Polyamide-based film, preparation method thereof, and cover window and display device comprising the same
The embodiments provide a polyamide-based film, which comprises a polyamide-based polymer and has an RSR A value of 3.4 m/N to 5.0 m/N as represented by the following Equation 1 based on the thickness of the film of 50 μm, and which is excellent in loop stiffness, static flexural characteristics, and folding characteristics while securing mechanical and optical properties at least a certain level, a process for preparing the same, and a cover window and a display device comprising the same. <Equation 1> RSR A =(RSR MD +RSR TD )/2 In Equation 1, RSR MD is the loop stiffness value measured with the MD direction of the film as the longitudinal direction at room temperature, and RSR TD is the loop stiffness value measured with the TD direction of the film as the longitudinal direction at room temperature.
1 . A polyamide-based film, which comprises a polyamide-based polymer and has an RSR A value of 3.6 m/N to 5.0 m/N as represented by the following Equation 1 and an RSL A value of 3.7 m/N to 5.0 m/N as represented by the following Equation 2 based on the thickness of the film of 50 μm:
RSR A =(RSR MD +RSR TD )/2 <Equation 1>
in Equation 1, RSR MD is the loop stiffness value measured with the MD direction of the film as the longitudinal direction at room temperature, and RSR TD is the loop stiffness value measured with the TD direction of the film as the longitudinal direction at room temperature, wherein RSR MD is 3.35 m/N to 5.0 m/N, and RSR TD is 3.3 m/N to 5.0 m/N,
RSL A =(RSL MD +RSL TD )/2 <Equation 2>
in Equation 2, RSL MD is the loop stiffness value measured with the MD direction of the film as the longitudinal direction within 1 minute after the film is left at −20° C. for 2 hours, and RSL TD is the loop stiffness value measured with the TD direction of the film as the longitudinal direction within 1 minute after the film is left at −20° C. for 2 hours,
wherein the polyamide-based polymer comprises an imide-based repeat unit and an amide-based repeat unit at a molar ratio of 0:100 to 7:93,
wherein the film is manufactured by a method comprising,
polymerizing a diamine compound, a dicarbonyl compound, and, optionally, a dianhydride compound in an organic solvent to prepare a polyamide-based polymer solution;
casting the solution and then drying it to prepare a gel sheet; and
thermally treating the gel sheet,
wherein the step of thermally treating the gel sheet is carried out by fixing both ends of the gel sheet in the transverse direction with a fixing part, and thermally treating it while the width of the fixed gel sheet is changed,
wherein the step of thermally treating the gel sheet comprises first thermal treatment through hot air supplied by at least one hot air blower; and second thermal treatment through at least one heater, and
wherein when the section in which the first thermal treatment step is carried out is referred to as a first thermal treatment section,
the section in which the second thermal treatment step is carried out is referred to as a second thermal treatment section,
the maximum width of the gel sheet in the first thermal treatment section is referred to as Wa,
the minimum width of the gel sheet is in the first thermal treatment section is referred to as Wb,
the minimum width of the gel sheet in the first thermal treatment section and the second thermal treatment section is referred to as Wc, and
the Wb/Wa value is 0.955 to 0.990, and the Wc/Wa value is 0.950 to 0.990.
2 . The polyamide-based film of claim 1 , wherein when the film based on a thickness of 50 μm is folded to have a radius of curvature of 2 mm, which is then left at 25° C. for 24 hours, and the force applied to the film is released, the inner angle of the film is 140° or more.
3 . The polyamide-based film of claim 1 , which has a modulus of 5 GPa or more.
4 . The polyamide-based film of claim 1 , which has a transmittance of 80% or more, a haze of 1% or less, and a yellow index or 5 or less.
5 . The polyamide-based film of claim 1 , which further comprises at least one selected from the group consisting of a filler, a blue pigment, and a UVA absorber.
6 . A cover window, which comprises a polyamide-based film according to claim 1 and a functional layer, wherein the polyamide-based film comprises a polyamide-based polymer and has an RSR A value of 3.6 m/N to 5.0 m/N as represented by the following Equation 1 and an RSL A value of 3.7 m/N to 5.0 m/N as represented by the following Equation 2 based on the thickness of the film of 50 μm:
RSR A =(RSR MD +RSR TD )/2 <Equation 1>
in Equation 1, RSR MD is the loop stiffness value measured with the MD direction of the film as the longitudinal direction at room temperature, and RSR TD is the loop stiffness value measured with the TD direction of the film as the longitudinal direction at room temperature, wherein RSR MD is 3.35 m/N to 5.0 m/N, and RSR TD is 3.3 m/N to 5.0 m/N,
RSL A =(RSL MD +RSL TD )/2 <Equation 2>
in Equation 2, RSL MD is the loop stiffness value measured with the MD direction of the film as the longitudinal direction within 1 minute after the film is left at −20° C. for 2 hours, and RSL TD is the loop stiffness value measured with the TD direction of the film as the longitudinal direction within 1 minute after the film is left at −20° C. for 2 hours,
wherein the polyamide-based polymer comprises an imide-based repeat unit and an amide-based repeat unit at a molar ratio of 0:100 to 7:93.
7 . A display device, which comprises a display unit; and a cover window disposed on the display unit, wherein the cover window comprises a polyamide-based film according to claim 1 and a functional layer, and the polyamide-based film comprises a polyamide-based polymer and has an RSR A value of 3.6 m/N to 5.0 m/N as represented by the following Equation 1 and an RSL A value of 3.7 m/N to 5.0 m/N as represented by the following Equation 2 based on the thickness of the film of 50 μm:
RSR A =(RSR MD +RSR TD )/2 <Equation 1>
in Equation 1, RSR MD is the loop stiffness value measured with the MD direction of the film as the longitudinal direction at room temperature, and RSR TD is the loop stiffness value measured with the TD direction of the film as the longitudinal direction at room temperature, wherein RSR MD is 3.35 m/N to 5.0 m/N, and RSR TD is 3.3 m/N to 5.0 m/N,
RSL A =(RSL MD +RSL TD )/2 <Equation 2>
in Equation 2, RSL MD is the loop stiffness value measured with the MD direction of the film as the longitudinal direction within 1 minute after the film is left at −20° C. for 2 hours, and RSL TD is the loop stiffness value measured with the TD direction of the film as the longitudinal direction within 1 minute after the film is left at −20° C. for 2 hours,
wherein the polyamide-based polymer comprises an imide-based repeat unit and an amide-based repeat unit at a molar ratio of 0:100 to 7:93,
wherein RSR MD is 3.35 m/N to 5.0 m/N, and RSR TD is 3.3 m/N to 5.0 m/N.