Polarizing plate and optical display device comprising same
Provided are a polarizing plate and an optical display device comprising same, wherein: the polarizing plate comprises a polarizer, a protection film formed on the surface of the polarizer, and a barrier layer formed on the other surface of the polarizer; the barrier layer is formed of a composition comprising a (meth)acryl-based copolymer, a curing agent, and a silane coupler; and the curing agent comprises a mixture of: a polyisocyanate curing agent containing a plurality of units, each containing an entirety of an alkylene group of two or more carbon atoms having a urethane bonding; and a polyisocyanate curing agent containing an isocyanurate group.
1 . A polarizing plate comprising:
a polarizer;
a protective film formed on one surface of the polarizer; and
a barrier layer formed on the other surface of the polarizer,
wherein the barrier layer is formed of a composition comprising
a (meth)acrylic copolymer,
a curing agent, and
a silane coupling agent,
the curing agent comprising a mixture of
a polyisocyanate curing agent comprising a plurality of units, each containing an alkylene group having a urethane bond and at least two carbon atoms, and an isocyanurate group-containing polyisocyanate curing agent comprising an isocyanurate of an aromatic isocyanate compound, and
wherein the aromatic isocyanate compound is at least one selected from among toluene diisocyanate, xylylene diisocyanate, halogenated toluene diisocyanate, phenylene diisocyanate, or tetramethyl-xylylene diisocyanate.
2 . The polarizing plate according to claim 1 , wherein the aromatic isocyanate compound is at least one selected from among toluene diisocyanate, halogenated toluene diisocyanate, or phenylene diisocyanate.
3 . The polarizing plate according to claim 1 , wherein the aromatic isocyanate compound is at least one selected from among toluene diisocyanate or halogenated toluene diisocyanate.
4 . The polarizing plate according to claim 1 , wherein a weight ratio of the polyisocyanate curing agent comprising a plurality of units each containing an alkylene group having a urethane bond and at least two carbon atoms to the isocyanurate group-containing polyisocyanate curing agent is in the range of 10:1 to 30:1.
5 . The polarizing plate according to claim 1 , wherein the polyisocyanate curing agent comprising a plurality of units each containing an alkylene group having a urethane bond and at least two carbon atoms comprises a polyisocyanate curing agent comprising a plurality of units represented by Formula 1:
*—R 1 —O—(C═O)—NH—R 2 —NCO, [Formula 1]
where * is a linking site; and R 1 and R 2 are the same or different from each other and a bivalent C 2 to C 20 aliphatic hydrocarbon group.
6 . The polarizing plate according to claim 5 , wherein R 2 in Formula 1 is a C 6 alkylene group.
7 . The polarizing plate according to claim 1 , wherein the silane coupling agent comprises an epoxy group-containing silane coupling agent.
8 . The polarizing plate according to claim 1 , wherein the composition comprises: 100 parts by weight of the (meth)acrylic copolymer; 10 parts by weight to 30 parts by weight of the polyisocyanate curing agent comprising a plurality of units each containing an alkylene group having a urethane bond and at least two carbon atoms; 0.1 parts by weight to 5 parts by weight of the isocyanurate group-containing polyisocyanate curing agent; and 0.1 parts by weight to 10 parts by weight of the silane coupling agent.
9 . The polarizing plate according to claim 7 , wherein the silane coupling agent further comprises an isocyanurate group-containing silane coupling agent.
10 . The polarizing plate according to claim 9 , wherein a weight ratio of the epoxy group-containing silane coupling agent to the isocyanurate group-containing silane coupling agent is in the range of 1:0.1 to 1:10.
11 . The polarizing plate according to claim 9 , wherein the isocyanurate group-containing silane coupling agent comprises a compound represented by Formula 3:
where R 1 , R 2 and R 3 are each independently a bivalent organic group, and R 4 , R 5 and R 6 are each independently an alkoxysilane group.
12 . The polarizing plate according to claim 9 , wherein the isocyanurate group-containing silane coupling agent is present in an amount of 0.1 parts by weight to 5 parts by weight relative to 100 parts by weight of the (meth)acrylic copolymer.
13 . The polarizing plate according to claim 1 , wherein the (meth)acrylic copolymer comprises a copolymer of a monomer mixture comprising 50 wt % to 80 wt % of a (meth)acrylic monomer having a glass transition temperature of 70° C. or more in a homopolymer phase.
14 . The polarizing plate according to claim 13 , wherein the (meth)acrylic monomer having a glass transition temperature of 70° C. or more in a homopolymer phase is at least one selected from among methyl methacrylate or isobornyl acrylate.
15 . The polarizing plate according to claim 13 , wherein the monomer mixture further comprises a hydroxyl group-containing (meth)acrylic monomer.
16 . The polarizing plate according to claim 1 , wherein the barrier layer has a modulus of 100 MPa or more at 25° C.
17 . The polarizing plate according to claim 1 , wherein the polarizing plate has a maximum decolorized length of 1,000 μm or less, as measured on the polarizer after the polarizing plate is left at 85° C. or 60° C. and at 95% relative humidity (RH) for 250 hours.
18 . An optical display device comprising the polarizing plate according to claim 1 .