IP Library Granted Patent US 12,415,738
Granted Patent B2
US 12,415,738 · App. 17/779,596 · Granted Sep 16, 2025

Fluorocarbon destruction method

Inventors: Chad L. Felch (Kronenwetter, WI); Philip A. Burclaff (Weston, WI)
Assignee: Lummus Technology LLC
C02F1/4672B01J41/04B01J49/57C02F1/42C02F2101/36C02F2303/16
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Quick Facts
Patent No.
US 12,415,738
App. No.
17/779,596
Granted
Sep 16, 2025
Kind
B2
Abstract

A method of destroying a fluorocarbon compound includes regenerating an adsorbent to remove the fluorocarbon compound and to produce a regeneration fluid having a concentration of the fluorocarbon compound and directing the regeneration fluid to an electro-oxidation system. The method also includes applying a current to the electro-oxidation system to oxidize the fluorocarbon compound within the regeneration fluid and measuring a quantity of fluorides in the regeneration fluid to determine the progress of the removal of the fluorocarbon compound from the regeneration fluid.

Claims (23)

1. A method of destroying a fluorocarbon compound, the method comprising:

regenerating an adsorbent to remove the fluorocarbon compound and to produce a regeneration fluid having a concentration of the fluorocarbon compound;

directing the regeneration fluid to an electro-oxidation system;

applying a current to the electro-oxidation system to oxidize the fluorocarbon compound within the regeneration fluid; and

measuring a quantity of fluorides in the regeneration fluid to determine the progress of the removal of the fluorocarbon compound from the regeneration fluid;

wherein the current has a current density of at least 5,000 A/m 2 .

2. The method of claim 1 , wherein the current density is at least 15,000 A/m 2 .

3. The method of claim 1 , further comprising measuring the total fluorocarbon input into the electro-oxidation system.

4. The method of claim 1 , wherein the adsorbent includes an ion-exchange resin.

5. The method of claim 1 , wherein the fluorocarbon compound includes per- and polyfluorinated alkyl substances (PFAS).

6. A method of destroying a fluorocarbon compound in a flow of water, the method composing:

directing the flow of water into a tank containing an adsorbent;

removing the fluorocarbon compound from the flow of water by facilitating the adsorption of the fluorocarbon compound with the adsorbent;

periodically regenerating the adsorbent to allow for re-use of the adsorbent, the process of regeneration comprising,

placing the adsorbent in a regeneration fluid, the fluorocarbon compound de-adsorbing from the adsorbent and collecting in the regeneration fluid;

directing the regeneration fluid to an electro-oxidation system;

applying a current to the electro-oxidation system to oxidize the fluorocarbon compound within the regeneration fluid; and

measuring a quantity of fluorides in the regeneration fluid to determine the progress of the removal of the fluorocarbon compound from the regeneration fluid;

wherein the current has a current density of at least 5,000 A/m 2 .

7. The method of claim 6 , wherein the current density is at least 15,000 A/m 2 .

8. The method of claim 6 , further comprising measuring the total fluorocarbon input into the electro-oxidation system.

9. The method of claim 6 , wherein the adsorbent includes an ion-exchange resin.

10. The method of claim 6 , wherein the fluorocarbon compound includes per- and polyfluorinated alkyl substances (PFAS).

Assignments (2)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jul 13, 2023
From: SIEMENS ENERGY, INC.
To: LUMMUS TECHNOLOGY LLC
Reel/Frame 064241/0044 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded May 26, 2022
From: FELCH, CHAD L.; BURCLAFF, PHILIP A.
To: SIEMENS ENERGY, INC.
Reel/Frame 060021/0021 →