Corrugated fuel electrode
A fuel electrode incorporates a first and second corrugated portion that are attached to each other at offset angles respect to their corrugation axis and therefore reinforce each other. A first corrugated portion may extend orthogonally with respect to a second corrugated portion. The first and second corrugated portions may be formed from metal wire and may therefore have a very high volumetric void fraction and a high surface area to volume ratio (sa/vol). In addition, the strands of the wire may be selected to enable high conductivity to the current collectors while maximizing the sa/vol. In addition, the shape of the corrugation, including the period distance, amplitude and geometry may be selected with respect to the stiffness requirements and electrochemical cell application factors. The first and second corrugated portions may be calendared or crushed to reduce thickness of the fuel electrode.
1. A rechargeable electrochemical cell comprising:
a fuel electrode comprising
a) a first corrugated portion formed of electrically conductive material, the first corrugated portion defining a first corrugation axis and defining a plurality of first apertures therethrough,
b) a second corrugated portion formed of electrically conductive material, the second corrugated portion defining a second corrugation axis offset from the first corrugation axis and defining a plurality of second apertures therethrough,
c) a third corrugated portion formed of electrically conductive material, the third corrugated portion defining a third corrugation axis aligned with the first corrugation axis and defining a plurality of third apertures therethrough, and
d) electrode attachments attaching the first corrugated portion and the third corrugated portion to opposite sides of the second corrugated portion;
a cathode;
an ionically conductive medium communicating the fuel electrode and the cathode; and
a metal fuel exposed to the ionically conductive medium, the metal fuel electrochemically despositable on the first corrugated portion, the second corrugated portion, and the third corrugated portion of the fuel electrode.
2. The rechargeable electrochemical cell of claim 1 , wherein
the first corrugation portion has a first corrugation ratio of amplitude to corrugation pitch,
the second corrugation portion has a second corrugation ratio of amplitude to corrugation pitch,
the third corrugation portion has a third corrugation ratio of amplitude to corrugation pitch, and
the first corrugation ratio, the second corrugation ratio, and the third corrugation ratio are each different from one another.
3. The rechargeable electrochemical cell of claim 1 , wherein
the first corrugation portion defines a cross-corrugation axis orthogonal to the first corrugation axis,
the first corrugation portion includes corrugation axis extensions extending parallel to the first corrugation axis, and
the first corrugation portion includes cross-corrugation extensions extending parallel to the cross-corrugation axis.
4. The rechargeable electrochemical cell of claim 3 , wherein each of the corrugation axis extensions has a diameter greater than a diameter of any of the cross-corrugation extensions.
5. The rechargeable electrochemical cell of claim 3 , wherein a subset of the corrugation axis extensions have a first diameter, and a remainder of the corrugation axis extensions have a second diameter different from the first diameter.