Heterophasic polypropylene composition
A heterophasic polypropylene composition comprises a matrix based on a propylene-random copolymer and a linear low density polyethylene dispersed in the matrix. The heterophasic polypropylene composition has both improved impact strength and reduced amount of fraction soluble in cold xylene (XCS), while maintaining optical properties. Further, the heterophasic polypropylene composition has an optimised ratio of impact strength to the amount of fraction soluble in cold xylene (XCS).p.
1. A heterophasic polypropylene composition (PP-C) comprising
65.0-95.0 wt % of a propylene random copolymer having a comonomer content of 2.0-5.0 wt % and
5.0-35.0 wt % of a linear low density polyethylene (LLDPE) having a density in a range of 905-923 kg/m 3 , when measured according to ISO1183,
wherein the heterophasic polypropylene composition has at least one first melting peak in a range of 110-125° C. and said first melting peak has a melt enthalpy of 30-100 J/g when determined according to ISO11357.
2. The heterophasic polypropylene composition (PP-C) according to claim 1 , comprising 70.0-92.0 wt % of the propylene random copolymer and 8.0-30.0 wt % of the linear low density polyethylene (LLDPE).
3. The heterophasic polypropylene composition (PP-C) according to claim 1 , wherein the heterophasic polypropylene composition (PP-C) has at least a first and a second melting peak.
4. The heterophasic polypropylene composition (PP-C) according to claim 1 , wherein the linear low density polyethylene (LLDPE) has a density of 910 to 921 kg/m 3 and/or an MFR (190/2) of 0.1-30 g/10 min when measured according to ISO1133.
5. The heterophasic polypropylene composition (PP-C) according to claim 1 , wherein the linear low density polyethylene (LLDPE) is a terpolymer of ethylene and two different comonomers selected from alpha olefins having from 4 to 10 carbon atoms.
6. The heterophasic polypropylene composition (PP-C) according to claim 1 , wherein the heterophasic polypropylene composition (PP-C) has a MFR230/2.16 according to ISO1133 of 1.0-60 g/10 min.
7. The heterophasic polypropylene composition (PP-C) according to claim 1 , wherein the LLDPE is produced in the presence of a metallocene catalyst.
8. The heterophasic polypropylene composition (PP-C) according to claim 1 , wherein 30-70 wt % of the propylene random copolymer comprises a polypropylene fraction (A) having comonomer content in a range of from 0.0 to 1.8 wt %.
9. The heterophasic polypropylene composition (PP-C) according to claim 1 , wherein the heterophasic polypropylene composition (PP-C) has:
i) a Charpy notched impact strength (NIS+23° C.) of 6.5-20 KJ/m 2 ;
ii) a fraction soluble in cold xylene (XCS) of 0.1-18.0 wt %, when determined according to ISO 16152 at 25° C.;
iii) a ratio of Charpy notched impact strength to fraction soluble in cold xylene (XCS) (NIS+23° C./XCS) of 0.60 to 1.50; or
a combination thereof.
10. The heterophasic polypropylene composition (PP-C) according to claim 1 , further comprising at least one alpha-nucleating agent, wherein the at least one alpha-nucleating agent is present in a range of 100-10.000 ppm relative to a total amount of the heterophasic polypropylene composition.
11. The heterophasic polypropylene composition (PP-C) according to claim 10 , wherein the heterophasic polypropylene composition comprises two different alpha nucleating agents.
12. The heterophasic polypropylene composition (PP-C) according to claim 1 , wherein the heterophasic polypropylene composition has a Haze of 5.0 to 38.0%, when determined according to ASTM D1003 on 1 mm plaques.
13. The heterophasic polypropylene composition (PP-C) according to claim 1 , wherein the heterophasic polypropylene composition has a flexural modulus according to ISO178 of 700-1600 MPa.
14. An article comprising the heterophasic polypropylene composition (PP-C) according to claim 1 , wherein the article is an injection molded article, a container, a closure cap, a screw cap or a closure system for food or fluid packaging.
15. A method of use of the heterophasic polypropylene composition (PP-C) according to claim 1 , the method comprising making an injection molded article from the heterophasic polypropylene composition.
16. The method of claim 15 , wherein the injection molded article is a closure cap, a screw cap or a closure system for food or fluid packaging.
17. The heterophasic polypropylene composition (PP-C) according to claim 3 , wherein the second melting peak is in a range of 140-165° C., when determined according to ISO11357.
18. The heterophasic polypropylene composition (PP-C) according to claim 5 , wherein the two different comonomers are 1-butene and 1-hexene.
19. The heterophasic polypropylene composition (PP-C) according to claim 5 , wherein the linear low density polyethylene (LLDPE) has a molecular weight distribution (MWD) of 1.5-10.0.
20. The heterophasic polypropylene composition (PP-C) according to claim 10 , wherein the at least one alpha-nucleating agent is a soluble nucleating agent.