Drawability enhancement in polymer thin films
A method includes applying a stress to a polymer thin film to stretch the polymer thin film along a first in-plane direction, and subsequently applying a stress to the polymer thin film to stretch the polymer thin film along a second in-plane direction orthogonal to the first in-plane direction to form an ultra-high modulus polymer thin film. Calendaring or hot pressing of the ultra-high modulus polymer thin film may improve its optical and/or thermal properties.
1. A method comprising:
applying a first stress to a polymer thin film to stretch the polymer thin film along a first in-plane direction;
applying a second stress to the polymer thin film to stretch the polymer thin film along a second in-plane direction orthogonal to the first in-plane direction to form an anisotropic polymer thin film having an elastic modulus along at least one in-plane direction of at least approximately 30 GPa; and
feeding the anisotropic polymer thin film through a nip opening of a pair of counter-rotating calendar rollers to form a calendared polymer thin film, wherein the calendared polymer thin film comprises a void volume of less than approximately 25% and an average void size of less than approximately 100 nm.
2. The method of claim 1 , wherein the first stress is applied prior to the second stress.
3. The method of claim 1 , wherein the first stress and the second stress are applied simultaneously.
4. The method of claim 1 , wherein the polymer thin film comprises polyethylene having a weight-averaged molecular weight of at least approximately 100,000 g/mol.
5. The method of claim 1 , comprising heating the polymer thin film to a temperature greater than a glass transition temperature of the polymer while applying each of the first stress and the second stress.
6. The method of claim 1 , comprising increasing a temperature of the polymer thin film while applying at least one of the first stress and the second stress.
7. The method of claim 1 , wherein a strain rate associated with deformation of the polymer thin film decreases while applying at least one of the first stress and the second stress.