Lower pyrolysis temperature binder for silicon-dominant anodes
Systems and methods are provided for carbon additives for direct coating of silicon-dominant anodes. An example composition for use in directly coated anodes may include a silicon-dominated anode active material, a carbon-based binder, and a carbon-based additive, with the composition being configured for low-temperature pyrolysis. The low-temperature pyrolysis may be conducted at <600° C. An anode may be formed using a direct coating process of the composition on a current collector. The anode active material yields silicon constituting between 86% and 97% of weight of the formed anode after pyrolysis. The carbon-based additive yields carbon constituting between 2% and 6% of weight of the formed anode after pyrolysis.
1. A method of forming an anode of a battery, the method comprising:
mixing a composition comprising a silicon-based active material, a carbon-based binder, and a carbon-based additive, wherein onset of pyrolysis of the composition starts at an onset pyrolysis temperature;
coating a conductive foil with the composition; and
subjecting the coated conductive foil to a pyrolysis process at a temperature less than 600° C. and greater than the onset pyrolysis temperature of the composition, wherein the pyrolysis process pyrolyzes the composition coated on the conductive foil resulting in the anode comprising the conductive foil and an active material layer of the pyrolyzed composition on the conductive foil.
2. The method according to claim 1 , comprising forming a lithium ion battery using the formed anode comprising the conductive foil and the active material layer.
3. The method according to claim 1 , wherein the carbon-based binder comprises polyamide-imide (PAI).
4. The method according to claim 1 , wherein the onset pyrolysis temperature of the composition on the conductive foil is below 500° C.
5. The method according to claim 1 , wherein carbonization of the composition on the conductive foil occurs at less than 600° C.
6. The method according to claim 1 , wherein silicon of the active material layer comprises at least 86% by weight of the formed anode.
7. The method according to claim 6 , wherein the silicon of the active material layer comprises up to 97% by weight of the formed anode.
8. The method according to claim 1 , wherein the carbon-based binder of the active material layer comprises between 4% and 5% by weight of the formed anode.
9. The method according to claim 1 , wherein the carbon-based additive of the active material later comprises between 2% and 6% by weight of the formed anode.
10. The method according to claim 1 , wherein the carbon-based additive comprises at least one of ECP, ECP600, Super-P, and SLP.
11. A method of forming a battery, the method comprising:
mixing a composition comprising a silicon-based active material and a binder, wherein onset of pyrolysis of the composition starts at an onset pyrolysis temperature;
coating a conductive foil with the composition;
pyrolyzing the composition by subjecting the coated conductive foil to a temperature less than 600° C. and greater than the onset pyrolysis temperature of the composition;
forming an anode of the battery from the coated conductive foil with the pyrolyzed composition; and
sandwiching a separator between the anode and a cathode of the battery.
12. The method according to claim 11 , wherein the binder is carbon-based.
13. The method according to claim 11 , wherein the binder comprises polyamide-imide (PAI).
14. The method according to claim 11 , wherein the onset pyrolysis temperature of the composition is below 500° C.
15. The method according to claim 11 , wherein carbonization of the composition occurs at less than 600° C.
16. The method according to claim 11 , wherein silicon of the pyrolyzed composition comprises at least 86% by weight of the formed anode.
17. The method according to claim 16 , wherein the silicon of the pyrolyzed composition comprises up to 97% by weight of the formed anode.
18. The method according to claim 11 , wherein carbon of the pyrolyzed composition comprises between 4% and 5% by weight of the formed anode.
19. The method according to claim 11 , wherein:
the composition includes a carbon-based additive; and
the carbon-based additive of the pyrolyzed composition comprises between 2% and 6% of weight of the formed anode.
20. The method to claim 19 , wherein the carbon-based additive comprises at least one of ECP, ECP600, Super-P, and SLP.