Carbon dioxide sequestered cement for well cementing
A method of making a cement composite can include contacting an aqueous solution comprising calcium ions with a carbon dioxide source producing a carbonated aqueous solution. Fine particles can be submerged in the carbonated aqueous solution to produce microaggregate particles comprising the fine particles coated with calcium carbonate. The microaggregate particles can be combined with cement particles to produce the cement composite. The cement composite can be used in cementing applications for hydrocarbon wells including for casing liners and well plugs.
1. A method of cementing a hydrocarbon well, the method comprising:
pumping a cement composite into the hydrocarbon well, wherein the cement composite comprises cement particles and microaggregate particles, wherein the microaggregate particles comprise fine particles coated with calcium carbonate,
wherein the fine particles comprise a silicon dioxide content of greater than 75%,
wherein the fine particles have a D50 value between 3 microns and 35 microns before the fine particles are coated with the calcium carbonate, and
wherein the fine particles have a D50 value between 25 microns and 60 microns after being coated with the calcium carbonate.
2. The method of claim 1 , wherein the cement composite forms a casing liner in the hydrocarbon well.
3. The method of claim 1 , wherein the cement composite forms a plug in the hydrocarbon well.
4. The method of claim 1 , wherein the cement composite comprises 50% or more by weight of the cement particles and 3% to 50% by weight of the fine particles with the calcium carbonate.
5. The method of claim 4 , wherein after pumping the cement composite into the hydrocarbon well, the cement composite is exposed to temperatures exceeding 230 degrees F.