COMPOSITIONS AND METHODS FOR SENSITIZING HEAT MEDIA
A heat-sensitive recording composition and recording material. The recording material comprising a substrate, wherein a heat-sensitive composition comprising color formers, color developers and a sensitizer comprising a combination of ortho-toluenesulfonamide and para-toluenesulfonamide (OPTSA) is deposited onto the surface of the substrate.
1 . A heat-sensitive recording composition comprising:
a) one or more color formers;
b) one or more color developers; and
c) at least one sensitizer comprising a mixture of ortho-toluenesulfonamide and para-toluenesulfonamide (OPTSA).
2 . The recording composition according to claim 1 , the at least one sensitizer has a ratio of ortho-toluenesulfonamides to para-toluenesulfonamides of from about 0.5:99.5 to about 99.5:0.5 based on dry weight of the OPTSA mixture.
3 . The recording composition according to claim 1 , wherein the at least one sensitizer is present in an amount of from about 0.1 to about 6 parts by dry mass per one part of the one or more color formers.
4 . The recording composition according to claim 1 , wherein the one or more color developers is chosen from phenolic color developers, non-phenolic color developers and combinations thereof.
5 . The recording composition according to claim 4 , wherein the one or more color developers is chosen from 5-(N-3-methylphenyl-sulfonylamido)-(N′,N″-bis-(3-methylphenyl)-isophthalic acid diamide, [3-(p-tolylsulfonylcarbamoylamino)phenyl]4-methylbenzenesulfonate, 2.4′-dihydroxydiphenylsulfone, 4.4′-dihydroxydiphenylsulfone, bis-(3-allyl-4-hydroxyphenyl) sulfone, 4-[4′-[(1′-methylethyloxy)phenyl]sulfonyl]phenol, 4-hydroxyphenyl 4-isoprooxyphenyl sulfone, N-{2-[(phenylcarbamoyl)amino]phenyl} benzenesulfonamide, phenol, 4-[[4-(2-propenlyloxy)phenyl]sulfonyl, 4-Hydroxy-4′benzyloxydiphenylsulfone, and 4.4′bis(N-carbamoyl-4-methylbenzenesulfonamide) diphenylmethane, 4.4′-sulfonylbis-polymer with 1.1′-oxybis[2-chloroethane], phenols, urea urethane compounds and combinations thereof.
6 . The recording composition according to claim 1 , wherein the one or more color formers is chosen from fluoran, phthalide, lactam, triphenylmethane, phenothiazine, spiropyran leuco dyes and combinations thereof.
7 . The recording composition according to claim 6 , wherein the one or more color formers is chosen from 2-anilino-3-methyl-6-diethylaminofluorane, 2-anilino-3-methyl-6-dibutylaminofluorane, 2-anilino-3-methyl-6-(methyl-N-isoamylamino)fluorine, 2-anilino-3-methyl-6-(N-ethyl-N-propylamino)fluorane, 2-anilino-3-methyl-6-di-n-amylaminofluorane, 2-anilino-3-methyl-6-(N-ethyl-N-ptolylamino)fluorane, 2-anilino-3-methyl-6-N-ethyl-N-sec-butylaminofluorane, 3-di-(n-pentylamino)-6-methyl-7-anilinofluorane, 3-(N-isoamyl-N-ethylamino)-6-methyl-7-anilinofluorane, 3-(N-n-hexyl-N-ethylamino)-6-methyl-7-anilinofluorane, 3-[N-(3-ethoxypropyl)-N-ethylamino]-6-methyl-7-anilinofluorane, 3-di-(n-butylamino)-7-2-chloroanilino)fluorane, 3-diethylamino-7-(2-chloroanilino)fluorane, 3-(N-cyclohexyl-N-methylamino)-6-methyl-7-anilinofluorane and combinations thereof.
8 . The recording composition according to claim 1 , further comprising at least one additive chosen from image stabilizers, sensitizers, fillers, binders, dispersants, antioxidants, anti-tack agents, antifoaming agents, light stabilizers, fluorescent brightening agents and combinations thereof.
9 . A method of producing a heat sensitive recording material, said method comprising:
providing a substrate;
applying or depositing one or more layers of a heat-sensitive recording composition according to claim 1 , on the substrate forming a heat-sensitive layer, thereby producing the heat sensitive recording material.
