Method for fabricating nano-particle having perovskite crystalline structure and resin composition including the nano-particle
A method for fabricating a nano-particle includes preparing a nano-particle dispersion including a nano-particle having a perovskite structure with a first ligand on a surface thereof and a non-polar solvent; and mixing a silane compound, a halogen compound and the nano-particle dispersion to substitute a silane ligand for the first ligand.
1. A method for fabricating a nano-particle, the method comprising:
preparing a nano-particle dispersion including a nano-particle having a perovskite structure with a first ligand on a surface thereof and a non-polar solvent; and
mixing a silane compound, a halogen compound and the nano-particle dispersion to substitute a silane ligand for the first ligand,
wherein the halogen compound includes at least one selected from the group consisting of a metal halide and an alkylammonium halide.
2. The method of claim 1 , wherein the first ligand includes a C3 to C18 alkyl chain.
3. The method of claim 1 , wherein the non-polar solvent includes at least one selected from the group consisting of dichloroethylene, trichloroethylene, chloroform, chlorobenzene, dichlorobenzene, styrene, xylene, toluene and cyclohexane.
4. The method of claim 1 , wherein the silane ligand is an X-type silane ligand having a functional group combined with the nano-particle and donating an electron to a cation of a surface of the nano-particle thereby forming a covalent binding.
5. The method of claim 4 , wherein the silane compound includes at least one selected from the group consisting of 3-aminopropyl triethoxysilane, (3-mercaptopropyl) trimethoxysilane, trimethoxysilylpropanethiol, and 3-(trihydroxysilyl) propylmethylphosphonate.
6. The method of claim 1 , wherein a volume ratio of the silane compound to the dispersion is 0.01 to 0.001.
7. A siloxane resin composition comprising:
a nano-particle fabricated by the method of claim 1 ; and
a siloxane resin including a hydrolytic or non-hydrolytic condensation reaction product derived from at least one silane compound selected from the group consisting of an organoalkoxysilane and organosilanediol, wherein the siloxane resin is free of methanol.
8. The siloxane resin composition of claim 7 , wherein the hydrolytic or non-hydrolytic condensation reaction product derived from the silane compound includes an oligomer obtained from condensation reaction of an organoalkoxysilane and organosilanediol.
9. The siloxane resin composition of claim 7 , wherein a content of the nano-particle is 0.1 to 10 parts by weight to 100 parts by weight of the siloxane resin.
10. The siloxane resin composition of claim 7 , further comprising a curing catalyst.