Yttrium-doped catalyst support
Disclosed herein are oxidation catalyst compositions comprising a first platinum group metal (PGM) component, a manganese (Mn) component, a first refractory metal oxide support material, and a metal component comprising yttrium, lanthanum, tin, magnesium, cerium, titanium, or a combination of any of the foregoing, wherein each of the first PGM component, the Mn component, and the metal component are supported on the first refractory metal oxide support material; catalyst articles coated with at least one such catalyst composition; and emission treatment systems including at least one such catalyst article.
1 . An oxidation catalyst composition comprising:
a first platinum group metal (PGM) component;
a manganese (Mn) component;
a first refractory metal oxide support material; and
a metal component comprising yttrium, lanthanum, tin, magnesium, cerium, titanium, or a combination thereof,
wherein the first PGM component, the manganese component, and the metal component are supported on the first refractory metal oxide support material;
wherein the first PGM component is platinum or a combination of platinum and palladium;
wherein a molar ratio of yttrium to manganese is from about 0.1 to about 10.
2 . The oxidation catalyst composition of claim 1 , wherein the Mn component is present in an amount ranging from about 0.1% to about 10% by weight, based on the total weight of the composition and calculated as the oxide.
3 . The oxidation catalyst composition of claim 1 , wherein the Mn component is selected from a group consisting of MnO, Mn 2 O 3 , MnO 2 , and combinations thereof.
4 . The oxidation catalyst composition of claim 1 , wherein the first PGM component is present in an amount ranging from about 0.1% to about 20% by weight, based on the weight of the composition.
5 . The oxidation catalyst composition of claim 1 , wherein:
the first PGM component is a combination of platinum and palladium; and the ratio of platinum to palladium by weight is from about 20 to about 0.1.
6 . The oxidation catalyst composition of claim 1 , wherein the first refractory metal oxide support comprises alumina, silica, zirconia, titania, ceria, or a combination thereof.
7 . The oxidation catalyst composition of claim 1 , wherein the first refractory metal oxide support is selected from a group consisting of gamma alumina, silica doped alumina, ceria doped alumina, zirconia doped alumina, and titania doped alumina.
8 . The oxidation catalyst composition of claim 1 , wherein the first refractory metal oxide support is selected from gamma alumina and alumina doped with an amount ranging from about 1% to about 20% by weight of SiO 2 .
9 . The oxidation catalyst composition of claim 1 , further comprising a first zeolite.
10 . The oxidation catalyst composition of claim 9 , wherein the first zeolite has a framework type selected from a group consisting of AFI, AFR, AFS, AFY, ASV, ATO, ATS, BEA, BEC, BOG, BPH, BSV, CAN, CON, CZP, DFO, EMT, EON, EZT, FAU, GME, GON, IFR, ISV, ITG, IWR, IWS, IWV, IWW, JSR, LTF, LTL, MAZ, MEI, MOR, MOZ, MSE, MTW, NPO, OFF, OKO, OSI, RON, RWY, SAF, SAO, SBE, SBS, SBT, SEW, SFE, SFO, SFS, SFV, SOF, SOS, STO, SSF, SSY, USI, UWY, VET, and mixtures or intergrowths thereof.
11 . The oxidation catalyst composition of claim 9 , wherein the first zeolite is ZSM-5, beta zeolite, mordenite, Y zeolite, chabazite, ferrierite, or a combination thereof.
12 . A catalytic article comprising:
a substrate having an inlet end and an outlet end defining an overall length; and
a catalytic coating comprising one or more washcoats disposed on at least a portion of the overall length of the substrate, wherein at least one of said washcoats comprises an oxidation catalyst composition of claim 1 .
13 . The catalytic article of claim 12 , wherein the catalytic coating comprises:
a first washcoat comprising an oxidation catalyst composition of claim 1 disposed on at least a portion of the overall length of the catalyst substrate; and
a second washcoat disposed on at least a portion of the overall length of the substrate, the second washcoat comprising:
a second PGM component supported on a second refractory metal oxide support material; and
a second zeolite,
wherein the oxidation catalyst composition comprising:
a first platinum group metal (PGM) component;
a manganese (Mn) component;
a first refractory metal oxide support material; and
a metal component comprising yttrium, lanthanum, tin, magnesium, cerium, titanium, or a combination thereof,
wherein the first PGM component, the manganese component, and the metal component are supported on the first refractory metal oxide support material;
wherein the first PGM component is platinum or a combination of platinum and palladium;
wherein a molar ratio of yttrium to manganese is from about 0.1 to about 10.
