the standard ISO 2115:1996 method which ranges from 0 to 60° C.
10 . The wood substrate as claimed in claim 1 , wherein said silane compound e) in route (ii) is selected from: epoxysilanes, aminosilanes, thiosilanes and hydroxysilanes.
11 . The wood substrate as claimed in claimed 1 wherein a comonomer (d) is included in the polymerization mixture of route (i-a) or is incorporated into the polymerization product of route (i-b); the comonomer (d) comprising, in addition to ethylenic unsaturation, at least one of the silane groups —Si(OR 1 ) 3 , —Si(R 2 (OR 1 ) 2 , or —Si(R 2 ) 2 (OR 1 ).
12 . The wood substrate as claimed in claim 11 , wherein said at least one ethylenically unsaturated comonomer d) in route (i) is selected from: (meth)acrylic, vinyl and allyl monomers carrying at least one silane group.
13 . The wood substrate as claimed in claim 1 , wherein said grafted silane groups are present with a content by weight of said comonomer d) and/or of said compound e) ranging from 0.01% to 5% with respect to the dry weight of said polymer.
14 . The wood substrate as claimed in claim 1 , wherein said aqueous polymer dispersion represents from 10% to 60% by dry weight of solids, with respect to the total weight of the solids of said coating composition.
15 . The wood substrate as claimed in claim 1 , wherein the coating composition is an aqueous paint, varnish or stain composition for the protection of wood.
16 . The wood substrate as claimed in claim 1 , wherein the coating composition is a primer and/or topcoat which is resistant to blistering and to the migration of tannins to a wood surface.
17 . The wood substrate as claimed in claim 1 , wherein the coating composition is crosslinkable with or without the addition of a crosslinking agent.
18 . The wood substrate as claimed in claim 1 , wherein the coating layer is a paint layer, a primer layer, a topcoat layer, a varnish layer, or a stain layer.
19 . The wood substrate as claimed in claim 1 , wherein said wood is chosen from: pine, fir, beech, oak, cedar, spruce, poplar, sweet chestnut, cherry, and walnut.