Encapsulated catalyst for one-part organopolysiloxane systems and methods related thereto
Described is a particle having a platinum-group catalyst that is fully encapsulated within a thermoplastic polymer. The particle can be used in a curable organopolysiloxane composition that also includes organopolysiloxane components.
1. A particle comprising:
a) a platinum-group catalyst; and
b) a molecular weight controlled thermoplastic polymer having a T g or softening temperature of at least 20° C. selected from the group consisting of:
i. polystyrene or a co-polymer thereof having a M w from about 500 g/mol to about 30,000 g/mol, and a polydispersity index (PDI) of less than 2;
ii. polymethylmethacrylate or a co-polymer thereof having a M w from about 500 g/mol to about 30,000 g/mol, and a PDI of less than 2;
iii. polyacrylonitrile or a co-polymer thereof having a M w from about 500 g/mol to about 30,000 g/mol, and a PDI of less than 2;
wherein the platinum-group catalyst is fully encapsulated within the thermoplastic polymer.
2. The particle of claim 1 , wherein the thermoplastic polymer is polystyrene or a co-polymer thereof having a M w from about 500 g/mol to about 30,000 g/mol, and a PDI of less than 2.
3. The particle of claim 2 , wherein the polystyrene or a co-polymer thereof has a PDI of less than 1.2.
4. The particle of claim 1 , wherein the polystyrene or a co-polymer thereof has a M w from about 1,000 g/mol to about 15,000 g/mol.
5. The particle of claim 1 , wherein the thermoplastic polymer is polymethylmethacrylate or a co-polymer thereof having a M w from about 500 g/mol to about 30,000 g/mol, and a PDI of less than 2.
6. The particle of claim 5 , wherein the polymethylmethacrylate or a co-polymer thereof has a M w from about 1,000 g/mol to about 15,000 g/mol.
7. The particle of claim 5 , wherein the polymethylmethacrylate or a co-polymer thereof has a PDI of less than 1.2.
8. The particle of claim 1 , wherein the thermoplastic polymer is polyacrylonitrile or a co-polymer thereof having a M w from about 500 g/mol to about 30,000 g/mol, and a PDI of less than 2.
9. The particle of claim 8 , wherein the polyacrylonitrile or a co-polymer thereof has a M w from about 1,000 g/mol to about 15,000 g/mol.
10. The particle of claim 8 , wherein the polyacrylonitrile or a co-polymer thereof has a PDI of less than 1.2.
11. The particle of claim 1 , wherein the particle has an average particle diameter from about 0.01 μm to about 500 μm.
12. The particle of claim 1 , wherein the particle comprises from about 0.01 wt % to about 50 wt % of the platinum-group catalyst.
13. A curable organopolysiloxane composition comprising:
(A) an organopolysiloxane represented by the average unit formula:
R a SiO (4-a)/2
wherein, R is a substituted or unsubstituted monovalent hydrocarbon group, and “a” is a number from 1.0 to 2.4, and having at least an average of 1.5 alkenyl groups in a molecule;
(B) an organopolysiloxane having at least an average of 1.5 silicon-bonded hydrogen atoms in a molecule; and
(C) a particle of claim 1 .
14. The curable organopolysiloxane composition of claim 13 , wherein the composition further comprises a reaction inhibitor in an amount of from 0.001 to 5 parts by weight per 100 parts by weight of component (A).
15. The curable organopolysiloxane composition of claim 13 , wherein component (B) is present in an amount such that a quantity of silicon-bonded hydrogen atoms in component (B) is from 0.05 to 20 mol per 1 mol of alkenyl groups in component (A).
16. The curable organopolysiloxane composition of claim 13 , wherein component (C) is present in an amount effective to promote crosslinking of the curable organopolysiloxane composition by a hydrosilylation reaction.
17. The curable organopolysiloxane composition of claim 13 , wherein component (C) is homogeneously dispersed in components (A) and (B).
18. The curable organopolysiloxane composition of claim 13 , wherein the curable organopolysiloxane composition is a homogeneous mixture of components (A), (B) and (C).
19. A method comprising the steps of:
a) providing the curable organopolysiloxane composition of claim 16 ; and
b) heating the curable organopolysiloxane composition to a temperature effective to melt the thermoplastic polymer to release the platinum-group catalyst, thereby promoting a crosslinking reaction between components (A) and (B) to cure the curable organopolysiloxane composition.
20. The method of claim 19 , wherein the temperature effective to melt the thermoplastic polymer is from about 30° C. to about 100° C.