HIGH THERMAL CONDUCTIVITY PHASE CHANGE COMPOSITE
In an aspect, a layered phase change composite comprises a phase change layer comprising a phase change material, a plurality of boron nitride particles, and a binder; and a first capping layer and a second capping layer located on opposing sides of the phase change layer. In another aspect, a method of making the layered phase change composite comprises forming the first capping layer from a first composition; forming the phase change layer from a phase change composition, wherein the forming the phase change layer comprises vibrating the phase change composition on a 3-directional vibration stage; and forming the second capping layer from a second composition.
1 . A layered phase change composite comprising:
a phase change layer comprising a phase change material, a plurality of boron nitride particles, and a binder; and
a first capping layer and a second capping layer located on opposing sides of the phase change layer.
2 . The layered phase change composite of claim 1 , wherein the phase change material comprises at least one of a C 10-36 alkane, a C 10-35 fatty acid, a C 10-35 fatty acid ester, or a vegetable oil.
3 . The layered phase change composite of claim 1 , wherein phase change layer comprises 50 to 99 volume percent of the phase change material based on the total volume of the phase change layer.
4 . The layered phase change composite of claim 1 , wherein phase change material has a transition temperature of −5 to 150 degrees Celsius.
5 . The layered phase change composite of claim 1 , wherein at least one of the plurality of boron nitride particles comprises a plurality of hexagonal boron nitride platelets; or the binder comprises at least one of polystyrene, epoxy, polybutadiene, or polyisoprene.
6 . The layered phase change composite of claim 1 , wherein phase change layer comprises 5 to 95 volume percent of the plurality of boron nitride particles based on the total volume of the phase change layer.
7 . The layered phase change composite of claim 1 , wherein phase change layer comprises 0.5 to 15 volume percent of the binder based on the total volume of the phase change layer; and wherein the binder comprises an epoxy.
8 . The layered phase change composite of claim 1 , wherein a thickness of the phase change layer is 0.05 to 10 mm; and wherein each of the capping layers independently has a layer thickness of 0.001 to 1 mm.
9 . The layered phase change composite of claim 1 , wherein the first capping layer and the second capping layer comprise an epoxy.
10 . The layered phase change composite of claim 1 , wherein the first capping layer and the second capping layer each independently comprise 10 to 100 volume percent of a binder based on the total volume of the respective capping layer; and 0 to 90 volume percent of a plurality of boron nitride particles based on the total volume of the respective capping layer.
11 . The layered phase change composite of claim 1 , wherein the layered phase change composite has at least one of a heat of fusion of at least 50 J/g measured using thermal gravitational analysis; or wherein the layered phase change composite has a thermal conductivity of greater than 0.5 Watts per meter Kelvin measured in accordance with ASTM D5470-17.
12 . An article comprising the layered phase change composite of claim 1 .
13 . The article of claim 12 , wherein the article is a thermal management material, a thermal pad, an electrode for energy storage, a supercapacitor, a fuel cell, a battery, a capacitive desalination device, an acoustic insulator, a thermal insulation composite, a chemical sensor, a mechanical sensor, a biomedical device, an actuator, an adsorbent, a catalyst support, a field emission device, a mechanical dampening device, a filter, a three-dimensional flexible electronic component, a circuit material, an integrated circuit package, a printed circuit board, an electronic device, a cosmetic product, a wearable electronic, a high efficiency flexible electronic device, a power electronics device, a high frequency device, or an energy storage device.
14 . A method of making the layered phase change composite of claim 1 , comprising:
forming the first capping layer from a first composition, wherein the forming the first capping layer optionally comprises vibrating the first composition on a 3-directional vibration stage;
forming the phase change layer from a phase change composition, wherein the forming the phase change layer comprises vibrating the phase change composition on a 3-directional vibration stage; and
forming the second capping layer from a second composition, wherein the forming the second capping layer optionally comprises vibrating the second composition on a 3-directional vibration stage; and
wherein the respective layers are each formed independently and then stacked on each other to form the composite and/or wherein at least one of the respective layers is formed directly on one of the other layers.
15 . The method of claim 14 , wherein the phase change composition is free of a solvent.
16 . The method of claim 14 ,
wherein the forming the first capping layer comprises casting a first composition comprising a first curable composition, a first solvent, and a first plurality of boron nitride particles on a 3-directional vibration stage, evaporating the first solvent while vibrating the stage in three directions, and curing the first curable composition to form the first capping layer;
wherein the forming the phase change layer comprises casting a phase change composition comprising the phase change material, a curable composition, and the plurality of boron nitride particles on the 3-directional vibration stage, vibrating the stage in three directions, and curing the curable composition to form the phase change layer;
wherein the forming the second capping layer comprises casting a second composition comprising a second curable composition, a second solvent, and a second plurality of boron nitride particles on a 3-directional vibration stage, evaporating the second solvent while vibrating the stage in three directions, and curing the second curable composition to form the second capping layer.
17 . The method of claim 16 , wherein the casting the phase change composition comprises casting the phase change composition onto the first capping layer.
18 . The method of claim 16 , wherein the casting the second composition comprises casting the second composition onto the phase change layer.
19 . The method of claim 16 , wherein each of the casting steps independently comprise vibrating the respective composition until a gel point in reached.
20 . The method of claim 14 , further comprising stacking the first capping layer, the phase change layer, and the second capping layer to form a layered stack and laminating the layered stack.