Polymer foam particles and process for production thereof based on polybutylene terephthalate
The invention relates to polymer foam particles, both in expanded and partly expanded form, from a polymer matrix based on a blend comprising polybutylene terephthalate and polyethylene terephthalate, to a process for production thereof, and to the use of polyethylene terephthalate for broadening the processing window of polybutylene terephthalate-based polymer foam particles in processing to give mouldings.
1. A polymer foam particle comprising at least one blowing agent selected from the group consisting of air, nitrogen and carbon dioxide, and 25 to 320 parts by mass of polyethylene terephthalate per 100 parts by mass of polybutylene terephthalate.
2. The polymer foam particle according to claim 1 , wherein the particle has a density of 50 to 700 kg/m 3 .
3. The polymer foam particle according to claim 1 , wherein the particle has a density of 90 to 400 kg/m 3 .
4. The polymer foam particle according to claim 1 , wherein the particle further comprises 0.1 to 20 parts by mass per 100 parts by mass of polybutylene terephthalate of talc.
5. The polymer foam particle according to claim 1 , wherein the particle further comprises 0.1 to 5 parts by mass per 100 parts by mass of polybutylene terephthalate of talc.
6. The polymer foam particle according to claim 4 , wherein the particle further comprises 0.1 to 20 parts by mass per 100 parts by mass of polybutylene terephthalate of at least one further additive other than talc.
7. The polymer foam particle according to claim 4 , wherein the particle further comprises 0.1 to 5 parts by mass per 100 parts by mass of polybutylene terephthalate of at least one further additive other than talc.
8. The polymer foam particle according to claim 6 , wherein the at least one further additive is selected from the group consisting of UV stabilizers, thermal stabilizers, lubricants, demoulding agents, fillers, reinforcers, nucleating agents, laser absorbers, di-or polyfunctional branching or chain-extending additives, hydrolysis stabilizers, antistats, emulsifiers, plasticizers, processing auxiliaries, flow auxiliaries, elastomer modifiers and colourants.
9. The polymer foam particle according to claim 6 , wherein the at least one further additive is tetrakis (2,4-di-tert-butylphenyl) 4,4′-biphenyldiphosphonite.
10. A process for producing polymer foam particles of claim 1 , the method comprising the steps of:
(a) introducing powders or pellets of a polymer matrix into an extruder with exclusion of crosslinking agents and/or chain-extending agents and plasticizing and homogenizing the powders or pellets,
(b) adding and dispersing into the plasticized polymer matrix a blowing agent selected from the group consisting of air, nitrogen and carbon dioxide,
(c) discharging the plasticized polymer matrix with the added blowing agent through an extruder die,
(d) pelletizing downstream of the extruder die the extruded polymer matrix strand with the added blowing agent to form expandable or at least partly expanded polymer foam particles, and
(e) expanding the polymer foam particles, wherein
the polymer matrix contains 25 to 320 parts by mass of polyethylene terephthalate per 100 parts by mass of polybutylene terephthalate.
11. The process according to claim 10 , wherein the process steps (c) and (d) are performed with or in a cooling fluid.
12. The process according to claim 10 , wherein the process step (e) is effected in a continuous infrared oven.
13. The process according to claim 10 , wherein the polymer foam particles have a density in the range from 50 to 700 kg/m3.
14. The process according to claim 10 , wherein the polymer foam particles have a density in the range from 90 to 400 kg/m 3 .
15. The process according to claim 13 , wherein the polymer matrix further comprises 0.1 to 20 parts by mass per 100 parts by mass of polybutylene terephthalate of talc.
16. The process according to claim 13 , wherein the polymer matrix further comprises 0.1 to 5 parts by mass per 100 parts by mass of polybutylene terephthalate of talc.
17. The process according to claim 15 , wherein the polymer matrix further comprises 0.1 to 20 parts by mass per 100 parts by mass of polybutylene terephthalate of at least one additive other than talc.
18. The process according to claim 15 , wherein the polymer matrix additionally contains 0.1 to 5 parts by mass per 100 parts by mass of polybutylene terephthalate of at least one additive other than talc.
19. The process according to claim 17 , wherein the least one additive other than talc is selected from the group consisting of UV stabilizers, thermal stabilizers, lubricants, demoulding agents, fillers, reinforcers, nucleating agents, laser absorbers, di-or polyfunctional branching or chain-extending additives, hydrolysis stabilizers, antistats, emulsifiers, plasticizers, processing auxiliaries, flow auxiliaries, elastomer modifiers and colourants.
20. The process according to claim 17 , wherein the at least one additive other than talc is tetrakis (2,4-di-tert-butylphenyl) 4,4′-biphenyldiphosphonite.