Organic electroluminescent compound and organic electroluminescent device comprising the same

1 . An organic electroluminescent compound represented by the following formula 2:

M(L 1 ) x (L 2 ) y   (2)

in formula 2,

M represents a metal having an atomic number greater than 40;

x represents 1 or 2;

y represents 1 or 2;

the sum of x and y is the oxidation number of M;

L 1 represents the ligand represented by formula 1;

in formula 1,

ring A represents a substituted or unsubstituted benzene ring, or a substituted or unsubstituted pyridine ring;

R, each independently, represents a substituted or unsubstituted (C1-C30)alkyl, a substituted or unsubstituted (C3-C30)cycloalkyl, a substituted or unsubstituted (C6-C30)aryl, or a substituted or unsubstituted (3- to 30-membered)heteroaryl;

R 1 , each independently, represents hydrogen, deuterium, a substituted or unsubstituted (C1-C30)alkyl, a substituted or unsubstituted (C3-C30)cycloalkyl, a substituted or unsubstituted (C6-C30)aryl, or a substituted or unsubstituted (3- to 30-membered)heteroaryl;

n represents an integer of 1 to 4, in which, if n is an integer of 2 or more, each of R 1 may be the same or different; and wherein

one or more hydrogen atoms in ring A, R, and R 1 may be replaced with one or more deuterium atoms; and

L 2 represents the ligand represented by the following formula 3 or 4:

in formulas 3 and 4,

R 4 to R 8 , each independently, represent hydrogen, deuterium, a substituted or unsubstituted (C1-C30)alkyl, a substituted or unsubstituted (C3-C30)cycloalkyl, a substituted or unsubstituted (C6-C30)aryl, or a substituted or unsubstituted (3- to 30-membered)heteroaryl; or R 4 and R 5 , R 5 and R 6 , adjacent R 7 's, and adjacent R 8 's, each independently, may be linked to each other to form a ring(s); and

d and e, each independently, represent an integer of 1 to 4, in which, if d and e, each independently, are an integer of 2 or more, each of R 7 and each of R 8 may be the same or different.

2 . The organic electroluminescent compound according to claim 1 , wherein the metal having an atomic number greater than 40 is Ir or Pt.

3 . The organic electroluminescent compound according to claim 1 , wherein the ligand L 1 is represented by the following formula 1-1 or 1-2:

in formulas 1-1 and 1-2,

R′ 1 to R′ 4 , each independently, represent hydrogen, deuterium, a substituted or unsubstituted (C1-C30)alkyl, or a substituted or unsubstituted (C3-C30)cycloalkyl; and

R, R 1 , and n are as defined in claim 1 .

4 . The organic electroluminescent compound according to claim 3 , wherein the organic electroluminescent compound is represented by the following formula 2-1 or 2-2:

in formulas 2-1 and 2-2,

R 7 and R 8 , each independently, represent hydrogen, deuterium, a substituted or unsubstituted (C1-C30)alkyl, a substituted or unsubstituted (C3-C30)cycloalkyl, a substituted or unsubstituted (C6-C30)aryl, or a substituted or unsubstituted (3- to 30-membered)heteroaryl; or adjacent R 7 's, and adjacent R 8 's, each independently, may be linked to each other to form a ring(s);

d and e, each independently, represent an integer of 1 to 4, in which, if d and e, each independently, are an integer of 2 or more, each of R 7 and each of R 8 may be the same or different;

x represents 1 or 2;

y represents 1 or 2;

the sum of x and y is the oxidation number of Ir;

R, R 1 , and n are as defined in claim 1 ; and

R′ 1 to R′ 4 are as defined in claim 3 .

5 . The organic electroluminescent compound according to claim 1 , wherein R, each independently, represents a (C1-C10)alkyl unsubstituted or substituted with deuterium, or an unsubstituted (C6-C25)aryl.