14 . The catalytic article of claim 13 , wherein the second zeolite has a framework type selected from a group consisting of AFI, AFR, AFS, AFY, ASV, ATO, ATS, BEA, BEC, BOG, BPH, BSV, CAN, CON, CZP, DFO, EMT, EON, EZT, FAU, GME, GON, IFR, ISV, ITG, IWR, IWS, IWV, IWW, JSR, LTF, LTL, MAZ, MEI, MOR, MOZ, MSE, MTW, NPO, OFF, OKO, OSI, RON, RWY, SAF, SAO, SBE, SBS, SBT, SEW, SFE, SFO, SFS, SFV, SOF, SOS, STO, SSF, SSY, USI, UWY, VET, and mixtures or intergrowths thereof.
15 . The catalytic article of claim 13 , wherein the second zeolite is ZSM-5, beta zeolite, mordenite, Y zeolite, chabazite, ferrierite, or a combination thereof.
16 . The catalytic article of claim 13 , wherein the second zeolite is beta zeolite, and the beta zeolite is promoted with iron in an amount ranging from about 0.5% to about 10% by weight, calculated as the oxide.
17 . The catalytic article of claim 13 , wherein the second PGM component is platinum or a combination of platinum and palladium, and the ratio of platinum to palladium by weight is from about 0.1 to about 20.
18 . The catalytic article of claim 13 , wherein the second refractory metal oxide support is selected from gamma alumina and alumina doped with from about 1% to about 20% by weight of SiO 2 .
19 . The catalytic article of claim 13 , wherein the second washcoat is substantially free of a manganese component.
20 . The catalytic article of claim 13 , wherein the second washcoat is substantially free of any yttrium component.
21 . The catalytic article of claim 13 , wherein the second washcoat is disposed directly on the substrate, and the first washcoat is on at least a portion of the second washcoat.
22 . The catalytic article of claim 13 , wherein the first washcoat is disposed directly on the substrate, and the second washcoat is on at least a portion of the first washcoat.
23 . The catalytic article of claim 13 , wherein the catalytic article possesses a zoned configuration, the first washcoat is disposed on the catalyst substrate from the outlet end to a length from about 10% to about 80% of the overall length, and the second washcoat is disposed on the catalyst substrate from the inlet end to a length from about 30% to about 90% of the overall length.
24 . The catalytic article of claim 13 , further comprising a third washcoat comprising a third refractory metal oxide impregnated with a third PGM component comprising platinum and palladium.
25 . The catalytic article of claim 24 , wherein the third refractory metal oxide is gamma alumina or alumina doped with an amount ranging from about 1% to about 20% SiO 2 .
26 . The catalytic article of claim 24 , wherein the third washcoat is disposed directly on the substrate, and the first and second washcoats are disposed on at least a portion of the third washcoat.
27 . The catalytic article of claim 24 , wherein the catalytic article possesses a zoned configuration, the third washcoat is disposed directly on the substrate, the first washcoat is disposed on the third washcoat from the outlet end to a length from about 10% to about 80% of the overall length, and the second washcoat is disposed on the third washcoat from the inlet end to a length from about 30% to about 90% of the overall length.
28 . An exhaust gas treatment system comprising the catalytic article of claim 13 , wherein the catalytic article is downstream of and in fluid communication with an internal combustion engine.
29 . A method for treating an exhaust gas stream comprising hydrocarbons and/or carbon monoxide and/or NO x , the method comprising passing the exhaust gas stream through the catalytic article of claim 13 , or the exhaust gas treatment system of claim 28 .
30 . A method for treating an exhaust gas stream comprising hydrocarbons and/or carbon monoxide and/or NO x , the method comprising passing the exhaust gas stream through the exhaust gas treatment system of claim 28 .
31 . An oxidation catalyst composition comprising:
a first platinum group metal (PGM) component;
a manganese (Mn) component;
a first refractory metal oxide support material; and
a metal component comprising yttrium or an oxide thereof,
wherein the first PGM component, the manganese component, and the metal component are supported on the first refractory metal oxide support material,
wherein the yttrium is present in an amount by weight ranging from about 0.5% to about 10%, based on the total weight of the composition and calculated as the oxide.