Nickel foil for production of thin-film capacitor, and manufacturing method for same
Provided is an electrolytic nickel foil including, on at least one surface thereof, a flat surface having the following surface roughness: a Ra of 0.05 μm or less, a Rz of 0.2 μm or less, and a Rt of 0.5 μm or less and a glossiness of 200 GU or more as determined by measuring a 60° specular reflection angle.
1. A method of preparing an electrolytic nickel foil for a thin film capacitor, on at least one surface thereof, a flat surface having an arithmetic average roughness (Ra) of 0.05 μm or less, a ten-point average roughness (Rz) of 0.20 μm or less, a maximum protrusion height (Rt) of 0.50 μm or less, and a 60° specular gloss of 200 GU or more,
wherein the method comprises performing electrolytic plating with an electrolyte including 400 to 600 g/L of a nickel ion precursor, 10 to 30 g/L of a pH buffer, and 0.5 to 2.0 g/L of a roughness controlling agent and having a pH of 1 to 5, and
wherein the roughness controlling agent comprises saccharin and sodium allyl sulfonate, and
the concentration ratio of saccharin and sodium allyl sulfonate is 1:0.05 to 1:20.
2. The method of claim 1 , wherein the nickel ion precursor is one or more selected from the group consisting of nickel sulfate, nickel sulfamate, nickel chloride, and nickel nitrate.
3. The method of claim 1 , wherein the electrolytic plating is performed by applying current at a current density of 10 to 100 A/dm2 at 40° C. to 60° C.
4. A method of preparing an electrolytic nickel foil for a thin film capacitor, on at least one surface thereof, a flat surface having an arithmetic average roughness (Ra) of 0.05 μm or less, a ten-point average roughness (Rz) of 0.20 μm or less, a maximum protrusion height (Rt) of 0.50 μm or less, and a 60° specular gloss of 200 GU or more,
wherein the method comprises performing electrolytic plating with an electrolyte including 400 to 600 g/L of a nickel ion precursor, 10 to 30 g/L of a pH buffer, and 0.5 to 2.0 g/L of a roughness controlling agent and having a pH of 1 to 5, and
wherein the roughness controlling agent comprises 0.1 to 1 g/L of saccharin and 0.4 to 0.8 g/L of sodium allyl sulfonate, and wherein the roughness controlling agent is less than 0.04 wt % of the electrolyte.
5. The method of claim 4 , wherein the nickel ion precursor is one or more selected from the group consisting of nickel sulfate, nickel sulfamate, nickel chloride, and nickel nitrate.
6. The method of claim 4 , wherein the electrolytic plating is performed by applying current at a current density of 10 to 100 A/dm2 at 40° C. to 60° C.