High-voltage Components
The present invention relates to high-voltage components, especially for electromobility, containing polymer compositions based on at least one polyamide and at least one sulfide containing cerium, and to the use thereof for production of polyamide-based high-voltage components or for marking of polyamide-based products as high-voltage components by laser.
1 . A polymer composition comprising A) at least one polyamide and B) at least one sulfide containing cerium.
2 . The polymer composition as claimed in claim 1 , wherein
for every 100 parts by mass of at least one polyamide,
0.01 to 5 parts by mass of at least one sulfide containing cerium are used.
3 . The polymer composition as claimed in claim 1 , wherein at least cerium(III) sulfide or cerium(III) sulfide/lanthanum(III) sulfide is used.
4 . The polymer composition as claimed in claim 1 , further comprising C) at least one filler or reinforcer, with the proviso that the polymer compositions, in the RAL color system, correspond to color number RAL2003, RAL2004, RAL2007, RAL2008, RAL2009, RAL2010 or RAL2011.
5 . The polymer composition as claimed in claim 1 , further comprising D) at least one flame retardant, or further comprising both the component D) and C) at least one filler or reinforcer, with the proviso that the polymer compositions, in the RAL color system, correspond to color number RAL2003, RAL2004, RAL2007, RAL2008, RAL2009, RAL2010 or RAL2011.
6 . The polymer composition as claimed in claim 1 , comprising E) at least one further additive other than a filler or reinforcer or flame retardant, or further comprising the component E) and one or both of D) at least one flame retardant and C) at least one filler or reinforcer, with the proviso that the polymer compositions, in the RAL color system, correspond to color number RAL2003, RAL2004, RAL2007, RAL2008, RAL2009, RAL2010 or RAL2011.
7 . The polymer composition as claimed in claim 4 , wherein the filler or reinforcer is selected from the group of glass beads or solid or hollow glass beads, or glass fibers, ground glass, amorphous quartz glass, aluminum borosilicate glass having an alkali metal content of 1%, amorphous silica, quartz flour, calcium silicate, calcium metasilicate, magnesium carbonate, kaolin, calcined kaolin, chalk, kyanite, powdered or ground quartz, mica, phlogopite, barium sulfate, feldspar, wollastonite, montmorillonite, pseudoboehmite of the formula AlO(OH), magnesium carbonate and talc.
8 . The polymer composition as claimed in claim 5 , wherein the flame retardant is selected from mineral flame retardants, nitrogen-containing flame retardants and phosphorus-containing flame retardants.
9 . The polymer composition as claimed in claim 6 , wherein at least one thermal stabilizer is used as additive E).
10 . The polymer composition as claimed in claim 6 , wherein titanium dioxide is used as additive E).
11 . The polymer composition as claimed in claim 1 , wherein nylon-6, nylon-6,6, nylon-4,6 and/or a semiaromatic copolyamide is/are used as polyamide.
12 . A high-voltage component comprising the polymer composition as claimed in claim 1 .
13 . The high-voltage component as claimed in claim 12 , wherein the component comprises covers for electrics or electronics, control devices, covers/housings for fuses, relays, battery cell modules, fuse holders, fuse plugs, terminals, cable holders or sheathings.
14 . A process for producing the polymer composition as claimed in claim 1 , comprising mixing the components A) and B), optionally with one or more components chosen from C) at least one filler or reinforcer, D) at least one flame retardant and E) at least one further additive other than a filler or reinforcer or flame retardant, in at least one mixing system, with the proviso that the polymer composition, in the RAL color system, corresponds to color number RAL2003, RAL2004, RAL2007, RAL2008, RAL2009, RAL2010 or RAL2011.
15 . A process for producing high-voltage components, comprising mixing A) at least one polyamide and B) at least one sulfide containing cerium to give polymer compositions that are discharged to give strands, cooling and pelletizing the resulting polymer compositions, and further processing the compositions by injection molding, by extrusion methods, or by blow molding.
16 . A method of marking a polyamide-based product, comprising irradiating the product using a laser, wherein at least one sulfide containing cerium is used in the polyamide.
17 . The polymer composition as claimed in claim 4 , wherein the at least one filler or reinforcer C) is present in an amount of 1 to 150 parts by mass, based on 100 parts by mass of the component A).
18 . The polymer composition as claimed in claim 5 , wherein the at least one flame retardant D) is present in an amount of 3 to 100 parts by mass, based on 100 parts by mass of the component A).
19 . The polymer composition as claimed in claim 6 , wherein the at least one further additive E) is present in an amount of 0.01 to 80 parts by mass, based on 100 parts by mass of the component A).
20 . The process as claimed in claim 15 , wherein 0.01 to 5 parts by mass of the sulfide containing cerium is used per 100 parts by mass of polyamide.