Method and composition
The present invention relates to a method of preparing a catalyst article comprising steps: (a) preparing a washcoat composition by combining at least the following components: a support material comprising a mixed oxide, a mixture of oxides or a molecular sieve comprising (i) alumina and (ii) silica and/or zirconia; a metal oxide sol comprising at least one of titania, silica or zirconia; a liquid medium; (b) applying the washcoat composition to a substrate to form a washcoating; and (c) drying and/or calcining the washcoating; wherein the method further comprises a step of impregnating the support material with a platinum group metal component. The prepared catalyst article may be suitable for the treatment of emissions from an internal combustion engine or a gas turbine, for example, the treatment of carbon monoxide and/or formaldehyde emissions from a natural gas fueled internal combustion engine or gas turbine.
1. A method of preparing a catalyst article comprising steps:
(a) preparing a washcoat composition by combining at least the following components:
a support material comprising a mixed oxide, a mixture of oxides or a molecular sieve;
a metal oxide sol comprising at least one of titania, silica or zirconia;
a liquid medium;
(b) applying the washcoat composition to a substrate to form a washcoating; and
(c) drying and/or calcining the washcoating;
wherein the method further comprises a step of impregnating the support material with a platinum group metal component;
wherein the molecular sieve comprises (i) alumina and silica and/or zirconia; and
wherein the metal oxide sol is a titania sol.
2. The method of claim 1 , wherein the support material is a silica-alumina mixed oxide, a zirconia-alumina mixed oxide or an aluminosilicate molecular sieve.
3. The method of claim 1 , wherein the support material is a silica-alumina mixed oxide.
4. The method of claim 3 , wherein the support material is a silica-alumina mixed oxide having a silica content in the range 1 to 40 wt %.
5. The method of claim 3 , wherein the support material is a silica-alumina mixed oxide having a silica content in the range 2 to 35 wt %.
6. The method of claim 3 , wherein the support material is a silica-alumina mixed oxide having a silica content in the range 5 to 30 wt %.
7. The method of claim 1 , wherein the support material has a D90 particle size of ≤50 μm.
8. The method of claim 1 , wherein the support material is impregnated with PGM component prior to step (a) by contacting the support material with an impregnation solution, wherein the impregnation solution comprises the PGM component.
9. The method of claim 1 , wherein the support material is impregnated with PGM component subsequent to step (a) and prior to step (b) by blending the washcoat composition formed in step (a) with an impregnation solution comprising the PGM component.
10. The method of claim 1 , wherein the support material is impregnated with platinum group metal component subsequent to step (c), which method further comprises:
(d) applying an impregnation solution to the substrate to form a second coating, wherein the impregnation solution comprises the PGM component; and
(e) drying and/or calcining the second coating.
11. The method of claim 1 , wherein the platinum group metal component comprises platinum, palladium or a mixture of platinum and palladium.
12. The method of claim 1 , wherein the platinum group metal component is a platinum nitrate or a platinum acetate.
13. The method of claim 1 , wherein the metal oxide of the metal oxide sol has a BET surface area of ≥100 m 2 /g.
14. The method of claim 1 , wherein the metal oxide sol has a D50 particle size of ≤1 μm.
15. The method of claim 1 , wherein the metal oxide of the metal oxide sol has a BET surface area of ≥200 m 2 /g.
16. The method of claim 1 , wherein the metal oxide of the metal oxide sol has a BET surface area of ≥300 m 2 /g.
17. The method of claim 1 , wherein the metal oxide sol has a D50 particle size of ≤0.5 μm.