Gypsum cement compositions with aggregate stabilizers and methods for forming floor underlayment
This disclosure provides gypsum cement compositions which comprise an aggregate stabilizing mixture containing a combination of a polysaccharide gum and a polyacrylamide-gelatin blend, and methods for making and using these compositions, including pourable/pumpable floor underlayment slurries and methods for forming high strength underlayment on different substrates.
1. A composition for producing a gypsum cement slurry, the composition comprising:
a) calcium sulfate hemi-hydrate;
b) cement;
c) a dispersant;
d) a defoamer; and
e) an aggregate stabilizing mixture, wherein the aggregate stabilizing mixture comprises:
a polysaccharide gum in an amount from 0.001% to 0.5% by weight of the composition, and
a polyacrylamide-gelatin blend in an amount from 0.00125% to 0.01% by weight of the composition; and
wherein the composition is a dry mixture.
2. The composition of claim 1 , wherein the composition further comprises polyethylene glycol in an amount from 0.1% to 10% by weight of the composition.
3. The composition of claim 1 , wherein the polysaccharide gum includes one or more of the following: xanthan gum, welan gum and/or diutan gum.
4. The composition of claim 1 , wherein the aggregate stabilizing mixture comprises alpha-calcined gypsum.
5. The composition of claim 1 , wherein calcium sulfate hemi-hydrate is supplied as calcined gypsum, synthetic gypsum or any combination thereof.
6. The composition of claim 1 , wherein cement is class C cement in an amount from 0.5% to 50% by weight.
7. The composition of claim 1 , wherein the composition comprises at least one set retarding agent and/or at least one set accelerating agent.
8. The composition of claim 1 , wherein the composition further comprises at least one aggregate.
9. The composition of claim 8 , wherein the aggregate includes one or more of the following: sand, perlite, glass beads, rock, gravel, silica fume, clay, pumice, foam, vermiculite, fly ash, slag, silica fume, or any combination thereof in an amount from 100 parts by weight to 300 parts by weight of aggregate per 100 parts by weight of the composition.
10. The composition of claim 1 , wherein the composition further comprises sand in an amount from 1 to 2 cubic feet of sand per 80 pounds of the composition.
11. The composition of claim 1 , wherein the composition is further characterized by one or more of the following features:
the dispersant in an amount from 0.2% to 10% by weight; and/or
the defoamer in an amount from 0.1% to 1% by weight.
12. The composition of claim 1 , wherein calcium sulfate hemi-hydrate is spray-coated with a set retarding agent.
13. A gypsum cement slurry, the gypsum cement slurry comprising:
i) the composition of claim 1 ;
ii) at least one aggregate; and
iii) water, and
wherein water is used in an amount from 150 cubic centimeters (cc) to 400 cubic centimeters (cc) per 1,000 grams of components i) and ii); and
wherein the weight by weight (w/w) ratio of component ii) to component i) is in the range from 1:1 to 3:1.
14. The gypsum cement slurry of claim 13 , wherein the aggregate is one or more of the following: sand, perlite, glass beads, rock, gravel, silica fume, clay, pumice, foam, vermiculite, fly ash, slag, silica fume, or any combination thereof.
15. A method of preparing a calcium sulfate hemi-hydrate/cement composition, the method comprising:
a) mixing together an aggregate stabilizing mixture containing alpha-calcined calcium sulfate hemihydrate, a polysaccharide gum and polyacrylamide-gelatin blend; and
b) mixing the mixture of step a) into a composition comprising at least the following components: calcined gypsum and/or synthetic gypsum, and cement, and
wherein the aggregate stabilizing mixture is mixed in step b) in an amount resulting in the composition comprising:
a polysaccharide gum in an amount from 0.001% to 0.5% by weight of the composition, and
a polyacrylamide-gelatin blend in an amount from 0.00125% to 0.01% by weight of the composition.
16. The method of claim 15 , wherein the aggregate stabilizing mixture contains the polysaccharide gum in an amount from 1% to 30% by weight and polyacrylamide-gelatin blend in an amount from 0.05% to 5% by weight.
17. The method of claim 15 , wherein the polysaccharide gum includes one or more of the following: xanthan gum, welan gum and/or diutan gum.
18. A method for producing floor or floor underlayment, the method comprising:
i. mixing a gypsum cement slurry from the composition of claim 1 , at least one aggregate and water in a mixing vessel, wherein water is used in an amount from 150 cubic centimeters (cc) to 300 cubic centimeters (cc) per 1,000 grams of the composition and aggregate; and wherein the weight by weight (w/w) ratio of the aggregate to the composition is in the range from 1:1 to 3:1; and
ii. applying the gypsum cement slurry to a substrate.
19. The method of claim 18 , wherein the gypsum cement slurry is applied by pumping the gypsum cement slurry through a hose.