Compositions and methods for synthesis of 2,3-dichloro-1,1,1,2-tetrafluoropropane and 2,3,3,3-tetrafluoropropene
A method of synthesizing 2,3,3,3-tetrafluoropropene (1234yf) from 2-chloro-3,3,3-trifluoropropene (1233xf). The 2-chloro-3,3,3-trifluoropropene (1233xf) is reacted in the vapor phase, in the presence of a catalyst, at a temperature and pressure sufficient to selectively convert the 2-chloro-3,3,3-trifluoropropene (1233xf) to 2,3,3,3-tetrafluoropropene (1234yf) without the use of antimony-based catalysts.
1. A composition comprising:
(a) -1-chloro-2,3,3,3-tetrafluoropropene (1224 yd),
(b) at least one of 2,3,3,3-tetrafluoropropene (1234yf) and 1-chloro-trifluoropropyne,
(c) optionally 1,2-dichloro-3,3,3-trifluoropropene (1223xd), and
(d) at least one additional compound selected from 2-chloro-3,3,3-trifluoropropene (1233xf), 3,3,3-trifluoropropene (1243zf), 2-chloro-1,1,1,2 tetrafluoropropane (244bb), 2-bromo-3,3,3-trifluoropropene (1233xfB), 2,3-dichloro-1,1,1-trifluoropropane (243 db), 3,3,3-trifluoropropyne, 1-chloro-1,2,3,3,3-pentafluoropropene (1215yb), 2-chloro-1,3,3,3-tetrafluoropropene (1224xe), 3-chloro-1,1,1-trifluoropropane (253fb), 1,1,1,2-tetrafluoropropane (254eb), 1,1-dichloro-2,3,3,3-tetrafluoroprop-1-ene (1214ya), 2,2-dichloro-1,1,1-trifluoroethane (123), and 2-chloro-1,1,1,2-tetrafluoroethane (124),
wherein the amount of 1-chloro-2,3,3,3-tetrafluoropropene (1224 yd) is greater than the amount of the at least 2,3,3,3-tetrafluoropropene (1234yf) and 1-chloro-trifluoropropyne, optional 1,2-dichloro-3,3,3-trifluoropropene (1223xd), and the at least one additional compound.
2. The composition of claim 1 wherein the amount of the at least one of 2,3,3,3-tetrafluoropropene (1234yf) and 1-chloro-trifluoropropyne, optional 1,2-dichloro-3,3,3-trifluoropropene (1223xd), and the at least one additional compound ranges from greater than 0 to about 8% by weight based on the total amount of the composition.
3. The composition of claim 1 wherein 1-chloro-trifluoropropyne is present.
4. The composition of claim 1 , comprising between greater than 0 and about 10 wt % 1,2-dichloro-3,3,3-trifluoropropene (1223xd) based on the total amount of the composition.
5. The composition of claim 1 wherein 2,3,3,3-tetrafluoropropene (1234yf) is present in an amount of between >0 and less than about 0.02% by weight, based on the total amount of the composition.
6. The composition of claim 1 wherein 2,3-dichloro-1,1,1-trifluoropropane (243 db) is present.
7. A composition comprising 1-chloro-2,3,3,3-tetrafluoropropene (1224 yd), 1-chloro-trifluoropropyne, and at least one additional compound selected from the group consisting of 2-chloro-3,3,3-trifluoropropene (1233xf), 2,3,3,3-tetrafluoropropene (1234yf), 3,3,3-trifluoropropene (1243zf), 2-chloro-1,1,1,2 tetrafluoropropane (244bb), (2-bromo-3,3,3-trifluoropropene (1233xfB), 2,3-dichloro-1,1,1-trifluoropropane (243 db), 3,3,3-trifluoropropyne, 1-chloro-1,2,3,3,3-pentafluoropropene (1215yb), 1,2-dichloro-3,3,3-trifluoropropene (1223xd), 2-chloro-1,3,3,3-tetrafluoropropene (1224xe), 3-chloro-1,1,1-trifluoropropane (253fb), 1,1-dichloro-2,3,3,3-tetrafluoroprop-1-ene (1214ya), 2,2-dichloro-1,1,1-trifluoroethane (123), and 2-chloro-1,1,1,2-tetrafluoroethane (124).
8. A composition comprising 1-chloro-2,3,3,3-tetrafluoropropene (1224 yd),
(i) one of 1-chloro-trifluoropropyne and 1,2-dichloro-3,3,3-trifluoropropene (1223xd),
(ii) one of 2,3,3,3-tetrafluoropropene (1234yf) and 2-chloro-3,3,3-trifluoropropene (1233xf), and
(iii) at least one additional compound selected 2-bromo-3,3,3-trifluoropropene (1233xfB), 2,3-dichloro-1,1,1-trifluoropropane (243 db), 1-chloro-1,2,3,3,3-pentafluoropropene (1215yb), 2-chloro-1,3,3,3-tetrafluoropropene (1224xe), 3-chloro-1,1,1-trifluoropropane (253fb), 1,1,1,2 tetrafluoroprop-1-ene (254eb), 1,1-dichloro-2,3,3,3-tetrafluoroprop-1-ene (1214ya), 2,2-dichloro-1,1,1-trifluoroethane (123), and 2-chloro-1,1,1,2-tetrafluoroethane (124).
9. The composition of claim 8 wherein 2,3-dichloro-1,1,1-trifluoropropane (243 db) is present.
10. The composition of claim 8 wherein at least two of 2-bromo-3,3,3-trifluoropropene (1233xfB), 2,3-dichloro-1,1,1-trifluoropropane (243 db), 1-chloro-1,2,3,3,3-pentafluoropropene (1215yb), 2-chloro-1,3,3,3-tetrafluoropropene (1224xe), 3-chloro-1,1,1-trifluoropropane (253fb), 1,1,1,2-tetrafluoropropane (254eb), 1,1-dichloro-2,3,3,3-tetrafluoroprop-1-ene (1214ya), 2,2-dichloro-1,1,1-trifluoroethane (123), and 2-chloro-[1,1,1,2-tetrafluoroethane (124) are present.