Pressure-sensitive adhesive layer
The present application provides a pressure-sensitive adhesive layer comprising at least first and second regions having different physical properties, wherein the difference in physical properties, such as an elastic modulus or creep strain rate is maintained relatively large for each region, and the difference in physical properties, such as a peel force or recovery rate is maintained relatively small for each region.
1. A pressure-sensitive adhesive layer, comprising:
a first region and
a second region having different storage elastic moduli or creep strain rates from the first region,
wherein the pressure-sensitive adhesive layer comprises an acrylic copolymer containing an alkyl(meth)acrylate unit, a unit of Formula 1 below, a polar functional group-containing unit and a unit of Formula 2 below,
wherein the alkyl(meth)acrylate unit has a linear or branched alkyl group having 1 to 10 carbon atoms,
wherein the polar functional group-containing unit is a unit derived from a hydroxy group-containing monomer,
wherein the unit of Formula 1 is comprised in the acrylic copolymer in an amount ranging from 70 to 260 parts by weight relative to 100 parts by weight of the alkyl (meth)acrylate unit,
wherein a ratio of the weight (A) of the unit of Formula 1 relative to the weight (B) of the polar functional group-containing unit is 1.7 or more and 5 or less, and
wherein the acrylic copolymer has a melting point of −20° C. or less:
wherein, R 1 represents hydrogen or an alkyl group, R 2 represents an alkyl group having 11 to 13 carbon atoms and R 3 represents an aromatic ketone group or a (meth)acryloyl group.
2. The pressure-sensitive adhesive layer according to claim 1 , wherein the acrylic copolymer is a crystalline copolymer.
3. The pressure-sensitive adhesive layer according to claim 1 , wherein the polar functional group-containing unit is comprised in the acrylic copolymer in an amount ranging from 5 to 100 parts by weight relative to 100 parts by weight of the alkyl(meth)acrylate unit.
4. The pressure-sensitive adhesive layer according to claim 1 , wherein the R 2 of Formula 1 is a linear unsubstituted alkyl group.
5. The pressure-sensitive adhesive layer according to claim 1 , wherein the unit of Formula 2 is comprised in the acrylic copolymer in an amount ranging from 0.001 to 5 parts by weight relative to 100 parts by weight of the alkyl(meth)acrylate unit.
6. The pressure-sensitive adhesive of claim 1 , the different storage elastic moduli or creep strain rates are imparted by different cross-linking densities.
7. The pressure-sensitive adhesive of claim 6 , the first region comprises a relatively high cross-linking density and the second region comprises a relatively low cross-linking density.
8. The pressure-sensitive adhesive of claim 1 , the first region comprises a relatively high storage elastic modulus and/or a relatively low creep strain rate and the second region comprises a relatively low storage elastic modulus and/or a relatively high creep strain rate.
9. The pressure-sensitive adhesive layer according to claim 1 , wherein an absolute value of a difference in creep strain rates of the first and second regions according to Equation 1 below is 20% or more, and wherein an absolute value of a difference in recovery rates of the first and second regions according to Equation 2 below is 15% or less:
D C60 =100×( C 60.1 −C 60.2 )/ C 60.2 [Equation 1]
D R60 =100×( R 60.1 −R 60.2 )/ R 60.2 [Equation 2]
wherein, D C60 is the difference in the creep strain rates, C 60.1 is a creep strain rate of the first region at 60° C., and C 60.2 is a creep strain rate of the second region at 60° C.; and D R60 is the difference in the recovery rates, R 60.1 is a recovery rate of the first region at 60° C., and R 60.2 is a recovery rate of the second region at 60° C.
10. The pressure-sensitive adhesive layer according to claim 1 , wherein an absolute value of a difference in storage elastic moduli of the first and second regions according to Equation 5 below is 10% or more, and an absolute value of a difference in peel forces of the first and second regions according to Equation 8 below is 40% or less:
D M60 =100×( M 60.1 −M 60.2 )/ M 60.2 [Equation 5]
D PG =100×( P G.1 −P G.2 )/ P G.2 [Equation 8]
wherein, D M60 is the difference in the storage elastic moduli, M 60.1 is a storage elastic modulus of the first region at 60° C., and M 60.2 is a storage elastic modulus of the second region at 60° C.; and DPG is the difference in peel force, P G.1 is a peel force of the first region to the glass, and P G.2 is a peel force of the second region to the glass.
11. A pressure-sensitive adhesive film, comprising:
a base film; and
the pressure-sensitive adhesive layer of claim 1 formed on one side or both sides of the base film.
12. An optical laminate, comprising:
an optical film; and
the pressure-sensitive adhesive layer of claim 1 formed on one side or both sides of the optical film.
13. The optical laminate of claim 12 , wherein the optical film is a polarizing film, a polarizing plate, or a retardation film.
14. A flexible device, comprising:
a display panel; and
the pressure-sensitive adhesive layer of claim 1 formed on one side or both sides of the display panel.
15. The flexible device of claim 14 , wherein the flexible device is a rollable device or a foldable device.
16. A flexible device, comprising:
a display panel; and
the pressure-sensitive adhesive film of claim 11 formed on one side or both sides of the display panel.
17. The flexible device of claim 16 , wherein the flexible device is a rollable device or a foldable device.
18. A flexible device, comprising:
a display panel; and
the optical laminate of claim 12 formed on one side or both sides of the display panel.
19. The flexible device of claim 18 , wherein the flexible device is a rollable device or a foldable device.
20. The flexible device of claim 18 , wherein the optical film is a polarizing film, a polarizing plate, or a retardation film.