IP Library Patent Application 17630536
Patent Application
App. No. 17/630,536

Polybutylene Terephthalate With Low THF Content

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Quick Facts
Patent No.
US None
App. No.
17/630,536
Abstract

The invention relates to the use of at least one copolymer of at least one olefin, preferably an alpha-olefin, and at least one acrylic ester of an aliphatic alcohol, wherein the Melt Flow Index of the copolymer is not less than 100 g/10 min, for production of polybutylene terephthalate-based automotive interior parts having a low tetrahydrofuran content by injection molding.

Claims (16)

1 . An automotive interior part containing a composition based on polybutylene terephthalate and at least one copolymer of at least one olefin and at least one acrylic ester of an aliphatic alcohol, wherein the Melt Flow Index of the copolymer to be determined according to DIN EN ISO 1133 [2] at 190° C. and a test weight of 2.16 kg is not less than 100 g/10 min and based on 100 parts by mass of polybutylene terephthalate the composition employs 0.1 to 20 parts by mass of copolymer.

2 . The automotive interior part as claimed in claim 1 , wherein the Melt Flow Index is not less than 150 g/10 min.

3 . The automotive interior part as claimed in claim 1 , wherein the olefin employed is an alpha-olefin.

4 . The automotive interior part as claimed in claim 3 , wherein the olefin employed is at least one selected from the group of ethene, propene, 1-butene, 1-pentene, 1-hexene, 1-octene, and 3-methyl-1-pentene.

5 . The automotive interior part as claimed in claim 1 , wherein an aliphatic alcohol having 1 to 30 carbon atoms is employed.

6 . The automotive interior part as claimed in claim 1 , wherein the copolymer consists of at least one olefin and at least one acrylic ester of an aliphatic alcohol, wherein the Melt Flow Index of the copolymer is not less than 100 g/10 min.

7 . The automotive interior part as claimed in claim 6 , wherein the copolymer consists of ethene and (2-ethyl)hexyl acrylate.

8 . The automotive interior part as claimed in claim 1 , having a TVOC to be determined according to VDA 277 of <50 μgC/g and a VOC THF to be determined according to VDA 278 of <8 μg/g.

9 . The automotive interior part as claimed in claim 1 , wherein the copolymer is employed in combination with at least one filler.

10 . The automotive interior part as claimed in claim 9 , wherein 0.001 to 70 parts by mass of filler per 100 parts by mass of polybutylene terephthalate are employed.

11 . The automotive interior part as claimed in claim 9 , wherein the filler is selected from the group comprising talc, mica, silicate, quartz, titanium dioxide, wollastonite, kaolin, kyanite, amorphous silicas, magnesium carbonate, chalk, feldspar, barium sulfate, glass spheres, glass fibers and carbon fibers.

12 . A method for preparing polybutylene terephthalate-based compounds for processing into injection molded parts having a TVOC to be determined according to VDA 277 of <50 μgC/g and a VOC THF to be determined according to VDA 278 of <8 μg/g, comprising compounding polybutylene terephthalate with least one copolymer of at least one olefin and at least one acrylic ester of an aliphatic alcohol, wherein the Melt Flow Index (MFI) of the copolymer to be determined according to DIN EN ISO 1133 [2] at 190° C. and a test weight of 2.16 kg is not less than 100 g/10 min, wherein per 100 parts by mass of PBT 0.1 to 20 parts by mass of copolymer are employed.

13 . A method for reducing the outgassing of tetrahydrofuran from injection molded polybutylene terephthalate-based automotive interior parts, comprising compounding polybutylene terephthalate with at least one copolymer of at least one olefin and at least one acrylic ester of an aliphatic alcohol, wherein the Melt Flow Index of the copolymer to be determined according to DIN EN ISO 1133 [2] at 190° C. and a test weight of 2.16 kg is not less than 100 g/10 min and per 100 parts by mass of polybutylene terephthalate the compounds employ 0.1 to 20 parts by mass of copolymer.

14 . The method as claimed in claim 12 , wherein the olefin is an alpha-olefin.

15 . The method as claimed in claim 12 , wherein the aliphatic alcohol has 1 to 30 carbon atoms.

16 . The method as claimed in claim 12 , wherein the Melt Flow Index is not less than 150 g/10 min.

Assignments (3)
CHANGE OF NAME AND ADDRESS Recorded May 6, 2026
From: LANXESS PERFORMANCE MATERIALS GMBH
To: ENVALIOR DEUTSCHLAND GMBH
Reel/Frame 075513/0147 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Apr 3, 2023
From: LANXESS DEUTSCHLAND GMBH
To: LANXESS PERFORMANCE MATERIALS GMBH
Reel/Frame 063205/0552 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Mar 8, 2022
From: BIENMUELLER, MATTHIAS; HARMS, SEBASTIAN
To: LANXESS DEUTSCHLAND GMBH
Reel/Frame 059192/0323 →