6 . The organic electroluminescent compound according to claim 1 , wherein R 1 and R 4 to R 8 , each independently, are selected from the group consisting of hydrogen, deuterium, methyl, ethyl, n-propyl, isopropyl, n-butyl, isobutyl, sec-butyl, tert-butyl, n-pentyl, tert-pentyl, neopentyl, isopentyl, sec-pentyl, sec-isopentyl, 3-pentyl, and phenyl; and the hydrogen in R 1 and R 4 to R 8 may be substituted with deuterium.

7 . The organic electroluminescent compound according to claim 3 , wherein R′ 1 to R′ 4 , each independently, are selected from the group consisting of hydrogen, deuterium, methyl, ethyl, n-propyl, isopropyl, n-butyl, isobutyl, sec-butyl, tert-butyl, n-pentyl, tert-pentyl, neopentyl, isopentyl, sec-pentyl, sec-isopentyl, and 3-pentyl; and the hydrogen in R′ 1 to R′ 4 may be substituted with deuterium.

8 . The organic electroluminescent compound according to claim 1 , wherein the substituent(s) of the substituted benzene ring, the substituted pyridine ring, the substituted alkyl, the substituted aryl, the substituted heteroaryl, and the substituted cycloalkyl, each independently, are at least one selected from the group consisting of deuterium; a halogen; a cyano; a carboxyl; a nitro; a hydroxyl; a phosphine oxide; a (C1-C30)alkyl; a halo(C1-C30)alkyl; a (C2-C30)alkenyl; a (C2-C30)alkynyl; a (C1-C30)alkoxy; a (C1-C30)alkylthio; a (C3-C30)cycloalkyl; a (C3-C30)cycloalkenyl; a (3- to 7-membered)heterocycloalkyl; a (C6-C30)aryloxy; a (C6-C30)arylthio; a (3- to 30-membered)heteroaryl unsubstituted or substituted with a (C6-C30)aryl(s); a (C6-C30)aryl unsubstituted or substituted with at least one of a (C1-C30)alkyl(s), a (C6-C30)aryl(s), and a (3- to 30-membered)heteroaryl(s); a tri(C1-C30)alkylsilyl; a tri(C6-C30)arylsilyl; a di(C1-C30)alkyl(C6-C30)arylsilyl; a (C1-C30)alkyldi(C6-C30)arylsilyl; a fused ring group of a (C3-C30) aliphatic ring(s) and a (C6-C30) aromatic ring(s); an amino; a mono- or di-(C1-C30)alkylamino; a mono- or di-(C2-C30)alkenylamino; a (C1-C30)alkyl(C2-C30)alkenylamino; a mono- or di-(C6-C30)arylamino; a (C1-C30)alkyl(C6-C30)arylamino; a mono- or di-(3- to 30-membered)heteroarylamino; a (C1-C30)alkyl(3- to 30-membered)heteroarylamino; a (C2-C30)alkenyl(C6-C30)arylamino; a (C2-C30)alkenyl(3- to 30-membered)heteroarylamino; a (C6-C30)aryl(3- to 30-membered)heteroarylamino; a (C1-C30)alkylcarbonyl; a (C1-C30)alkoxycarbonyl; a (C6-C30)arylcarbonyl; a (C6-C30)arylphosphinyl; a di(C6-C30)arylboronyl; a di(C1-C30)alkylboronyl; a (C1-C30)alkyl(C6-C30)arylboronyl; a (C6-C30)aryl(C1-C30)alkyl; and a (C1-C30)alkyl(C6-C30)aryl.

9 . The organic electroluminescent compound according to claim 1 , wherein the organic electroluminescent compound is selected from the group consisting of the following:

10 . An organic electroluminescent material comprising the organic electroluminescent compound according to claim 1 .

11 . An organic electroluminescent device comprising a cathode, an anode, and a light-emitting layer between the cathode and the anode, wherein the light-emitting layer comprises the organic electroluminescent compound according to claim 1 .