Polyamide compositions
The present invention relates to flame retardant polyamide-based compositions or moulding materials and to articles of manufacture of the electricals or electronics industries producible therefrom, in particular charging components, containing at least one polyamide, aluminium oxide, magnesium hydroxide and at least one organic epoxide.
1 . A composition comprising:
a) at least one polyamide selected from the group consisting of polyamide 6 (PA 6), polyamide 66 (PA 66), and copolyamide of PA6 or PA66,
b) aluminum oxide in an amount of 20 to 300 parts by mass per 100 parts by mass of the at least one polyamide,
c) magnesium hydroxide in an amount of 120 to 350 parts by mass per 100 parts by mass of the at least one polyamide, and
d) 2 to 10 parts by mass per 100 parts by mass of the at least one polyamide of at least one organic, halogen-free, epoxidized compound comprising two epoxy groups per molecule, wherein the at least one epoxidized compound is either:
(i) an epoxidized compound which is an oligomeric reaction product of bisphenol A with epichlorohydrin having an epoxy index according to ISO 3001 in the range from 450 to 750 grams per equivalent, or
(ii) an epoxidized compound which includes in any combination and frequency an epoxy-containing unit:
and the unit:
and/or the unit:
or
(iii) an epoxidized compound of formula (II):
wherein
R 9 , R 1 ° independently of one another represent H or C 1 -C 6 -alkyl,
R 11 represents C 1 -C 6 -alkyl,
X and Y each represent integers in the range from 0 to 20,
with the proviso that either X or Y is ≥1 at least once, and
Z represents an integer in the range from 2 to 20,
R* represents H or C 1 -C 8 -alkyl, and
wherein the units designated X, Y, Z may occur repeatedly and in any desired sequence, or
(iv) an epoxidized compound is an oligomeric reaction product of bisphenol A with epichlorohydrin of formula (III):
wherein a represents average number of repeating units and is an integer from 0 to 12, and wherein
the composition exhibits a UL94 V-0 flammability classification at wall thicknesses≤ 0.75 mm.
2 . The composition according to claim 1 , wherein the aluminum oxide is present in an amount from 70 to 120 parts by mass per 100 parts by mass of the at least one polyamide.
3 . The composition according to claim 1 , wherein the magnesium hydroxide is present in an amount from 120 to 210 parts by mass per 100 parts by mass of the at least one polyamide.
4 . The composition according to claim 1 , wherein at least one of the two epoxy groups is terminal.
5 . The composition according to claim 1 , wherein the at least one polyamide is selected from semicrystalline polyamides which have a melting enthalpy in the range from 4 to 25 J/g measured by the DSC method according to ISO 11357 in the 2 nd heating and integration of the melting peak.
6 . An article of manufacture for the electrical or electronics industries which comprises the composition according to claim 1 .
7 . The article according to claim 6 , wherein the article is a charging component.
8 . The article according to claim 7 , wherein the article is a charging component for electromobility.
9 . The article according to claim 8 , wherein the charging component is a battery charging component for charging electrical batteries.
10 . The article according to claim 7 , wherein the charging component is a charging cable plug, a charging inlet or a component of a charging inlet.
11 . The article according to claim 10 , wherein the charging component is a pin holder of a charging inlet.
12 . A process for producing an article of manufacture for of the electrical or electronics industries, comprising the steps of processing a composition into a molding material by mixing components of the composition together, extruding the composition in a water bath, cooling the extruded composition until palletizable, pelletizing the cooled and palletizable composition, and injecting molding pellets of the composition to form the article of manufacture, wherein the composition comprises:
a) at least one polyamide selected from the group consisting of polyamide 6 (PA 6), polyamide 66 (PA 66), and copolyamide of PA6 or PA66,
b) aluminum oxide in an amount of 20 to 300 parts by mass per 100 parts by mass of the at least one polyamide,
c) magnesium hydroxide in an amount of 120 to 350 parts by mass per 100 parts by mass of the at least one polyamide, and
d) 2 to 10 parts by mass per 100 parts by mass of the at least one polyamide of at least one organic, halogen-free, epoxidized compound comprising two epoxy groups per molecule, wherein the at least one epoxidized compound is either:
(i) an epoxidized compound which is an oligomeric reaction product of bisphenol A with epichlorohydrin having an epoxy index according to ISO 3001 in the range from 450 to 750 grams per equivalent, or
(ii) an epoxidized compound which includes in any combination and frequency an epoxy-containing unit:
and the unit:
and/or the unit:
or
(iii) an epoxidized compound of formula (II):
wherein
R 9 , R 10 independently of one another represent H or C 1 -C 6 -alkyl,
R 11 represents C 1 -C 6 -alkyl,
X and Y each represent integers in the range from 0 to 20,
with the proviso that either X or Y is ≥1 at least once, and
Z represents an integer in the range from 2 to 20,
R* represents H or C 1 -C 8 -alkyl, and
wherein the units designated X, Y, Z may occur repeatedly and in any desired sequence, or
(iv) an epoxidized compound is an oligomeric reaction product of bisphenol A with epichlorohydrin of formula (III):
wherein a represents average number of repeating units and is an integer from 0 to 12, and wherein
the composition exhibits a UL94 V-0 flammability classification at wall thicknesses≤ 0.75 mm.
13 . The process according to claim 12 , wherein the article of manufacture is a charging component.
14 . The process according to claim 13 , wherein the article of manufacture is a battery charging component.
15 . The process according to claim 13 , wherein the article of manufacture is a charging cable plug, a charging inlet or a component of a charging inlet.
16 . A moulding material which comprises the composition according to claim 1 .
17 . An article of manufacture for the electrical or electronics industries which comprises the moulding material according to claim 16 .
18 . A composition comprising:
(a) at least one polyamide,
(b) 70 to 300 parts by mass per 100 parts by mass of the at least one polyamide of aluminum oxide,
(c) 120 to 350 parts by mass per 100 parts by mass of the at least one polyamide of magnesium hydroxide, and
(d) 2 to 10 parts by mass per 100 parts of the at least one polyamide of at least one organic, halogen-free, epoxidized compound, wherein
the at least one organic, halogen-free, epoxidized compound is an oligomeric reaction product of bisphenol A with epichlorohydrin having an epoxy index according to ISO 3001 in the range from 450 to 750 grams per equivalent, and wherein
the composition exhibits a UL94 V-0 flammability classification at wall thicknesses ≤0.75 mm.
19 . A method of increasing UL94 flammability classification of a component having a wall thickness≤0.75 mm which is formed of a composition comprising:
(a) at least one polyamide,
(b) aluminum oxide, and
(c) 120 to 350 parts by mass per 100 parts by mass of the at least one polyamide of magnesium hydroxide, wherein
the method comprises incorporating into the composition an effective UL94 flammability classification increasing amount of at least one organic, halogen-free, epoxidized compound, wherein the at least one organic, halogen-free, epoxidized compound is an oligomeric reaction product of bisphenol A with epichlorohydrin having an epoxy index according to ISO 3001 in the range from 450 to 750 grams per equivalent.