IP Library Granted Patent US 12,116,732
Granted Patent B2
US 12,116,732 · App. 17/754,082 · Granted Oct 15, 2024

Paper products incorporating surface enhanced pulp fibers and having decoupled wet and dry strengths and methods of making the same

Inventors: Bradley Langford (Fort Mill, SC); David Lloyd (Fort Mill, SC); Brian Ranson (Fort Mill, SC); Gwen Johnston (Fort Mill, SC); Dale Kavalew (Fort Mill, SC)
Assignee: Domtar Paper Company, LLC
D21H27/40D21D1/34D21H11/02D21H17/26D21H17/55D21H21/20D21H27/02B31F1/07
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Quick Facts
Patent No.
US 12,116,732
App. No.
17/754,082
Granted
Oct 15, 2024
Kind
B2
Abstract

A method of making a paper product can comprise making one or more sheets at least by, for each of the sheet(s), forming a web from one or more furnishes that comprise fibers dispersed in water. The fibers of the furnish(es) can comprise a plurality of first fibers that are hardwood fibers and a plurality of second fibers that include softwood fibers and surface enhanced pulp fibers (SEPF), the SEPF having a length weighted average fiber length of at least 0.20 mm. The method can comprise at least partially dewatering the web to form the sheet. The sheet(s) can be laminated and/or embossed such that a total dry tensile strength of the paper product is less than or equal to 90% of the sum of the total dry tensile strength(s) of the sheet(s).

Claims (62)

1. A method of making a paper product, the method comprising:

laminating and/or embossing one or more sheets such that a total dry tensile strength of the paper product is less than or equal to 90% of the sum of the total dry tensile strength(s) of the sheet(s);

wherein each of the sheet(s) comprises one or more furnishes each comprising:

a plurality of first fibers that are hardwood fibers; and

a plurality of second fibers including softwood fibers and surface enhanced pulp fibers (SEPF) having a length weighted average fiber length that is at least 0.20 millimeters (mm), wherein the SEPF are made by refining a pulp feed, the refining including for each of one or more mechanical refiners:

introducing the pulp feed between two refining elements of the refiner, each of the refining elements comprising:

a plurality of bars, each protruding from a surface of the refining element and having a width that is less than or equal to 1.3 mm; and

a plurality of grooves defined by the bars, each having a width that is less than or equal to 2.5 mm; and

rotating at least one of the refining elements;

wherein refining the pulp feed is performed such that the refiner(s) consume at least 300 kilowatt-hours (kWh) per ton of fiber in the pulp feed; and

introducing one or more wet strength resins to the one or more furnishes such that, per ton of fiber in the one or more furnishes, at least 13 kilograms (kg) of a first wet strength resin and/or at least 2.5 kg of a second wet strength resin are introduced,

wherein the paper product has a basis weight of greater than 51.6 gsm; and

wherein by weight:

at least 90% of the second fibers are the softwood fibers; and

between 1% and 10% of the second fibers are the SEPF.

2. The method of claim 1 , wherein:

the one or more sheets comprise two or more sheets; and

the method comprises laminating the sheets.

3. The method of claim 1 , comprising embossing the sheet(s).

4. A method of making a paper product, the method comprising:

making one or more sheets at least by, for each of the sheet(s):

forming a web from one or more furnishes that comprise fibers dispersed in water, the fibers of the furnish(es) comprising:

a plurality of first fibers that are hardwood fibers; and

a plurality of second fibers including softwood fibers and surface enhanced pulp fibers (SEPF) having a length weighted average fiber length that is at least 0.20 millimeters (mm), wherein the SEPF are made by refining a pulp feed, the refining including for each of one or more mechanical refiners:

introducing the pulp feed between two refining elements of the refiner, each of the refining elements comprising:

 a plurality of bars, each protruding from a surface of the refining element and having a width that is less than or equal to 1.3 mm; and

 a plurality of grooves defined by the bars, each having a width that is less than or equal to 2.5 mm; and

rotating at least one of the refining elements;

wherein refining the pulp feed is performed such that the refiner(s) consume at least 300 kilowatt-hours (kWh) per ton of fiber in the pulp feed;

introducing one or more wet strength resins to the one or more furnishes such that, per ton of fiber in the one or more furnishes, at least 13 kilograms (kg) of a first wet strength resin and/or at least 2.5 kg of a second wet strength resin are introduced; and

at least partially dewatering the web to form the sheet; and

laminating and/or embossing the sheet(s) such that a total dry tensile strength of the paper product is less than or equal to 90% of the sum of the total dry tensile strength(s) of the sheet(s),

wherein the paper product has a basis weight of greater than 51.6 gsm; and

wherein by weight:

at least 90% of the second fibers are the softwood fibers; and

between 1% and 10% of the second fibers are the SEPF.

