METHOD FOR THE PRODUCTION OF A POLYESTER CARBONATE
The present invention relates to a method for producing an aliphatic polyester carbonate, the polyester carbonate itself, and to moulding compositions and moulded articles containing the polyester carbonate. The claimed method is characterised in particular in that the method comprises three steps and the last step is a melt transesterification method in the presence of two catalysts.
1 .- 15 . (canceled)
16 . A process for preparing a polyester carbonate comprising the steps of:
(i) reacting a mixture comprising at least one linear aliphatic dicarboxylic acid and/or at least one cycloaliphatic dicarboxylic acid and at least one aliphatic and/or aromatic carbonate, in the presence of at least one first catalyst that is basic, to form an aliphatic diester of formula (1)
in which
A in each case independently represents an aliphatic or aromatic radical,
D represents R 3 or one of formulas (1a) or (1b),
where R 3 represents a linear alkylene group having 3 to 16 carbon atoms and this alkylene group may optionally be mono- or polysubstituted or
in which
B in each case independently represents a CH 2 group, O or S,
R 1 in each case independently represents a single bond or an alkylene group having 1 to 10 carbon atoms and
R 2 in each case independently represents an alkyl group having 1 to 10 carbon atoms,
n is a number between 0 and 3,
m is a number between 0 and 6 and “*” indicate the positions at which the
—(C═O)OA groups in formula (1) are present,
(ii) separating the aliphatic diester of formula (1) from the mixture from process step (i),
(iii) reacting the separated aliphatic diester of formula (1), at least one dihydroxy compound, and at least one diaryl carbonate in a melt transesterification process in the presence of a mixture comprising a second catalyst and a third catalyst,
wherein the second catalyst is a tertiary nitrogen base,
wherein the third catalyst is a basic alkali metal salt,
and wherein the proportion of alkali metal cations in process step (iii) is 0.0010% to 0.0030% by weight based on all components used in process step (iii).
17 . The process as claimed in claim 16 , wherein B in formulas (Ia) and (Ib) represents a CH 2 group.
18 . The process as claimed in claim 17 , wherein the cycloaliphatic dicarboxylic acid is selected from the group consisting of cyclohexane-1,4-dicarboxylic acid, cyclohexane-1,3-dicarboxylic acid, cyclohexane-1,2-dicarboxylic acid, and hydrogenated dimer fatty acid and mixtures of these aliphatic dicarboxylic acids.
19 . The process as claimed in claim 16 , wherein, in process step (i), an aromatic carbonate of formula (III) is used
where R, R′, and R″ may each independently be identical or different and represent hydrogen, optionally branched C1-C34 alkyl, C7-C34 alkylaryl or C6-C34 aryl; in addition R may also denote —COO—R″′, where R″′ represents optionally branched C1-C34 alkyl, C7-C34 alkylaryl or C6-C34 aryl.
20 . The process as claimed in claim 16 , wherein the first catalyst used in process step (i) is selected from the group consisting of cesium carbonate, sodium phenoxide, and 4-dimethylamine pyridine and mixtures of these substances.
21 . The process as claimed in claim 16 , wherein the first catalyst used in process step (i) is used in an amount of from 0.005% to 0.2% by weight based on all of the components used in process step (i).
22 . The process as claimed in claim 16 , wherein the second catalyst used in process step (iii) is used in an amount of from 0.005% to 0.02% by weight based on all components used in process step (iii).
23 . The process as claimed in claim 16 , wherein the second catalyst used in process step (iii) is selected from the group consisting of bases derived from guanidine, 4-dimethylaminopyridine, 1,8-diazabicyclo[5.4.0]undec-7-ene, and 1,5-diazabicyclo[4.3.0]non-5-ene and mixtures of these substances.
24 . The process as claimed in a claim 16 , wherein the alkali metal cations in process step (iii) are selected from sodium cations, lithium ions, cesium cations, and mixtures thereof.
25 . The process as claimed in claim 24 , wherein the third catalyst used in process step (iii) is selected from the group consisting of sodium hydroxide, lithium hydroxide, sodium phenoxide, lithium phenoxide, sodium benzoate, lithium benzoate, and cesium carbonate and mixtures of these substances.
26 . The process as claimed in claim 16 , wherein the dihydroxy compound in process step (iii) is selected from the group consisting of cyclohexane-1,2-diol, cyclohexane-1,3-diol, cyclohexane-1,4-diol, cyclohexane-1,2-dimethanol, cyclohexane-1,3-dimethanol, cyclohexane-1,4-dimethanol, tricyclodecanedimethanol, 3,9-bis(1,1-dimethyl-2-hydroxyethyl)-2,4,8,10-tetraoxaspiro[5.5]undecane, 2,2-bis(4-hydroxycyclohexyl)propane, tetrahydrofuran-2,5-dimethanol, bisphenol A, 1,1-bis(4-hydroxyphenyl)-3,3,5-trimethylcyclohexane, 4,4′-dihydroxybiphenyl (DOD), 4,4′-dihydroxydiphenyl ether (DOD ether), bisphenol B, bisphenol M, the bisphenols (V) to (VII)
where in formulas (V) to (VII) R′ in each case represents C 1 -C 4 alkyl, aralkyl or aryl.
27 . The process as claimed in claim 26 , wherein the dihydroxy compound in process step (iii) is selected from the group consisting of isomannide, isoidide, and isosorbide and mixtures thereof.
28 . A polyester carbonate obtainable by the process as claimed in claim 16 .
29 . A molding compound comprising a polyester carbonate as claimed in claim 28 .
30 . A molding comprising a polyester carbonate as claimed in claim 28 .