Valve leak repair composition

1. An injectable packing stick extrusion for use in the repair of a leaking valve subjected to fluid flow through or into a conduit controlled by the valve, the packing stick extrusion comprising:

(a) a calcium sultanate complex grease comprising at least one polyalphaolefin;

(b) at least one anti-wear/anti-galling agent;

(c) at least one binding/thickening agent; and

(d) a plasticizing agent miscible with the calcium sultanate complex grease

wherein the packing stick extrusion, when injected, repairs the valve without interrupting the flow of the fluids through or into the conduit.

2. The injectable packing stick extrusion of claim 1 , further comprising at least one ester.

3. The injectable packing stick extrusion of claim 2 , wherein the at least one ester is a component of the calcium sulfonate complex grease.

4. The injectable packing stick extrusion of claim 3 , wherein the plasticizing agent is miscible with the ester of the calcium sultanate complex grease.

5. The injectable packing stick extrusion of claim 1 , wherein the calcium sulfonate complex grease comprises micellular calcium salt in combination with calcium sulfonate.

6. The injectable packing stick extrusion of claim 1 , wherein at least one of the following is true:

(a) the at least one polyalphaolefin is selected from the group consisting of polyethylenes, polypropylenes, polybutenes, polypentenes, polyhexenes and polyheptenes;

(b) the plasticizing agent is an isocyanate reaction product of castor oil or a diglycol ester of a dibasic acid;

(c) the anti-wear/anti-galling agent is selected from the group consisting of graphite, engineered graphite, molybdenum disulfide, tungsten disulfide, mineral carbonates, mineral silicates, mineral fluorides, mineral oxides and combinations thereof; or

(d) the binding/thickening agent is selected from the group consisting of silica, organophilic clay, powdered metallic soaps and combinations thereof.

7. The injectable packing stick extrusion of claim 3 , wherein the combination of the at least one polyalphaolefin and the least one ester in the calcium sultanate complex grease is present in an amount between from about 60 to about 95% by weight.

8. The injectable packing stick extrusion of claim 7 , wherein the at least one ester is an ester of a diol or polyol having from about 3 to about 20 hydroxyl groups and an aliphatic acid having from about 1 to about 24 carbon atoms.

9. The injectable packing stick extrusion of claim 1 , comprising:

(a) from about 20 to about 60 w/w % of the calcium sultanate complex grease;

(b) from about 20 to about 50 w/w % of the anti-wear/anti-galling agent;

(c) from about 5 to about 20 w/w % of the binding/thickening agent; and

(d) from about 2 to about 20 w/w % of the plasticizing agent.

10. The injectable packing stick extrusion of claim 1 , wherein at least one of the following is true;

(a) the at least one polyalphaolefin has a viscosity of 8 to 60 centistokes at 100° C.;

(b) the calcium sulfonate complex grease has a dropping point greater than 500° F., ASTM D-2265;

(c) the injectable packing packing extrusion has a penetration index from about 75 to about 95 at 77° F., ASTM D-217;

(d) the calcium sultanate complex grease has a melting point from about 320° F. to about 600° F.;

(e) the calcium sulfonate complex grease has a total base number from about 300 to about 500 mg KOH/gm.

11. An extruded stick for repairing valve gates or stems comprising:

(a) a calcium sultanate complex grease comprising at least one polyalphaolefin;

(b) at least one anti-wear/anti-galling agent;

(c) at least one binding/thickening agent; and

(d) a plasticizing agent miscible with the calcium sulfonate complex grease wherein the extruded stick is capable of adhering to the valve gate or stem to be repaired and further is resistant to degradation and decay caused by the action of water and hydrocarbon within a conduit controlled by the valve gate or stem and further wherein the extruded stick exhibits a cone penetration value at 77° F. from about 75 to about 100, ASTM 0217.

12. The extruded stick of claim 11 , further comprising at least one ester.

13. The extruded stick of claim 12 , wherein the at least one ester is a component of the calcium sulfonate complex grease.

14. The extruded stick of claim 13 , wherein the plasticizing agent is miscible with the at least one ester.

15. The extruded stick of claim 12 , wherein the at least one ester is an ester of a diol or polyol having from about 3 to about 20 hydroxyl groups and an aliphatic acid having from about 1 to about 24 carbon atoms.

16. The extruded stick of claim 11 , wherein at least one of the following is true:

(a) the at least one polyalphaolefin is selected from the group consisting of polyethylenes, polypropylenes, polybutenes, polypentenes, polyhexenes and polyheptenes;

(b) the plasticizing agent is an isocyanate reaction product of castor oil or a diglycol ester of a dibasic acid;

(c) the anti-wear/anti-galling agent is selected from the group consisting of graphite, engineered graphite, molybdenum disulfide, tungsten disulfide, mineral carbonates, mineral silicates, mineral fluorides, mineral oxides and combinations thereof; or

(d) the binding/thickening agent is selected from the group consisting of silica, organophilic clay, powdered metallic soaps and combinations thereof.

17. A water-insoluble valve packing extruded stick for use in the repair of a leaking valve subjected to fluid flow through or into a conduit controlled by the valve, the extruded stick comprising:

(a) a calcium over-based sulfonate in a base oil, the base oil comprising a lubricating oil and a polyalphaolefin oil;

(b) at least one anti-wear/anti-galling agent;

(c) at least one binding/thickening agent;

(d) an ester; and

(e) a plasticizing agent miscible with the calcium sulfonate complex grease wherein the non-curable water-insoluble valve packing stick has a putty consistency and, when injected, repairs the valve without interrupting the flow of the fluids through or into the conduit and further wherein the non-curable water-insoluble valve packing stick exhibits a cone penetration value at 77° F. from about 75 to about 100, ASTM D217.

18. The water-insoluble valve packing extruded stick of claim 17 , wherein the calcium over-based sulfonate comprises from about 55 to about 95 percent by weight of the base oil and between from about 5 to about 40 percent by weight of calcium sulfonate.

19. The water-insoluble valve packing putty extruded stick of claim 18 , wherein the ester is a component of the base oil.

20. The water-insoluble valve packing extruded stick of claim 18 , wherein the ester is present in an amount from about 5 to about 65% by weight based on the base oil and ester combined.