IP Library Granted Patent US 12,285,504
Granted Patent B2
US 12,285,504 · App. 17/633,897 · Granted Apr 29, 2025

Dispersible nonwoven materials including CMC-based binders

Inventors: Ronald T. Moose (Lakeland, TN); Jacek K. Dutkiewicz (Cordova, TN); Alan J. Campbell (Germantown, TN)
Assignee: Glatfelter Corporation
A61K8/0208A61K8/20A61K8/731A61K8/86A61Q19/10D04H1/425D04H1/587D04H1/64
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Quick Facts
Patent No.
US 12,285,504
App. No.
17/633,897
Granted
Apr 29, 2025
Kind
B2
Abstract

Nonwoven materials having at least one layer comprising cellulose fibers, synthetic fibers, or combinations thereof are provided. Such nonwoven materials are at least partially covered on their surface with a binder including carboxymethyl cellulose (CMC) and a metallic salt, the binder having a pH of from about 4.3 to about 4.5. Nonwoven materials including such binder provide for increased wet strength and dispersibility and are suitable for use in a variety of applications, including wipes.

Claims (26)

1. A nonwoven material comprising:

at least one layer comprising cellulose fibers, synthetic fibers, or any combination thereof;

a binder covering at least a portion of the at least one layer, wherein the binder comprises carboxymethyl cellulose and a metallic salt, and the binder has a pH ranging from about 4.3 to about 4.5; and

a lotion, the lotion comprising from 24 to 29 wt % of ethanol.

2. The nonwoven material of claim 1 , wherein the binder has a pH ranging from about 4.3 to about 4.4.

3. The nonwoven material of claim 1 , wherein the binder has a pH ranging from about 4.4 to about 4.5.

4. The nonwoven material of claim 1 , wherein the carboxymethyl cellulose and metallic salt are present in the binder in a weight:weight ratio of about 1:1.

5. The nonwoven material of claim 1 , wherein the carboxymethyl cellulose and metallic salt are present in the binder in a weight:weight ratio of about 3:1.

6. The nonwoven material of claim 1 , wherein the metallic salt comprises calcium chloride.

7. The nonwoven material of claim 1 , wherein the binder further comprises a surfactant.

8. The nonwoven material of claim 1 , wherein the binder further comprises a plasticizer.

9. The nonwoven material of claim 8 , wherein the plasticizer comprises a polyethylene glycol.

10. The nonwoven material of claim 1 , wherein the cellulose fibers comprise modified cellulose fibers, cellulose fluff, or eucalyptus pulp, or any combination thereof.

11. The nonwoven material of claim 1 , wherein the cellulose fibers comprise softwood fibers, hardwood fibers, or a combination of softwoods fibers and hardwood fibers.

12. The nonwoven material of claim 1 , wherein the synthetic fibers comprise bicomponent fibers.

13. The nonwoven material of claim 1 , wherein the nonwoven material has a wet strength of from about 350 gli to about 400 gli.

14. A personal care product, comprising the nonwoven material of claim 1 .

15. The personal care product of claim 14 , wherein the personal care product is a wipe.

16. The nonwoven material of claim 1 , wherein the lotion has a pH ranging from about 7 to about 9.

17. A nonwoven material comprising:

at least one layer comprising cellulose fibers, synthetic fibers, or any combination thereof;

a binder covering at least a portion of the at least one layer, wherein the binder has a pH ranging from about 4.3 to about 4.5 and comprises:

carboxymethyl cellulose; and

one or more metallic salts, the one or more metallic salts present in the binder in an amount ranging from about 15 to about 50 wt %, relative to the weight of the carboxymethyl cellulose; and

a lotion, the lotion comprising from 24 to 29 wt % of ethanol.

18. The nonwoven material of claim 17 , wherein the one or more metallic salts are present in the binder in an amount ranging from about 25 to about 50 wt %, relative to the weight of the carboxymethyl cellulose.

