SMOKING DEVICE COMPRISING AT LEAST ONE BREAKABLE FLAVOURING CAPSULE
A smoking device including a tubular element containing tobacco and a filtering element connected to an end of the tubular element. The filtering element includes at least one breakable flavouring capsule which includes at least one core having at least one lipophilic substance and at least one flavouring agent dispersed or dissolved in the lipophilic substance; at least one breakable coating which coats the core and which has at least one chitosan having a weight average molecular weight (Mw) between 25 kDa and 400 kDa. Preferably, the breakable coating further includes at least one polyhydroxyalkanoate (PHA). The frangible coating that coats the core is able to preserve its hardness, and therefore its breakability, during use by the smoker, i.e. in the presence of humidity and heat that develop from the combustion of tobacco.
1 . A smoking device comprising a tubular element containing tobacco and a filtering element connected to an end of said tubular element, wherein said filtering element includes at least one breakable flavouring capsule which comprises:
at least one core comprising at least one lipophilic substance and at least one flavouring agent dispersed or dissolved in said lipophilic substance; and
at least one breakable coating which coats said core and which comprises at least one chitosan having a weight average molecular weight (Mw) comprised between 25 kDa and 400 kDa.
2 . The device according to claim 1 , wherein said at least one chitosan has a weight average molecular weight (Mw) comprised between 50 kDa and 350 kDa.
3 . The device according to claim 1 , wherein said at least one chitosan has a Brookfield viscosity, measured at 25° C. on an aqueous solution at 1% by weight of acetic acid containing 1% by weight of chitosan, from 20 to 300 cP.
4 . The device according to claim 1 , wherein said at least one lipophilic substance is selected from the group consisting of: triglycerides, in particular medium-chain C 6 -C 12 fatty acid triglycerides, such as caproic, caprylic, capric and lauric acid, or mixtures thereof; vegetable oils, such as olive oil, corn seed oil, sunflower seed oil, peanut oil, soybean oil, coconut oil, almond oil.
5 . The device according to claim 1 , wherein said at least one flavouring agent is selected from the group consisting of: bergamot oil, eucalyptol oil, mint oil, ethyl methylphenylglycidate (strawberry flavour), or mixtures thereof.
6 . The device according to claim 1 , wherein the core comprises: from 80% by weight to 99.5% by weight of at least one lipophilic substance, and from 0.5% by weight to 20% by weight of at least one flavouring agent, the percentage by weight being expressed with respect to the overall weight of the core.
7 . The device according to claim 1 , wherein the breakable coating further comprises at least one polyhydroxyalkanoate (PHA).
8 . The device according to claim 7 , wherein the breakable coating comprises: from 20% by weight to 80% by weight of at least one chitosan, and from 20% by weight to 80% by weight of at least one PHA, the percentage by weight being expressed with respect to the overall weight of the coating.
9 . The device according to claim 1 , wherein said at least one flavouring agent is adsorbed on particles of a PHA.
10 . The device according to claim 7 , wherein the PHA is selected from the group consisting of: poly-hydroxybutyrate (PHB), poly-3-hydroxyvalerate (PHV), poly-3-hydroxyhexanoate (PHH), poly-3-hydroxyoctanoate (PHO), poly(3-hydroxybutyrate-co-3-hydroxyvalerate) (PHBV), poly(3-hydroxybutyrate-co-3-hydroxyesanoate) (PHBH), poly(3-hydroxybutyrate-co-4-hydroxybutyrate), poly(3-hydroxyoctanoate-co-3-hydroxyundecen-10-enoate) (PHOU), poly(3-hydroxybutyrate-co-3-hydroxyvalerate-co-4-hydroxyvalerate) (PHBVV), polyhydroxybutyrate-hydroxyvalerate copolymer, or mixtures thereof.
11 . The device according to claim 1 , wherein said at least one breakable coating has a crushing strength comprised between 2 N and 16 N.
12 . A breakable flavouring capsule which comprises:
at least one core comprising at least one lipophilic substance and at least one flavouring agent dispersed or dissolved in said lipophilic substance; and
at least one breakable coating which coats said core and which comprises at least one chitosan having a weight average molecular weight (Mw) comprised between 25 kDa and 400 kDa.
13 . The capsule according to claim 12 and further comprising:
at least one core comprising at least one lipophilic substance and at least one flavouring agent dispersed or dissolved in said lipophilic substance;
at least one breakable coating which coats said core and which comprises at least one chitosan having a weight average molecular weight (Mw) comprised between 50 kDa and 350 kDa.
14 . Use of a capsule according to claim 12 , to aromatize the smoke generated in a smoking device.
15 . A process for producing a capsule according to claim 12 , the process including the following steps:
providing a suspension or a solution of at least one flavouring agent in at least one lipophilic substance,
providing a solution or an aqueous acid suspension of at least one chitosan,
coextruding said suspension or solution of at least one flavouring agent and said solution or acid aqueous suspension of at least one chitosan through a coaxial needle, so as to coat cores of said suspension or solution of at least one flavouring agent with a coating layer of said solution or acid aqueous suspension of at least one chitosan, and
solidifying and drying said cores thus coated by obtaining the capsules.
16 . The process according to claim 15 , wherein the step of solidifying the coated cores is carried out by immersing the capsule as soon as coextruded in a solidification solution.
17 . The process according to claim 16 , wherein the solidification solution is an aqueous solution of a product selected from the group consisting of: alkali or alkaline-earth metal hydroxides (in particular NaOH or KOH), sodium pentabasic triphosphate, phytic acid, sodium citrate, oxalic acid, or mixtures thereof.