IP Library Granted Patent US 12,679,762
Granted Patent B2
US 12,679,762 · App. 17/619,959 · Granted Jul 14, 2026

Low bio-persistent high temperature resistant inorganic fibers

Inventors: Donghui Zhao (Amherst, NY); Jason M. Hamilton (Lancaster, NY); Karen L. Hanson (Youngstown, NY); Mauricio Munhoz De Souza (Amherst, NY)
Assignee: UNIFRAX I LLC
C03C13/00C03B37/01C03C3/087C03C4/0014C03C2204/00C03C2213/02
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Quick Facts
Patent No.
US 12,679,762
App. No.
17/619,959
Filed
Dec 16, 2021
Granted
Jul 14, 2026
Kind
B2
Art Unit
1731
USPC
501/35
Abstract

A high temperature resistant inorganic fiber includes 72 to 77.3 weight percent silica; 10.2 to 15 weight percent magnesia; 12.4 to 17 weight percent calcia; 0 to 1.5 weight percent alumina; and 0 to 0.6 weight percent total alkali oxides; the fiber has a use temperature of at least 1260° C.; the fiber may exhibit a shrinkage of greater than 5% after exposure to a temperature of 1400° C. for 24 hours; and the fiber may have a melt temperature of less than 1400° C.

Claims (22)

1 . A high temperature resistant inorganic fiber comprising:

72 to 77.3 weight percent silica;

10.5 to 15 weight percent magnesia;

12.5 to 17 weight percent calcia;

0 to 1.5 weight percent alumina; and

0.1 to 0.6 weight percent total alkali oxides;

wherein the fiber has a use temperature of at least 1260° C. and exhibits a shrinkage of less than 3% after exposure to a temperature of 1260° C. for 24 hours;

wherein the fiber exhibits a shrinkage of greater than 5% after exposure to a temperature of 1400° C. for 24 hours; and

wherein the fiber does not comprise strontia.

2 . The fiber of claim 1 , wherein the fiber comprises 11 to 15 weight percent magnesia and 13 to 17 weight percent calcia.

3 . The fiber of claim 1 , wherein the fiber exhibits a dissolution rate of greater than 100 ng/cm 2 -hr after 6 hours in simulated lung fluid.

4 . The fiber of claim 1 , wherein the fiber comprises greater than 0 to 0.5 weight percent lithium oxide.

5 . The fiber of claim 1 , wherein the fiber comprises greater than 0 to 0.5 weight percent potassium oxide.

6 . The fiber of claim 1 , wherein the fiber comprises 0.5 to 1.1 weight percent alumina.

7 . The fiber of claim 1 , wherein the fiber comprises:

73 to 75.8 weight percent silica;

11 to 15 weight percent magnesia;

13 to 17 weight percent calcia;

0.2 to 1.5 weight percent alumina; and

0.1 to 0.6 weight percent total alkali oxides.

8 . The fiber of claim 1 , wherein the fiber comprises potassium oxide and lithium oxide and wherein a weight ratio of potassium oxide to lithium oxide is less than 7.

9 . The fiber of claim 1 , wherein the fiber comprises potassium oxide and lithium oxide and wherein a sum of the potassium oxide and lithium oxide is from greater than 0.2 weight percent to less than 0.5 weight percent.

Assignments (5)
FIRST LIEN PATENT SECURITY AGREEMENT Recorded Oct 2, 2024
From: LYDALL PERFORMANCE MATERIALS (US), INC.; LYDALL INC.; REFRACTORY SPECIALTIES, INCORPORATED; SOUTHERN FELT COMPANY, INC.; UNIFRAX I LLC; STELLAR MATERIALS
To: WILMINGTON SAVINGS FUND SOCIETY, FSB, AS COLLATERAL AGENT
Reel/Frame 069091/0735 →
SECOND LIEN TRADEMARK SECURITY AGREEMENT Recorded Oct 2, 2024
From: LYDALL PERFORMANCE MATERIALS (US), INC.; LYDALL INC.; REFRACTORY SPECIALTIES, INCORPORATED; SOUTHERN FELT COMPANY, INC.; UNIFRAX I LLC; STELLAR MATERIALS
To: WILMINGTON TRUST, NATIONAL ASSOCIATION, AS SECOND LIEN NOTES COLLATERAL AGENT
Reel/Frame 069091/0923 →
RELEASE OF FIRST LIEN SECURITY INTEREST IN PATENT COLLATERAL AT REEL/FRAME NO. 65291/0036 Recorded Oct 2, 2024
From: MORGAN STANLEY SENIOR FUNDING, INC., AS COLLATERAL AGENT
To: UNIFRAX I LLC
Reel/Frame 069103/0576 →
PATENT SECURITY AGREEMENT Recorded Oct 19, 2023
From: UNIFRAX I LLC
To: MORGAN STANLEY SENIOR FUNDING, INC., AS COLLATERAL AGENT
Reel/Frame 065291/0036 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Dec 16, 2021
From: ZHAO, DONGHUI; HAMILTON, JASON M.; HANSON, KAREN L.; DE SOUZA, MAURICIO MUNHOZ
To: UNIFRAX I LLC
Reel/Frame 058523/0216 →