Producing semi-crystalline pulverulent polycarbonate and use thereof in additive manufacturing
Ways of preparing a partially crystalline polycarbonate powder are provided that include dissolving an amorphous polycarbonate in a polar aprotic solvent to form a first solution of solubilized polycarbonate at a first temperature. The first solution is then cooled to a second temperature, the second temperature being lower than the first temperature, where a portion of the solubilized polycarbonate precipitates from the first solution to form a second solution including the partially crystalline polycarbonate powder. Certain partially crystalline polycarbonate powders resulting from such methods are particularly useful in additive manufacturing processes, including powder bed fusion processes.
1. A method of preparing a partially crystalline polycarbonate powder, the method comprising:
dissolving an amorphous polycarbonate in a polar aprotic solvent to form a first solution of solubilized polycarbonate at a first temperature; and
cooling the first solution to a second temperature, the second temperature being lower than the first temperature, wherein a portion of the solubilized polycarbonate precipitates from the first solution to form a second solution comprised of precipitated partially crystalline polycarbonate powder and a dissolved remaining portion of polycarbonate in the solvent, wherein the dissolving step includes heating the amorphous polycarbonate in the polar aprotic solvent to form the first solution of solubilized polycarbonate at the first temperature, the first temperature being greater than room temperature.
2. The method of claim 1 , further comprising separating the precipitated partially crystalline polycarbonate powder from the second solution leaving a remaining second solution comprised of the aprotic solvent and dissolved remaining portion of polycarbonate in the solvent.
3. The method of claim 2 , further comprising drying the separated partially crystalline polycarbonate powder.
4. The method of claim 2 , further comprising repeating the dissolving step using the remaining second solution as the polar aprotic solvent and repeating the cooling step to form the second solution including another partially crystalline polycarbonate powder.
5. The method of claim 1 , wherein the polar aprotic solvent includes dimethyl sulfoxide.
6. The method of claim 1 , wherein the polar aprotic solvent consists essentially of dimethyl sulfoxide.
7. The method of claim 1 , wherein the cooling step includes cooling the first solution to the second temperature, the second temperature being room temperature.
8. The method of claim 1 , wherein the first solution is supersaturated with amorphous polycarbonate at the first temperature.
9. The method of claim 1 , wherein the partially crystalline polycarbonate powder has a D90 particle size of less than about 150 micrometers.
10. The method of claim 1 , wherein the partially crystalline polycarbonate powder has an average particle diameter from about 1 micrometer to about 100 micrometers.
11. The method of claim 1 , wherein the partially crystalline polycarbonate powder has an average particle diameter from about 30 micrometers to about 40 micrometers.
12. The method of claim 1 , wherein the partially crystalline polycarbonate powder is in the form of spheroidal particles.
13. The method of claim 1 , wherein the partially crystalline polycarbonate powder has at least about 20% crystallinity.
14. The method of claim 1 , wherein the partially crystalline polycarbonate powder has a crystallinity between about 25% and about 35%.
15. A method of preparing an object comprising:
preparing a partially crystalline polycarbonate powder according to the method of claim 1 ; and
using the partially crystalline polycarbonate powder in a powder bed fusion process to form the object.
16. A method of preparing a partially crystalline polycarbonate powder, the method comprising:
dissolving an amorphous polycarbonate in a polar aprotic solvent to form a first solution of solubilized polycarbonate at a first temperature; and
cooling the first solution to a second temperature, the second temperature being lower than the first temperature, wherein a portion of the solubilized polycarbonate precipitates from the first solution to form a second solution comprised of precipitated partially crystalline polycarbonate powder and a dissolved remaining portion of polycarbonate in the solvent, wherein the partially crystalline polycarbonate powder has a D90 particle size of less than about 150 micrometers.
17. A method of preparing a partially crystalline polycarbonate powder, the method comprising:
dissolving an amorphous polycarbonate in a polar aprotic solvent to form a first solution of solubilized polycarbonate at a first temperature; and
cooling the first solution to a second temperature, the second temperature being lower than the first temperature, wherein a portion of the solubilized polycarbonate precipitates from the first solution to form a second solution comprised of precipitated partially crystalline polycarbonate powder and a dissolved remaining portion of polycarbonate in the solvent, wherein the partially crystalline polycarbonate powder has at least about 20% crystallinity.
18. A method of preparing an object comprising:
preparing a partially crystalline polycarbonate powder according to the method of claim 16 ; and
using the partially crystalline polycarbonate powder in a powder bed fusion process to form the object.
19. A method of preparing an object comprising:
preparing a partially crystalline polycarbonate powder according to the method of claim 17 ; and
using the partially crystalline polycarbonate powder in a powder bed fusion process to form the object.