Assignments (10)
RELEASE OF SECURITY INTEREST Recorded May 5, 2025
From: U.S. BANK TRUST COMPANY, NATIONAL ASSOCIATION
To: GLATFELTER CORPORATION; AVINTIV SPECIALTY MATERIALS, LLC; FIBERWEB, LLC; BERRY FILM PRODUCTS COMPANY, INC.; PROVIDENCIA USA, INC.
Reel/Frame 071176/0799 →
RELEASE OF SECURITY INTEREST Recorded Dec 9, 2024
From: PNC BANK, NATIONAL ASSOCIATION
To: GLATFELTER CORPORATION; PHG TEA LEAVES, INC.; MOLLANVICK, INC.; GLATFELTER COMPOSITE FIBERS NA, INC.; GLATFELTER DIGITAL SOLUTIONS, LLC; GLATFELTER HOLDINGS, LLC; GLATFELTER MT. HOLLY LLC; GLATFELTER ADVANCED MATERAILS N.A., LLC; GLATFELTER TWIG AMERICA, INC.; GLATFELTER SONTARA AMERICA, INC.; GLATFELTER SONTARA OLD HICKORY, INC.; GLATFELTER INDUSTRIES ASHEVILLE, INC.
Reel/Frame 069519/0217 →
TERMINATION AND RELEASE OF SECURITY INTEREST IN INTELLECTUAL PROPERTY Recorded Nov 7, 2024
From: PNC BANK, NATIONAL ASSOCIATION
To: GLATFELTER CORPORATION; PHG TEA LEAVES, INC.; MOLLANVICK, INC.; GLATFELTER COMPOSITE FIBERS NA, INC.; GLATFELTER DIGITAL SOLUTIONS, LLC; GLATFELTER HOLDINGS, LLC; GLATFELTER MT. HOLLY LLC; GLATFELTER ADVANCED MATERIALS N.A., LLC; GLATFELTER TWIG AMERICAN, INC.; GLATFELTER SONTARA AMERICA, INC.; GLATFELTER SONTARA OLD HICKORY, INC.; GLATFELTER INDUSTRIES ASHEVILLE, INC.
Reel/Frame 069314/0152 →
SECURITY AGREEMENT (TERM LOAN) Recorded Nov 5, 2024
From: GLATFELTER CORPORATION; AVINTIV SPECIALTY MATERIALS, LLC; FIBERWEB, LLC; BERRY FILM PRODUCTS COMPANY, INC.; PROVIDENCIA USA, INC.
To: CITIBANK, N.A., AS COLLATERAL AGENT
Reel/Frame 069305/0145 →
RELEASE OF SECURITY INTERESTS AT REEL/FRAME 063205/0068 Recorded Nov 5, 2024
From: ALTER DOMUS (US) LLC, AS ADMINISTRATIVE AGENT
To: GLATFELTER CORPORATION; PHG TEA LEAVES, INC.; MOLLANVICK, INC.; GLATFELTER COMPOSITE FIBERS NA, INC.; GLATFELTER DIGITAL SOLUTIONS, LLC; GLATFELTER HOLDINGS, LLC; GLATFELTER MT. HOLLY LLC; GLATFELTER ADVANCED MATERIALS N.A., LLC; GLATFELTER TWIG AMERICA, INC.; GLATFELTER SONTARA AMERICA, INC.; GLATFELTER SONTARA OLD HICKORY, INC.; GLATFELTER INDUSTRIES ASHEVILLE, INC.
Reel/Frame 069303/0774 →
SECURITY AGREEMENT (ABL) Recorded Nov 5, 2024
From: GLATFELTER CORPORATION; AVINTIV SPECIALTY MATERIALS, LLC; FIBERWEB, LLC; BERRY FILM PRODUCTS COMPANY, INC.; PROVIDENCIA USA, INC.
To: WELLS FARGO BANK, NATIONAL ASSOCIATION, AS COLLATERAL AGENT
Reel/Frame 069305/0032 →
SECURITY AGREEMENT (NOTES) Recorded Nov 5, 2024
From: GLATFELTER CORPORATION; AVINTIV SPECIALTY MATERIALS, LLC; FIBERWEB, LLC; BERRY FILM PRODUCTS COMPANY, INC.; PROVIDENCIA USA, INC.
To: U.S. BANK TRUST COMPANY, NATIONAL ASSOCIATION, AS COLLATERAL AGENT
Reel/Frame 069305/0111 →
AMENDED AND RESTATED IP SECURITY AGREEMENT Recorded Apr 4, 2023
From: GLATFELTER CORPORATION; PHG TEA LEAVES, INC.; MOLLANVICK, INC.; GLATFELTER COMPOSITE FIBERS NA, INC.; GLATFELTER DIGITAL SOLUTIONS, LLC; GLATFELTER HOLDINGS, LLC; GLATFELTER MT. HOLLY LLC; GLATFELTER ADVANCED MATERAILS N.A., LLC; GLATFELTER TWIG AMERICA, INC.; GLATFELTER SONTARA AMERICA, INC.; GLATFELTER SONTARA OLD HICKORY, INC.; GLATFELTER INDUSTRIES ASHEVILLE, INC.
To: PNC BANK, NATIONAL ASSOCIATION
Reel/Frame 063250/0393 →
SECURITY INTEREST Recorded Mar 30, 2023
From: GLATFELTER CORPORATION; PHG TEA LEAVES, INC.; MOLLANVICK, INC.; GLATFELTER COMPOSITE FIBERS NA, INC.; GLATFELTER DIGITAL SOLUTIONS, LLC; GLATFELTER HOLDINGS, LLC; GLATFELTER MT. HOLLY LLC; GLATFELTER ADVANCED MATERIALS N.A., LLC; GLATFELTER TWIG AMERICA, INC.; GLATFELTER SONTARA AMERICA, INC.; GLATFELTER SONTARA OLD HICKORY, INC.; GLATFELTER INDUSTRIES ASHEVILLE, INC.
To: ALTER DOMUS (US) LLC, AS ADMINISTRATIVE AGENT
Reel/Frame 063205/0068 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Oct 20, 2022
From: MOOSE, RONALD T.; DUTKIEWICZ, JACEK K.; CAMPBELL, ALAN J.
To: GLATFELTER CORPORATION
Reel/Frame 061481/0001 →