5. The method of claim 4 ,

wherein the first wet strength resin comprises polyamide-epichlorohydrin and the second wet strength resin comprises carboxymethyl cellulose.

6. The method of claim 4 , wherein by weight:

between 10% and 35% of the fibers of the furnish(es) are the first fibers; and

at least 40% of the fibers of the furnish(es) are the second fibers.

7. A paper product comprising:

a first plurality of first fibers that are hardwood fibers;

a second plurality of second fibers including softwood fibers and surface enhanced pulp fibers (SEPF), wherein the SEPF are made by refining a pulp feed, the refining including for each of one or more mechanical refiners:

introducing the pulp feed between two refining elements of the refiner, each of the refining elements comprising:

a plurality of bars, each protruding from a surface of the refining element and having a width that is less than or equal to 1.3 millimeters (mm); and

a plurality of grooves defined by the bars, each having a width that is less than or equal to 2.5 mm; and

rotating at least one of the refining elements;

wherein refining the pulp feed is performed such that the refiner(s) consume at least 300 kilowatt-hours (kWh) per ton of fiber in the pulp feed;

one or more plies comprising the first and second fibers; and

one or more wet strength resins comprising, per ton of fiber in the paper product, at least 13 kilograms (kg) of polyamide-epichlorohydrin and/or at least 2.5 kg of carboxymethyl cellulose;

wherein:

the one or more plies comprise two or more plies that are coupled together; and/or the paper product is embossed; and

by weight:

at least 90% of the second fibers are the softwood fibers; and

between 1% and 10% of the second fibers are the SEPF.

8. The paper product of claim 7 , wherein the one or more plies comprise two or more plies that are coupled together.

9. The paper product of claim 7 , wherein the paper product is embossed.

10. The paper product of claim 7 , wherein by weight between 10% and 35% of the fibers of the paper product are the first fibers; and

at least 40% of the fibers of the paper product are the second fibers.

11. The paper product of claim 7 , wherein the paper product has a basis weight that is less than or equal to 26 gsm per ply.

12. The paper product of claim 7 , wherein the paper product is a paper towel.

Assignments (6)
SECURITY INTEREST Recorded Jan 30, 2025
From: RESOLUTE FP US INC.; EAM CORPORATION; DOMTAR PAPER COMPANY, LLC
To: BANK MANDIRI (EUROPE) LIMITED, AS THE COLLATERAL AGENT
Reel/Frame 070059/0666 →
SECURITY AGREEMENT (SUPPLEMENT NO. 2 - 1ST LIEN) Recorded Mar 3, 2023
From: RESOLUTE FP US INC.; DOMTAR PAPER COMPANY, LLC
To: BARCLAYS BANK PLC, AS COLLATERAL AGENT
Reel/Frame 062945/0329 →
SECURITY AGREEMENT (SUPPLEMENT NO. 2 - ABL) Recorded Mar 2, 2023
From: RESOLUTE FP US INC.; DOMTAR PAPER COMPANY, LLC
To: BARCLAYS BANK PLC, AS COLLATERAL AGENT
Reel/Frame 062914/0333 →
NOTES PATENT SECURITY AGREEMENT Recorded Mar 2, 2023
From: DOMTAR PAPER COMPANY, LLC
To: THE BANK OF NEW YORK MELLON, AS COLLATERAL AGENT
Reel/Frame 062914/0676 →
TERM LOAN PATENT SECURITY AGREEMENT Recorded Mar 1, 2023
From: DOMTAR PAPER COMPANY, LLC
To: COBANK, ACB, AS COLLATERAL AGENT
Reel/Frame 062902/0610 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded May 9, 2022
From: LANGFORD, BRADLEY; LLOYD, DAVID; RANSON, BRIAN; JOHNSTON, GWEN; KAVALEW, DALE
To: DOMTAR PAPER COMPANY, LLC
Reel/Frame 059869/0114 →
Continuity (2)
Provisional Application 62904413 · Sep 23, 2019
Related Publication 20220333314A1 · Oct 20, 2022