Thermoplastic elastomer composition and automobile weather strip
Provided is a thermoplastic elastomer composition obtained by melt-kneading an ethylene/α-olefin/non-conjugated polyene copolymer rubber (A) that is a copolymer of ethylene, an α-olefin having 3 to 20 carbon atoms, and a non-conjugated polyene, a polyolefin resin (B), and a mineral oil-based softening agent (C) in the presence of an organic peroxide (D) and a crosslinking aid (E), the thermoplastic elastomer composition having a shear viscosity of from 5 Pa·s to 20 Pa·s at 140° C. and 10,000 s −1 .
1. A thermoplastic elastomer composition obtained by melt-kneading an ethylene/α-olefin/non-conjugated polyene copolymer rubber (A) that is a copolymer of ethylene, an α-olefin having 3 to 20 carbon atoms, and a non-conjugated polyene, a polyolefin resin (B), and a mineral oil-based softening agent (C) in the presence of an organic peroxide (D) and a crosslinking aid (E),
wherein, when a total exothermic energy amount of a peak observed when the polyolefin resin (B) is subjected to differential scanning calorimetry by decreasing a temperature from 200° C. to −80° C. at −10° C./min in conformity with ISO 11357-3:2018 is defined as 100%, a temperature at which the observed peak reaches 95% by being integrated from a high-temperature side is from 75° C. to 95° C.,
wherein a mass ratio (C)/(A) between the mineral oil-based softening agent (C) and the ethylene/α-olefin/non-conjugated polyene copolymer rubber (A) falls within a range of from 0.8 to 1.9,
the thermoplastic elastomer composition having a shear viscosity of from 5 Pas to 20 Pa·s at 140° C. and 10,000 s −1 .
2. The thermoplastic elastomer composition according to claim 1 , wherein, when the thermoplastic elastomer composition is subjected to differential scanning calorimetry by decreasing a temperature from 200° C. to −80° C. at −10° C./min in conformity with ISO 11357-3:2018, an exothermic peak is observed at from 70° C. to 85° C.
3. The thermoplastic elastomer composition according to claim 1 , wherein the thermoplastic elastomer composition has an endothermic energy amount of from 1 J·g −1 to 25 J·g −1 for a peak observed when differential scanning calorimetry is performed by increasing a temperature from −80° C. to 200° C. at 10° C./min in conformity with ISO 11357-3:2018.
4. The thermoplastic elastomer composition according to claim 1 , further comprising an amorphous polyolefin resin (F) having an endothermic energy amount of 10.5 J·g −1 or less for a peak observed when differential scanning calorimetry is performed by increasing a temperature from −80° C. to 200° C. at 10° C./min in conformity with ISO 11357-3:2018.
5. An automobile weather strip, in at least part of which the thermoplastic elastomer composition of claim 1 is used.