Additive manufacturing break away support material
An additive manufacturing composition useful as a support material for common build materials (e.g., polyamide or polyester) is comprised of a blend of an elastomer toughened styrenic polymer having discreet domains of polymerized conjugate diene dispersed within a styrenic matrix and a vinyl aromatic-maleic anhydride copolymer. The composition may be used as a support material in additive manufacturing methods such as extrusion methods (e.g., fused filament fabrication). The compositions may be tuned to realize the desired adherence to facilitate the desired support while also allowing for the mechanical removal without breakage of the underlying part or residual adhered support material.
1. A composition comprising a blend of an elastomer toughened styrenic polymer having discreet domains of polymerized conjugate diene dispersed within a styrenic matrix and a vinyl aromatic-maleic anhydride copolymer, wherein the elastomer toughened styrenic polymer is present in an amount of 25% to 50% by weight of the composition and the vinyl aromatic-maleic anhydride copolymer is present in an amount of 20% to 45% by weight of the composition.
2. The composition of claim 1 , wherein the elastomer toughened styrenic polymer is a copolymer of styrene and a conjugated diene and optionally an unsaturated nitrile.
3. The composition of claim 2 , wherein the elastomer toughened styrenic polymer is a copolymer of styrene and butadiene.
4. The composition of claim 1 , wherein the conjugated diene is present in an amount of about 5% to 15% by weight of the elastomer toughened styrenic polymer.
5. The composition of claim 1 , wherein the vinyl aromatic-maleic anhydride copolymer is styrene-maleic anhydride copolymer, a vinyl aromatic block elastomer having maleic anhydride grafted thereto or combination thereof.
6. The composition of claim 5 , wherein the vinyl aromatic block elastomer is styrene-(butadiene)-styrene (SBS), styrene-isoprene-styrene (SIS), styrene isoprene butylene styrene (SIBS), styrene-(ethylene-butylene)-styrene (SEBS) or mixture thereof.
7. The composition of claim 6 , wherein the vinyl aromatic block elastomer is the SEBS.
8. The composition of claim 1 , wherein the vinyl aromatic-maleic anhydride copolymer has a maleic anhydride amount that is about 5% to 50% by weight of the vinyl aromatic-maleic anhydride copolymer.
9. The composition of claim 1 , further comprised of a copolymer of an acrylate and a vinyl aromatic monomer.
10. The composition of claim 9 , wherein the acrylate-vinyl aromatic copolymer is further comprised of a conjugated diene, unsaturated nitrile or combination thereof.
11. The composition of claim 10 , wherein the acrylate-vinyl aromatic copolymer is a copolymer of methyl methacrylate-acrylonitrile-butadiene-styrene (MABS).
12. The composition of claim 1 , wherein the composition is a filament.
13. The composition of claim 12 , wherein the filament has a diameter of about 1 millimeter to about 3 millimeters.