IP Library Granted Patent US 11,560,396
Granted Patent B2
US 11,560,396 · App. 17/718,503 · Granted Jan 24, 2023

Diphosphites having an open and a closed 2,4-methylated outer unit

Inventors: Robert Franke (Marl, DE); Anna Chiara Sale (Recklinghausen, DE); Alexander Brächer (Haltern am See, DE); Dirk Fridag (Haltern am See, DE); Ana Markovic (Haltern am See, DE); Peter Kucmierczyk (Herne, DE); Johannes Knossalla (Gahlen, DE)
Assignee: EVONIK OPERATIONS GMBH
C07F9/65746B01J31/0257B01J31/2213C07B41/06C07F15/0073B01J2231/321B01J2531/822
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Quick Facts
Patent No.
US 11,560,396
App. No.
17/718,503
Granted
Jan 24, 2023
Kind
B2
Abstract

Diphosphites having an open and a closed 2,4-methylated outer unit and use thereof in hydroformylation.

Claims (12)

1. A compound of the structure (I):

where R 1 , R 2 are selected from: —H, —(C 1 -C 12 )-alkyl or —O—(C 1 -C 12 )-alkyl.

2. The compound according to claim 1 , where R 1 , R 2 are selected from: —H, —(C 1 -C 12 )-alkyl.

3. The compound according to claim 1 , where R 1 , R 2 are —(C 1 -C 12 )-alkyl.

4. The compound according to claim 1 , where R 2 are the same radical.

5. The compound according to claim 1 , where the compound has the structure (1):

6. A ligand metal complex comprising a compound according to claim 1 and a substance containing a metal selected from: Rh, Ru, Co or Ir.

7. A process comprising the process steps of:

a) initially charging an olefin,

b) adding a compound according to claim 1 and a substance containing a metal selected from: Rh, Ru, Co or Ir,

c) supplying H 2 and CO, and

d) heating the reaction mixture from steps a) to c), with conversion of the olefin to an aldehyde.

Assignments (2)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jan 9, 2024
From: EVONIK OPERATIONS GMBH
To: EVONIK OXENO GMBH & CO. KG
Reel/Frame 066242/0585 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Nov 7, 2022
From: FRANKE, ROBERT; SALE, ANNA CHIARA; BRÄCHER, ALEXANDER; FRIDAG, DIRK; MARKOVIC, ANA; KUCMIERCZYK, PETER; KNOSSALLA, JOHANNES
To: EVONIK OPERATIONS GMBH
Reel/Frame 061679/0696 →