10 . The method according to claim 9 , wherein the substrate has one or more coatings on its surface and wherein the heat-sensitive recording composition is deposited onto the one or more coatings.
11 . A recording sheet comprising:
a substrate;
a recording composition disposed on the substrate and comprising one or more color formers; one or more color developers; and at least one sensitizer comprising a mixture of ortho-toluenesulfonamide and para-toluenesulfonamides (OPTSA).
12 . The recording sheet according to claim 11 , the at least one sensitizer has a ratio of ortho-toluenesulfonamides to para-toluenesulfonamides of from about 0.5:99.5 to about 99.5:0.5 based on dry weight of the OPTSA mixture.
13 . The recording sheet according to claim 12 , wherein the at least one sensitizer is present in an amount of from about 0.1 to about 6 parts by dry mass per one part of the one or more color formers.
14 . The recording sheet according to claim 11 , wherein the one or more color developers is selected from phenolic color developers, non-phenolic color developers and combinations thereof.
15 . The recording sheet according to claim 14 , wherein the one or more of the color developers is selected from the group consisting of 5-(N-3-methylphenyl-sulfonylamido)-(N′,N″-bis-(3-methylphenyl)-isophthalic acid diamide and [3-(p-tolylsulfonylcarbamoylamino)phenyl]4-methylbenzenesulfonate, 2.4′-dihydroxydiphenylsulfone, 4.4′-dihydroxydiphenylsulfone, bis-(3-allyl-4-hydroxyphenyl)sulfone, 4-[4′-[(1′-methylethyloxy)phenyl]sulfonyl]phenol, 4-hydroxyphenyl 4-isoprooxyphenylsulfone, N-{2-[(phenylcarbamoyl)amino]phenyl} benzenesulfonamide, phenol, 4-[[4-(2-propenlyloxy)phenyl]sulfonyl, 4-Hydroxy-4′benzyloxydiphenylsulfone, and 4.4′bis(N-carbamoyl-4-methylbenzenesulfonamide) diphenylmethane, 4.4′-sulfonylbis-polymer with 1.1′-oxybis[2-chloroethane], phenols, urea urethane compounds and combinations thereof.
16 . The recording sheet according to claim 11 , wherein the one or more color formers are selected from the group consisting of fluoran, phthalide, lactam, triphenylmethane, phenothiazine, spiropyran leuco dyes and combinations thereof.
17 . The recording sheet of claim 16 , wherein the one more color formers is selected from the group consisting 2-anilino-3-methyl-6-diethylaminofluorane, 2-anilino-3-methyl-6-dibutylaminofluorane, 2-anilino-3-methyl-6-(methyl-N-isoamylamino)fluorine, 2-anilino-3-methyl-6-(N-ethyl-N-propylamino)fluorane, 2-anilino-3-methyl-6-di-n-amylaminofluorane, 2-anilino-3-methyl-6-(N-ethyl-N-ptolylamino)fluorane, 2-anilino-3-methyl-6-N-ethyl-N-sec-butylaminofluorane, 3-di-(n-pentylamino)-6-methyl-7-anilinofluorane, 3-(N-isoamyl-N-ethylamino)-6-methyl-7-anilinofluorane, 3-(N-n-hexyl-N-ethylamino)-6-methyl-7-anilinofluorane, 3-[N-(3-ethoxypropyl)-N-ethylamino]-6-methyl-7-anilinofluorane, 3-di-(n-butylamino)-7-2-chloroanilino)fluorane, 3-diethylamino-7-(2-chloroanilino)fluorane, and 3-(N-cyclohexyl-N-methylamino)-6-methyl-7-anilinofluorane, 6-methyl-7-anilinofluorane and combinations thereof.
18 . The recording sheet according to claim 11 , wherein the recording composition further comprises image stabilizers, sensitizers, fillers, binders, dispersants, antioxidants, anti-tack agents, antifoaming agents, light stabilizers, fluorescent brightening agents and combinations thereof.
19 . The recording sheet according to claim 11 , wherein the substrate has one or more coatings on its surface and wherein the heat-sensitive recording composition is deposited onto or applied to the one or more coatings.
20 . The recording sheet according to claim 19 , wherein one or more topcoat layers is applied to the heat-sensitive layer.