Multilayer anode and lithium secondary battery including the same
A multilayer anode includes an anode collector, and a plurality of anode mixture layers sequentially stacked on at least one surface of the anode collector, and including natural graphite as an anode active material. A weight ratio of the natural graphite in innermost and outermost anode mixture layers is greater than a weight ratio of the natural graphite in an anode mixture layer located between the innermost and outermost anode mixture layers, in a stacking direction of the plurality of anode mixture layers. Performance of a cell may be improved and calendering-calender contamination occurring in a calendering process and an electrode stripping phenomenon may be prevented.
1. A multilayer anode comprising:
an anode current collector; and
a plurality of anode mixture layers including
an innermost anode mixture layer and an outermost anode mixture layer in a stacking direction of the anode mixture layers and at least one anode mixture layer positioned between the innermost anode mixture layer and the outermost anode mixture layer,
the innermost anode mixture layer, the outermost anode mixture layer and the at least one anode layer being sequentially stacked on at least one surface of the anode current collector,
wherein the innermost anode mixture layer and the outermost anode mixture layer include natural graphite, and the at least one anode mixture layer positioned between the innermost anode mixture layer and the outermost anode mixture layer includes artificial graphite, and
the natural graphite has a specific surface area smaller than a specific surface area of the artificial graphite at the same particle size.
2. The multilayer anode of claim 1 , wherein a weight ratio of the natural graphite contained in the innermost anode mixture layer and the outermost anode mixture layer is greater than a weight ratio of the natural graphite of the at least one anode mixture layer positioned between the innermost negative electrode mixture layer and the outermost anode mixture layer.
3. The multilayer anode of claim 1 , wherein the anode mixture layer is formed of three or more layers.
4. The multilayer anode of claim 1 , wherein based on a thickness direction of the anode mixture layer from the anode current collector, a weight ratio of the natural graphite in a portion corresponding to 0-20% and 80-100% of a total height of a plurality of the anode mixture layers is greater than a weight ratio of the natural graphite in a portion excluding the portion corresponding to 0-20% and 80-100% of the total height.
5. The multilayer anode of claim 1 , wherein the natural graphite of the innermost anode mixture layer is included in an amount of 50 to 100% by weight based on a total weight of an active material of the innermost anode mixture layer.
6. The multilayer anode of claim 1 , wherein the natural graphite of the outermost anode mixture layer is included in an amount of 50 to 100% by weight based on a total weight of an active material of the outermost anode mixture layer.
7. The multilayer anode of claim 1 , wherein the at least one anode mixture layer located between the innermost and outermost anode mixture layers is located within a range of 21 to 79% in a thickness direction of the anode mixture layer from the anode current collector.
8. The multilayer anode of claim 1 , wherein the anode mixture layer comprises at least one anode active material selected from artificial graphite, natural graphite, soft carbon, hard carbon acetylene carbon black, ketjen black, carbon nanotubes, carbon nanofibers and silicon oxide.
9. The multilayer anode of claim 1 , wherein the anode mixture layer further comprises a binder and a conductive material.
10. A lithium secondary battery comprising the multilayer anode according to claim 1 .