Mixed waste plastics compatibilizers for asphalt
An asphalt modifier includes bitumen, polyolefin particles, and one or more alkyl terephthalamides. Preparing an asphalt modifier includes combining one or more alkyl terephthalamides, polyolefin particles, and bitumen, and dispersing the polyolefin particles in the bitumen to yield the asphalt modifier. Digesting polyethylene terephthalate includes combining polyethylene terephthalate with an alkylamine or carboxyalkylamine to yield a reaction mixture, and heating the reaction mixture to a temperature between about 20° C. and about 300° C. to yield an alkyl terephthalamide.
1. An asphalt modifier comprising:
bitumen;
polyolefin particles; and
one or more alkyl terephthalamides represented by the following structure:
wherein each R is independently a C6 to C20 alkyl or C6-C20 carboxyalkyl, and at least one R is a C6 to C20 alkyl, and the polyolefin particles are dispersed throughout the bitumen.
2. The asphalt modifier of claim 1 , wherein each R is independently a C8 to C16 alkyl.
3. The asphalt modifier of claim 2 , wherein each R is independently a C8, C12, or C16 alkyl.
4. The asphalt modifier of claim 1 , wherein the polyolefin particles comprise low-density polyethylene (LDPE), high-density polyethylene (HDPE), linear low-density polyethylene (LLDPE), polypropylene (PP), or any copolymer or combination thereof.
5. The asphalt modifier of claim 1 , wherein the one or more alkyl terephthalamides serve as an interface between the bitumen and the polyolefin particles.
6. The asphalt modifier of claim 1 , wherein the asphalt modifier comprises up to 20 wt % of the polyolefin particles.
7. The asphalt modifier of claim 1 , wherein the asphalt modifier comprises up to 5 wt % of the one or more alkyl terephthalamides.
8. The asphalt modifier of claim 1 , further comprising poly(ethylene terephthalate) oligomers.
9. A method of making the asphalt modifier of claim 1 , the method comprising:
combining:
one or more alkyl terephthalamides represented by the following structure:
wherein each R is independently a C6 to C20 alkyl or C6-C20 carboxyalkyl, and at least one R is a C6 to C20 alkyl;
polyolefin particles; and
bitumen; and
dispersing the polyolefin particles in the bitumen to yield the asphalt modifier.
10. The method of claim 9 , further comprising preparing the one or more alkyl terephthalamides from waste poly(ethylene terephthalamide).
11. The method of claim 9 , wherein dispersing the polyolefin particles in the bitumen occurs at a temperature in a range between about 150° C. and about 200° C.
12. A modified asphalt comprising the asphalt modifier of claim 1 .