Porous composite separator for secondary battery and lithium secondary battery including the same
Provided are a composite separator for a secondary battery and a lithium secondary battery including the same, and specifically, a composite separator for a secondary battery showing excellent physical properties such as thermal safety and electrochemical safety, and a lithium secondary battery including the separator are provided.
1 . A porous composite separator comprising:
a porous substrate; and
a porous coating layer formed by coating one or both surfaces of the porous substrate with a slurry including a gas adsorbent and a binder,
wherein the gas adsorbent is coated or adsorbed with an inorganic acid, and
wherein a content of the inorganic acid relative to a weight of the gas adsorbent is 0.1 to 5 wt %.
2 . The porous composite separator of claim 1 , wherein the inorganic acid is any one or a mixture of two or more selected from inorganic acids including fluorine, sulfur, and nitrogen.
3 . The porous composite separator of claim 1 , wherein the gas adsorbent is any one or a mixture of two or more selected from porous carbon materials, porous metal organic frameworks, porous silica gel, and zeolites.
4 . The porous composite separator of claim 1 , wherein an average size of the gas adsorbent is 5 μm or less.
5 . The porous composite separator of claim 1 , wherein an average pore size of the gas adsorbent is 50 nm or less.
6 . The porous composite separator of claim 1 , wherein a specific surface area of the gas adsorbent by BET measurement is 50 m 2 /g or more.
7 . The porous composite separator of claim 1 , wherein a CO 2 adsorption amount of the gas adsorbent measured at 25° C. under 1 atm is 50 cc/g or more.
8 . The porous composite separator of claim 1 , wherein the porous coating layer is applied on 80% or more of an area of the porous substrate.
9 . The porous composite separator of claim 1 , wherein the binder is any one or a mixture of two or more selected from polyvinylidene fluoride-co-hexafluoropropylene, polyvinylidene fluoride-co-trichloroethylene, polymethylmethacrylate, polyacrylonitrile, polyvinylpyrrolidone, polyvinyl acetate, polyethylene-co-vinyl acetate, polyimide, polyethylene oxide, cellulose acetate, cellulose acetate butyrate, cellulose acetate propionate, cyanoethylpullulan, cyanoethyl polyvinyl alcohol, cyanoethyl cellulose, cyanoethyl sucrose, pullulan, carboxyl methyl cellulose, and polyvinyl alcohol.
10 . The porous composite separator of claim 1 , wherein the porous composite separator has a thickness of 5 to 100 μm.
11 . The porous composite separator of claim 1 , wherein the porous composite separator has a thermal shrinkage measured at 150° C. of 5% or less.
12 . The porous composite separator of claim 1 , wherein the porous composite separator has a puncture strength of 420 gf or more as measured in accordance with a measurement method of ASTM D3763-02.
13 . The porous composite separator of claim 1 , wherein a number of charge and discharge cycles until SOH of a battery including the porous composite separator is 70% is 1000 or more.
14 . A lithium secondary battery comprising the porous composite separator of claim 1 .
15 . The lithium secondary battery of claim 14 , wherein an energy density of a positive electrode active material of the lithium secondary battery is 400 Wh/g or more.
16 . The porous composite separator of claim 1 , wherein the porous coating layer does not include inorganic particles which are different from the gas adsorbent.
17 . The porous composite separator of claim 1 , wherein the inorganic acid is any one or a mixture of two selected from inorganic acids including fluorine, and nitrogen.
18 . A porous composite separator comprising:
a porous substrate; and
a porous coating layer formed by coating one or both surfaces of the porous substrate with a slurry including a gas adsorbent and a binder,
wherein the gas adsorbent is coated or adsorbed with an inorganic acid including fluorine.