Batteries utilizing anode coatings directly on nanoporous separators
Provided are methods of preparing a separator/anode assembly for use in an electric current producing cell, wherein the assembly comprises an anode current collector layer interposed between a first anode layer and a second anode layer and a porous separator layer on the side of the first anode layer opposite to the anode current collector layer, wherein the first anode layer is coated directly on the separator layer.
1. A lithium battery comprising:
an anode layer comprising a pigment dispersion, wherein said pigment dispersion comprises an organic solvent, an anode active material in pigment form, and a conductive carbon pigment;
a porous separator layer, wherein said porous separator layer is selected so that there is no penetration of said conductive carbon pigment into said porous separator layer; and
an anode current collector, wherein said anode layer is disposed between said porous separator layer and said anode current collector.
2. The lithium battery of claim 1 , wherein said porous separator layer is selected so that there is no penetration of said anode active material into the porous separator layer.
3. The lithium battery of claim 1 , wherein said porous separator layer has an average pore diameter that is smaller than the average diameter of said anode active material in pigment form.
4. The lithium battery of claim 1 , wherein said porous separator layer has an average pore diameter that is smaller than the average diameter of said conductive carbon pigment.
5. The lithium battery of claim 1 , wherein said anode current collector comprises a metal.
6. The lithium battery of claim 1 , wherein said anode active material in pigment form has a diameter between 0.5 to 5 microns.
7. The lithium battery of claim 1 , wherein said anode layer has a contour that matches the contour of the said porous separator layer.
8. A lithium battery comprising:
an anode layer comprising a pigment dispersion, wherein said pigment dispersion comprises an organic solvent or water, an anode active material in pigment form, and a conductive carbon pigment; wherein said anode active material in pigment form has a diameter between 0.5 to 5 microns;
a porous separator layer, wherein said porous separator layer has an average pore diameter that is less than 0.2 microns; and
an anode current collector, wherein said anode layer is disposed between said porous separator layer and said anode current collector.
9. The lithium battery of claim 8 , wherein said porous separator layer has an average pore diameter that is less than 0.1 microns.
10. The lithium battery of claim 8 , wherein said anode current collector layer comprises a metal.
11. The lithium battery of claim 8 , wherein said porous separator layer is selected so that there is no penetration of said anode active material into the porous separator layer.
12. The lithium battery of claim 8 , wherein said porous separator layer is selected so that there is no penetration of said conductive carbon pigment into said porous separator layer.
13. The lithium battery of claim 8 , wherein said porous separator layer has an average pore diameter that is smaller than the average diameter of said anode active material in pigment form.
14. The lithium battery of claim 8 , wherein said porous separator layer has an average pore diameter that is smaller than the average diameter of said conductive carbon pigment.
15. The lithium battery of claim 8 , wherein said anode layer has a contour that matches the contour of the said porous separator layer.
16. A lithium battery comprising:
an anode layer comprising a pigment dispersion, wherein said pigment dispersion comprises an organic solvent, an anode active material in pigment form, and a conductive pigment;
a porous separator layer, wherein said porous separator layer is selected so that there is no penetration of said conductive pigment into said porous separator layer; and
an anode current collector, wherein said anode layer is disposed between said porous separator layer and said anode current collector.
17. The lithium battery of claim 16 , wherein said porous separator layer is selected so that there is no penetration of said anode active material into the porous separator layer.
18. The lithium battery of claim 16 , wherein said porous separator layer has an average pore diameter that is smaller than the average diameter of said anode active material in pigment form.
19. The lithium battery of claim 16 , wherein said porous separator layer has an average pore diameter that is smaller than the average diameter of said conductive pigment.
20. The lithium battery of claim 16 , wherein said anode current collector comprises a metal.
21. The lithium battery of claim 16 , wherein said anode active material in pigment form has a diameter between 0.5 to 5 microns.